聚苯胺/贵金属复合纳米材料的可控合成及催化应用

周传强; 韩杰; 郭荣

doi:10.11777/j.issn1000-3304.2020.20010

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聚苯胺/贵金属复合纳米材料的可控合成及催化应用

专论 | 更新时间：2021-01-26

- 聚苯胺/贵金属复合纳米材料的可控合成及催化应用
- Controllable Synthesis and Catalysis Application of Conducting Polymer/Noble Metal Nanoparticle Hybrids
- 高分子学报 2020年51卷第5期页码：517-529
- 作者机构：
  
  1.扬州大学化学化工学院　扬州 225002
  2.扬州大学测试中心　扬州 225009
- 作者简介：
  
  [ "韩杰，男，1981年生. 扬州大学化学化工学院教授，博士生导师. 2003和2008年于扬州大学化学化工学院获得学士和博士学位. 2008年6月进入扬州大学化学化工学院. 2010年获得全国百篇优秀博士论文提名奖，2012年获得教育部自然科学二等奖(排名第二)，2013年获第一届“东方胶化”杯全国胶体与界面年化学优秀青年教师一等奖，2016年入选江苏省高校“青蓝工程”中青年学术带头人培养对象，2017年入选江苏省第十四批“六大人才高峰”高层次人才计划，2018年入选扬州大学高端人才“领军人才”计划，2019年获得国家自然科学基金优秀青年科学基金资助. 主要从事导电高分子功能材料的组装与催化、新型两亲分子组装及应用等方面的研究" ]
- 基金信息：
  
  国家自然科学基金(基金号21922202，21673202)资助项目
- DOI：10.11777/j.issn1000-3304.2020.20010
  中图分类号：
- 纸质出版日期：2020-5，
  
  网络出版日期：2020-4-9，
  
  收稿日期：2020-1-13，
  
  修回日期：2020-2-16，
扫描看全文
周传强, 韩杰, 郭荣. 聚苯胺/贵金属复合纳米材料的可控合成及催化应用[J]. 高分子学报, 2020,51(5):517-529.

Chuan-qiang Zhou, Jie Han, Rong Guo. Controllable Synthesis and Catalysis Application of Conducting Polymer/Noble Metal Nanoparticle Hybrids[J]. Acta Polymerica Sinica, 2020,51(5):517-529.
周传强, 韩杰, 郭荣. 聚苯胺/贵金属复合纳米材料的可控合成及催化应用[J]. 高分子学报, 2020,51(5):517-529. DOI： 10.11777/j.issn1000-3304.2020.20010.

Chuan-qiang Zhou, Jie Han, Rong Guo. Controllable Synthesis and Catalysis Application of Conducting Polymer/Noble Metal Nanoparticle Hybrids[J]. Acta Polymerica Sinica, 2020,51(5):517-529. DOI： 10.11777/j.issn1000-3304.2020.20010.

摘要

导电高分子/贵金属复合纳米材料因其在催化、传感、表面增强拉曼、光热治疗等诸多领域的应用前景而受到广泛关注. 本文主要介绍我们课题组近年来利用可控合成策略制备的负载型和包埋型两种结构聚苯胺/贵金属复合纳米材料，以及利用复合纳米材料的结构和功能特性，对其在多相催化领域的应用、结构与催化性能之间构效关系的探索.

Abstract

Conducting polymer/noble metal nanoparticle hybrids have aroused increasing interest due to their potential application in ﬁelds of catalysis

sensing

surface-enhanced Raman

photo-thermal therapy and so on. The incorporation of conducting polymers with noble metal nanoparticles can produce new hybrids showing distinct properties that are not observed in the individual components. In general

the strategies in the synthesis of conducting polymer/noble metal nanoparticle hybrids involve the direct mixing of conducting polymers and noble metal nanoparticles

redox reaction between conducting polymers and noble metal ions

redox reaction between aniline monomers and noble metal ions

as well as aniline monomer polymerization in the presence of noble metal nanoparticles. Noble metal nanoparticles are either supported on surfaces of conducting polymer nanostructures or embedded in conducting polymer matrix. Our research focuses on the controllable synthesis of polyaniline/noble metal nanoparticle hybrids with compact interactions

which will show potential application as advanced nanocatalysts in diverse catalytic reactions. This fearfure artcle aims at reviewing our work in recent years on the synthetic strategies and catalysis application of polyaniline/noble metal nanoparticle hybrids. The supported polyaniline/noble metal nanoparticle hybrids can be synthesized through the redox reaction between polyaniline and noble metal ion

where the configuration of hybrids and size of supported noble metal nanoparticles are determined by polyaniline nanostructures and functional doping acids. The embedded polyaniline/noble metal nanoparticle hybrids can be synthesized through the redox reaction between aniline monomer and noble metal ion

where the functional substituents in aniline monomer play the determining role in reducing the size of noble metal nanoparticles in hybrids. In addition

the polymerization of aniline monomer on surfaces of noble metal nanoparticles can also lead to embedded polyaniline/noble metal nanoparticle hybrids with compact interaction. Polyaniline/noble metal nanoparticle hybrids have been successfully applied as nanocatalysts in nitrophenol reduction

alcohol oxidation

Suzuki-Miyaura cross-coupling

and Ullmann reactions. In particular

a novel yolk-in-shell nanostructure of polyaniline/Au hybrids have been emphasized and the synergistic catalytic effect of polyaniline for Au nanoparticles has been discussed.

关键词

导电高分子聚苯胺贵金属纳米粒子复合材料催化

Keywords

Conducting polymerPolyanilineNoble metal nanoparticleHybridCatalysis

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