中国嵌段共聚物受限自组装的研究进展

张连斌; 王珂; 朱锦涛

doi:10.11777/j.issn1000-3304.2017.17126

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中国嵌段共聚物受限自组装的研究进展

综述 | 更新时间：2021-01-26

- 中国嵌段共聚物受限自组装的研究进展
- Research Progress on Confined Assembly of Block Copolymers in China
- 高分子学报 2017年第8期页码：1261-1276
- 作者机构：
  
  华中科技大学化学与化工学院能量转换与存储材料化学教育部重点实验室武汉 430074
- 作者简介：
  
  张连斌, E-mail:zhanglianbin@mail.hust.edu.cn Lian-bin Zhang, E-mail:zhanglianbin@mail.hust.edu.cn
  朱锦涛, E-mail:jtzhu@mail.hust.edu.cn Jin-tao Zhu, E-mail:jtzhu@mail.hust.edu.cn
- 基金信息：
  
  国家自然科学基金(51525302)
- DOI：10.11777/j.issn1000-3304.2017.17126
  中图分类号：
- 纸质出版日期：2017-8，
  
  收稿日期：2016-7-26，
  
  修回日期：2016-8-12，
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张连斌, 王珂, 朱锦涛. 中国嵌段共聚物受限自组装的研究进展[J]. 高分子学报, 2017,(8):1261-1276.

Zhang Lian-bin, Wang Ke, Zhu Jin-tao. Research Progress on Confined Assembly of Block Copolymers in China[J]. Acta Polymerica Sinica, 2017,(8):1261-1276.
张连斌, 王珂, 朱锦涛. 中国嵌段共聚物受限自组装的研究进展[J]. 高分子学报, 2017,(8):1261-1276. DOI： 10.11777/j.issn1000-3304.2017.17126.

Zhang Lian-bin, Wang Ke, Zhu Jin-tao. Research Progress on Confined Assembly of Block Copolymers in China[J]. Acta Polymerica Sinica, 2017,(8):1261-1276. DOI： 10.11777/j.issn1000-3304.2017.17126.

摘要

近年来，嵌段共聚物在受限空间中的自组装已成为高分子科学领域一个新的关注点.在受限条件下，嵌段共聚物展现出更多的可调控性，可获得复杂多样的微相分离结构.这些新颖的结构为实现嵌段共聚物更加丰富的功能奠定了材料基础.中国的学者们在嵌段共聚物受限自组装的理论模拟和实验研究方面取得了一系列重要创新成果，有力地推动了该领域的发展.本文总结和评述了中国学者在该领域的研究进展，并展望了嵌段共聚物受限自组装研究未来发展的机遇与挑战.

Abstract

Block copolymers (BCPs) are a kind of copolymers containing homopolymer blocks that are chemically bonded together. They can undergo microphase separation (

i.e

self-assembly) to form well-defined nanostructures (

e.g

spheres

cylinders

vesicles

etc

since their non-compatible blocks are covalently bonded

limiting the macrophase separation. The self-assembled nanostructures possess great potential for various applications in the fields of nanolithography

photonic crystal

data storage

drug delivery and controlled release

diagnostics and others. When imposing spatial constrains on BCPs

where the confining volume has at least one dimension comparable to the period (

) of the bulk copolymer phase

a large variety of novel BCP assemblies (

e.g

helix

patchy

staking

and other complex structures) can be generated under confined space due to the symmetry breaking

interfacial interactions

structural frustration and confinement-induced entropy loss. Recently

the fabrication of confined assemblies of BCPs and investigation of the BCPs assembly in different confined geometries from experimental and theoretical simulation points have been a topic of great interest in the scientific communities in China. This review aims to summarize some research progress on confined assembly of BCPs in China

including the general concept of confined assembly of BCPs

experimental and simulative investigation of confined assemblies of BCPs through varying factors under different dimensions

and potential applications of confined BCP assemblies. Factors affecting the confined assembly of BCPs

including the degree of confinement (

D is the size of confinement space)

interfacial interaction (selective or neutral interface)

geometry of the confining space

block ratio

topology structure of the BCPs

and others

are also discussed. Moreover

compared with one dimension (1D) and 2D confinement

3D confinement provides the most tightly confining geometry (

i.e

highest confinement degree) and presents an enclosed surface around the BCPs

which may facilitate to easily manipulate new morphologies of the confined assembles and will attract more attention on this topic. To push forward the studies of the confined assembly of BCPs

the conjunction study of simulation and experiment is necessary for promoting the deep and systematic understanding of the phase behavior of BCPs under confinement

and sufficient attention should be paid to the studies of geometrical confinement on properties of the self-assembled polymeric materials.

关键词

嵌段共聚物自组装受限空间微相分离界面性质

Keywords

Block copolymersSelf-assemblyConfined spaceMicrophase separationInterfacial properties

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