TANG Tao, CHEN Hui, ZHANG Xuequan, LI Lin, HUANG Baotong. MOLECULAR STATE OF POLYMER IN THE INTERFACIAL AREA OF POLYOLEFIN AND POLAR POLYMES[J]. Acta Polymerica Sinica, 1996,(3):336-342.
TANG Tao, CHEN Hui, ZHANG Xuequan, LI Lin, HUANG Baotong. MOLECULAR STATE OF POLYMER IN THE INTERFACIAL AREA OF POLYOLEFIN AND POLAR POLYMES[J]. Acta Polymerica Sinica, 1996,(3):336-342.DOI:
In order to solve the characterization of interface in polymer blends
a new method that the interface is exposed by solvent dissolving selectively was put forward. By means of X-ray photoelectron spectrometry
we studied the molecular state of compatibilizer in the interfacial area of polyolefin and polar polymer
including -functionalized polymer
graft copolymer and polymer with reactive groups. The experimental results showed that when using as compatibilizers
functionalized polymer adopted favorable conformation to develop completely compatibilization efficiency in the interfacial area the backbone polymer and branch polymer of graft copolymer diffuse into the corresponding miscible polymer bulks;and the reactive groups enriched in the interfacial area before polymer with reactive groups reacting with some polymer bulks.