JIANG Huai-wei, LI Xi-ming, LIN Ming-zhang, NISHIMOTO Seiichi. A STUDY ON KINETICS OF GEL FORMATION OF POLYPROPYLENE/POLYETHYLENE BLENDS BY GAMMA RADIATION[J]. Acta Polymerica Sinica, 1991,(6):704-710.
JIANG Huai-wei, LI Xi-ming, LIN Ming-zhang, NISHIMOTO Seiichi. A STUDY ON KINETICS OF GEL FORMATION OF POLYPROPYLENE/POLYETHYLENE BLENDS BY GAMMA RADIATION[J]. Acta Polymerica Sinica, 1991,(6):704-710.DOI:
the relationship between sol fraction (s) and radiation dose (R) in radiation crosslinking of PP/HDPE blends was studied. The results indicate that both Charles-by-pinner expression and Chen-Liu-Tang expression
which were well applicable with radiation crosslinking of some polymers
do not well fit to the case of PP/HDPE blends.According to Zhang's assumption
which deals with relationship between structure and radiation crosslinking of pure polymers and applies to most cases
fracture density of polymer is proportional to Rβ
where β is a parameter depending on the structure of a polymer.In this paper
we extended their assumption to polymer blends
but the Rβ value of blends were modified by equation Rβ=∑fiRβi
where fi and βi are weight fraction and β value of i component in blend
respectively. Using the modified Rβ
good linear relation between R(s+s)and Rβ of PP/HDPE blends was obtained.