高性能纤维表面改性及其双马树脂基复合材料界面

陈平; 于祺; 熊需海; 刘东; 刘哲; 贾彩霞

doi:10.11777/j.issn1000-3304.2017.17081

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高性能纤维表面改性及其双马树脂基复合材料界面

专论 | 更新时间：2021-01-26

- 高性能纤维表面改性及其双马树脂基复合材料界面
- Surface Modification of High Performance Fibers and Interfacial Properties of Their Reinforced Bismaleimide Resin Matrix Composites
- 高分子学报 2018年49卷第3期页码：323-335
- 作者机构：
  
  1.精细化工国家重点实验室大连理工大学化工学院大连 116024
  2.先进聚合物基复合材料辽宁省重点实验室沈阳航空航天大学沈阳 110136
- 作者简介：
  
  [ "陈平，男，1964年出生.大连理工大学高分子材料学科教授/博士生导师. 1982 ~ 1989年在哈尔滨电工学院获得学士、硕士学位; 2002年在大连理工大学获得博士学位. 1989 ~ 1996年哈尔滨玻璃钢研究院工程师、高级工程师. 1996 ~ 2001年哈尔滨理工大学材料学院副教授、教授. 2001年至今，大连理工大学化工学院教授.现兼任先进聚合物基复合材料辽宁省重点实验室主任; 全国橡塑技术专家委员会第一届委员.先后获得1999年国务院政府特殊津贴，2003年第四届辽宁省青年科技奖，2005年第三届侯德榜化工科学技术奖青年奖，2008年中国石油与化学工业联合会青年科技突出贡献奖，2014年辽宁省第九届优秀科技工作者等荣誉称号.长期从事高性能高分子材料及其先进聚合物基复合材料等方面的研究" ]
- 基金信息：
  
  国防基础科研重点项目(A35201XXXXX);国家自然科学基金重点项目(10835004);国家自然科学基金(51303106);辽宁省重点科技攻关项目(2007403009);辽宁省优秀人才基金(LR2013002);辽宁省高等学校重点实验室基础研究项目(LZ2015057);三束材料改性教育部重点实验室创新基金(LABKF1502)
- DOI：10.11777/j.issn1000-3304.2017.17081
  中图分类号：
- 纸质出版日期：2018-3-20，
  
  收稿日期：2017-4-7，
  
  修回日期：2017-7-6，
扫描看全文
陈平, 于祺, 熊需海, 刘东, 刘哲, 贾彩霞. 高性能纤维表面改性及其双马树脂基复合材料界面[J]. 高分子学报, 2018,49(3):323-335.

Ping Chen, Qi Yu, Xu-hai Xiong, Dong Liu, Zhe Liu, Cai-xia Jia. Surface Modification of High Performance Fibers and Interfacial Properties of Their Reinforced Bismaleimide Resin Matrix Composites[J]. Acta Polymerica Sinica, 2018,49(3):323-335.
陈平, 于祺, 熊需海, 刘东, 刘哲, 贾彩霞. 高性能纤维表面改性及其双马树脂基复合材料界面[J]. 高分子学报, 2018,49(3):323-335. DOI： 10.11777/j.issn1000-3304.2017.17081.

Ping Chen, Qi Yu, Xu-hai Xiong, Dong Liu, Zhe Liu, Cai-xia Jia. Surface Modification of High Performance Fibers and Interfacial Properties of Their Reinforced Bismaleimide Resin Matrix Composites[J]. Acta Polymerica Sinica, 2018,49(3):323-335. DOI： 10.11777/j.issn1000-3304.2017.17081.

摘要

采用电感耦合射频等离子体(ICP)和介质阻挡放电(DBD)低温等离子体对高性能连续纤维表面进行改性，分别采用X光电子能谱(XPS)、原子力显微镜(AFM)和动态接触角测定仪(DCA)等分析测试手段系统地研究了等离子体处理时间、放电功率、放电气压等对连续碳纤维、聚苯并二噁唑(PBO)纤维改性处理前后，纤维表面状态、表面组成、表面形貌、浸润性能的变化规律以及经等离子体处理前后纤维增强双马树脂基复合材料界面结构与性能的影响关系及变化规律、复合材料界面粘结和破坏机理.研究结果表明，经过等离子体处理后，纤维表面接枝上了大量的含羧基、羟基等极性官能团，表面粗糙度增加，表面自由能增加，纤维浸润性能得到明显改善，导致纤维与双马树脂基体界面层间剪切强度(ILSS)明显提高，复合材料的破坏模式由未处理的界面脱粘破坏转变为等离子体处理后的树脂基体破坏.最后，对纤维表面时效性及其对纤维增强双马树脂基复合材料界面性能的影响关系也进行了论述.

Abstract

Surface modification of high-performance continuous fibers was carried out by inductively coupled plasma (ICP) and dielectric barrier discharge (DBD) cold plasma

respectively. The effects of treatment time

discharge power and pressure on the chemical composition

morphology and wetting ability of the fiber surface were investigated by X-ray photoelectron spectroscopy (XPS)

atomic force microscopy (AFM) and dynamic contact angle analysis (DCA). The relationship between interface structure and interfacial adhesion

and the failure mechanism of the fibers reinforced bismaleimide (BMI) composites were discussed. The results indicated that the treatment of PBO fibers by O

Ar and mixed O

/Ar ICP

respectively

would result in the decomposition of the phenyl rings and oxazole moieties on the fiber surface

along with the formation of some polar groups and active groups

such as ester bonds

amide bonds and free radicals. Sputtering and etching of plasma also brought about a rough morphology for fiber surface. The modification effect by Ar ICP was better than that by O

ICP

and O

/Ar ICP presented the best activation effect on the chemical compositions of PBO surface due to the synergy effect. The optimum ratio of O

/Ar mixture was 40% -60% of O

content. The interlaminar shear strength (ILSS) of PBO/BMI composite treated with O

/Ar ICP was 61.6 MPa

an increase by 38.1% compared with that of the untreated samples. The DBD plasma also improved the polarity

reactivity and the morphology of the PBO fiber surface. The effect of enhancement in ILSS values of PBO/BMI composites treated by O

DBD was better in comparison with that treated by air DBD. The ILSS value was increased to 57.1 MPa at 12 s when treated at 30 W/cm

by air DBD plasma

while that of PBO/BMI composites treated by oxy-DBD plasma under the same condition was 62 MPa. Scanning electron microscopy (SEM) micrographs demonstrated that the fracture failure mechanism of PBO/BMI composites treated by ICP or DBD plasma shifted from interface failure to matrix failure. Finally

the relationship between the aging behavior of the fiber surface and the interfacial property of the fiber reinforced BMI composites were also discussed. ILSS values of PBO/BMI composites decreased with storage time for the fibers treated by plasma.

关键词

连续纤维等离子体处理技术复合材料界面纤维表面改性界面结构与性能

Keywords

Continuous fibersPlasma treatment technologyComposite interfaceFiber surface modificationInterface structure and properties

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