HU Xiao-dong, WANG Fo-song, ZHAO Xiao-jang, YAN De-yue. STRUCTURE CHARACTER OF SOLUBLE POLYACETYLENE OBTAINED WITH RARE-EARTH BASED CATALYST[J]. Acta Polymerica Sinica, 1987,(4):306-311.
HU Xiao-dong, WANG Fo-song, ZHAO Xiao-jang, YAN De-yue. STRUCTURE CHARACTER OF SOLUBLE POLYACETYLENE OBTAINED WITH RARE-EARTH BASED CATALYST[J]. Acta Polymerica Sinica, 1987,(4):306-311.DOI:
Changchun Institute of Applied Chemistry; Academia Sinica)YAN Deyue(Department of Applied Chemistry; Jiaotong University; Shanghai);
Abstract
The structure and properties of soluble polyacetylene (PA) obtained with rare-earth catalyst are thoroughly investigated by UV
IR
Raman spectroscopes
ESR and X-ray diffraction. The soluble PA is different with film and powder PA in their spectra and ESR
which arises from the fact that the average molecular weight of the former is much lower than that of the latter. The experimental results indicate that linear PA usually has a critical average molecular weight for solution
and the soluble PA show some specular properties because its average mole-cular weight is below the critical value.