聚(3,4-乙烯二氧噻吩)在电磁屏蔽领域的应用

高晗; 张扬

doi:10.11777/j.issn1000-3304.2020.20071

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聚(3,4-乙烯二氧噻吩)在电磁屏蔽领域的应用

综述 | 更新时间：2021-01-26

- 聚(3,4-乙烯二氧噻吩)在电磁屏蔽领域的应用
- Application of Poly(3,4-ethylenedioxythiophene) in the Fields of Electromagnetic Interference Shielding
- 高分子学报 2020年51卷第9期页码：996-1009
- 作者机构：
  
  北京工商大学材料与机械工程学院　北京 100048
- 作者简介：
  
  [ "张扬，男，1982年生. 北京工商大学材料与机械工程学院副教授. 2009年毕业于中国科学院化学研究所，获高分子化学与物理专业博士学位. 2009 ~ 2012年在清华大学从事博士后研究工作. 2012年3月起任职于北京工商大学材料科学与工程系. 2018年在纽约州立大学布法罗分校访学. 目前主要从事聚合物基电磁功能复合材料的研究" ]
- 基金信息：
  
  国家自然科学基金(基金号 11564042)和北京市教育委员会-市自然科学基金联合(基金号 KZ202010011019)资助项目
- DOI：10.11777/j.issn1000-3304.2020.20071
  中图分类号：
- 纸质出版日期：2020-8-15，
  
  网络出版日期：2020-5-26，
  
  收稿日期：2020-3-16，
  
  修回日期：2020-3-27，
扫描看全文
高晗, 张扬. 聚(3,4-乙烯二氧噻吩)在电磁屏蔽领域的应用[J]. 高分子学报, 2020,51(9):996-1009.

Han Gao, Yang Zhang. Application of Poly(3,4-ethylenedioxythiophene) in the Fields of Electromagnetic Interference Shielding[J]. Acta Polymerica Sinica, 2020,51(9):996-1009.
高晗, 张扬. 聚(3,4-乙烯二氧噻吩)在电磁屏蔽领域的应用[J]. 高分子学报, 2020,51(9):996-1009. DOI： 10.11777/j.issn1000-3304.2020.20071.

Han Gao, Yang Zhang. Application of Poly(3,4-ethylenedioxythiophene) in the Fields of Electromagnetic Interference Shielding[J]. Acta Polymerica Sinica, 2020,51(9):996-1009. DOI： 10.11777/j.issn1000-3304.2020.20071.

摘要

随着现代电子信息技术的迅猛发展，电磁干扰问题日益严重，发展综合性能优异的电磁屏蔽材料具有重要意义. 聚(3

4-乙烯二氧噻吩) (poly(3

4-ethylenedioxythiophene)，PEDOT)具有分子结构简单、能隙小、电导率高等特点，为高性能电磁屏蔽材料的实现提供了新途径. 同时，随着对材料电磁屏蔽性能研究的深入以及制备技术的进步，将PEDOT与其他材料复合，通过合理的组分选择与结构设计，可以协同发挥各组分间电磁匹配特性，从而使PEDOT更好地满足柔性显示、智能可穿戴设备、高频器件、高精密电子设备等应用领域对电磁屏蔽材料“厚度薄、密度低、屏蔽强、屏蔽带宽宽”的具体要求. 近年来，较多的研究致力于此并取得重要的成果. 本文对以PEDOT为功能组分的电磁屏蔽材料的最新研究进展进行了综述，将近年来PEDOT及其与不同功能组分复合(包括导电组分、磁性组分及无电磁特性组分)构筑的电磁屏蔽材料体系的制备及电磁性能进行归纳总结，重点讨论电磁组分、微观结构与电磁屏蔽特性的联系，及其电磁屏蔽机理与性能优化方式，并对PEDOT在电磁屏蔽研究领域的机遇与挑战进行了展望.

Abstract

With the explosive development of modern electronic information technology

electromagnetic interference (EMI) has become increasingly prominent. The development of EMI shielding materials with excellent comprehensive performance has captured enormous scientific attention. Poly(3

4-ethylenedioxythiophene) (PEDOT) exhibits the characteristics of simple molecular structure

small energy gap and high electrical conductivity. These outstanding features provide a new perspective on the construction of high-performance electromagnetic shielding materials. At the same time

with the comprehensive investigations of EMI shielding properties and advances in synthesis technology

PEDOT is compounded with other functional components. Through rational components selection and structural design

the enhanced synergy of electromagnetic attenuation characteristics between the components is achieved. PEDOT will fulfill requirements of ‘thin thickness

low density

strong shielding capability

wide shielding bandwidth’ of advanced electromagnetic shielding materials. Thus

PEDOT-based materials can meet the high EMI shielding demands of flexible display

smart wearable devices

high-frequency devices

high-precision electronic equipment and other applications. Many researches have been done on this topic and numerous achievements have been realized over these years. This review surveys the recent advances of PEDOT-based electromagnetic shielding materials. The synthesis approaches of PEDOT are introduced first. Then

the construction strategies for representative PEDOT-based composites using conductive

magnetic and non-electromagnetic components are summarized. Their prominent and unique electromagnetic characteristics are discussed. Particularly

the relationship between the electromagnetic components

structure and electromagnetic characteristics are summarized. The EMI shielding mechanism and performance optimization approaches are also detailed. Finally

some problems existing in the current research are presented

as well as the suggestions and challenges regarding future research needs.

关键词

聚(34-乙烯二氧噻吩)电导率电磁参数电磁屏蔽机理

Keywords

Poly(34-ethylenedioxythiophene)Electrical conductivityElectromagnetic parameterElectromagnetic shielding mechanism

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