淀粉基生物可降解材料的研究新进展

朱建; 陈慧; 卢凯; 刘宏生; 余龙

doi:10.11777/j.issn1000-3304.2020.20089

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淀粉基生物可降解材料的研究新进展

综述 | 更新时间：2021-01-26

- 淀粉基生物可降解材料的研究新进展
- Recent Progress on Starch-based Biodegradable Materials
- 高分子学报 2020年51卷第9期页码：983-995
- 作者机构：
  
  1.华南理工大学可再生资源高分子研究中心　广州 510640
  2.广州知识城中国-新加坡国际联合研究院　广州 510663
- 作者简介：
  
  [ "余龙，男，1959年生. 现任中国新加坡国家联合研究院院长，华南理工大学博导教授，澳大利亚MONASH大学名誉高级研究员. 2002年被选为澳大利亚皇家化学学会Fellow. 大学本科毕业于华南理工大学，澳大利亚MONASH大学获博士学位. 1988 ~ 2015在澳大利亚学习工作，曾任澳大利亚科学与工业研究院材料研究所首席科学家. 2015年全职回国，任广东省海外引进创新团队负责人. 现担任8个SCI国际学术期刊的编委. 现任中国降解塑料协会副会长. 已经发表SCI收录学术论文160多篇，论文累计引用超过1万次(H-index 51). 近年来主要从事可再生资源高分子材料的研究，尤其淀粉基材料. 目前已产业化8项科研成果，包括全淀粉包装材料和全淀粉药用胶囊等. 近期研究开发出的全淀粉环保发泡包装材料和淀粉基水凝胶保湿缓释化肥也在产业化过程中" ]
- 基金信息：
  
  国家重点研发计划项目(项目号 2018YFD0400702)和广州市开发区国际合作项目(项目号 2018GH18)资助
- DOI：10.11777/j.issn1000-3304.2020.20089
  中图分类号：
- 纸质出版日期：2020-8-15，
  
  网络出版日期：2020-7-10，
  
  收稿日期：2020-4-1，
  
  修回日期：2020-5-4，
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朱建, 陈慧, 卢凯, 刘宏生, 余龙. 淀粉基生物可降解材料的研究新进展[J]. 高分子学报, 2020,51(9):983-995.

Jian Zhu, Hui Chen, Kai Lu, Hong-sheng Liu, Long Yu. Recent Progress on Starch-based Biodegradable Materials[J]. Acta Polymerica Sinica, 2020,51(9):983-995.
朱建, 陈慧, 卢凯, 刘宏生, 余龙. 淀粉基生物可降解材料的研究新进展[J]. 高分子学报, 2020,51(9):983-995. DOI： 10.11777/j.issn1000-3304.2020.20089.

Jian Zhu, Hui Chen, Kai Lu, Hong-sheng Liu, Long Yu. Recent Progress on Starch-based Biodegradable Materials[J]. Acta Polymerica Sinica, 2020,51(9):983-995. DOI： 10.11777/j.issn1000-3304.2020.20089.

摘要

从淀粉的微观结构、加工过程中的相变及淀粉改性等基础理论出发，针对淀粉基材料存在的机械性能较低，对水敏感性高等缺陷，以及发泡材料制备的特点，介绍了最新的基础研究和应用研究成果. 本文从淀粉基全天然高分子复合材料、纳米复合材料、自增强复合材料及功能性复合材料四个方面介绍了通过共混与复合制备淀粉基可生物降解材料，并且介绍了淀粉基材料防水改性的相关进展. 指出使用可再生的天然高分子材料对淀粉进行改性，不仅能够提高材料的各种性能，而且由于所有组分都来源于天然材料，制备出的共混、复合和涂层材料也都环保安全，甚至可以用来制备可食用包装，为研制新型淀粉基材料提供有力的理论和技术支持. 另外，目前对水在淀粉基发泡材料中如何同时担任增塑剂和发泡剂的机理研究取得突破性进展，发现并控制了泡孔结构由闭孔到开孔的转换临界点，研制并产业化了全淀粉发泡材料. 基于上述讨论，指出淀粉基可生物降解材料既有机遇，同时也面临挑战.

Abstract

Starch-based materials have showed greatly potentials

especially when more and more countries have passed the standards or regulations of banning or restricting disposable plastics. Many products

such as films

capsules

sheets

foam

etc.

have been developed and commercialized. Like all other materials

improving performance and decreasing cost are two on-going strategic. In principle

the properties of starch-based materials can be significantly improved by blending with synthetic oil-based polymers. However

these blends were not biodegradable thus losing the advantage of using a biodegradable polysaccharide. The polymer blends and composites only from natural raw materials are discussed in this work. This paper reviews the recent development of starch-based biodegradable materials. Based on fundamental achievements

such as microstructures

phase transitions and starch modified

this paper mainly focused on the latest development of solving some well-recognized weakness

such as lower mechanical properties

moisture sensitivity and developing starch-based foaming materials. It was found that various technologies in polymer industrials

such as blending

compositing

grafting

crosslinking

coating

etc

have been successfully developed to improve the performance of starch-based materials. The progress of starch-based polymer blending and compositing were introduced from four parts

including natural polymer composites

nano-composites

self-reinforce composites and functionalized composites

as well as the progress of starch waterproofing modification. It has been noticed that application of the natural materials from renewable resources as reinforce agents can not only reinforce or improve the performance of starch-based materials

but also develop environmentally friendly

even edible packaging. It is pointed out that application of the natural materials from renewable resources to reinforce or improve the performance of starch-based materials has showed great potential. It provides powerful theoretical and technical support for the development of new starch-based materials. Furthermore

through investigating the effects of water content on melting temperature (

)

crystallinity

foaming process

cell structures well as mechanical properties

the mechanism of how water acting as both plasticizer and blow agent at the same time have been explored. It was found that there existed a critical point of water content (between 16%–18%) at which the expending ratio changed significantly since the cell structure changed from opening to closing. These starch-based foaming materials were developed and industrialized. In summary

there are both challenges and opportunities in developing starch-based materials.

关键词

淀粉微观结构相变复合材料机械性能水分敏感性发泡材料

Keywords

Microstructures of starchPhase transitionCompositesMechanical propertiesMoisture sensitivityFoam

references

Yu L, Christie G. J Mater Sci , 2005 . 40 ( 1 ): 111 - 116 . DOI:10.1007/s10853-005-5694-1http://doi.org/10.1007/s10853-005-5694-1 .

Yu L, Dean K, Li L. Prog Polym Sci , 2006 . 31 ( 6 ): 576 - 602 . DOI:10.1016/j.progpolymsci.2006.03.002http://doi.org/10.1016/j.progpolymsci.2006.03.002 .

Jiménez A, Fabra M J, Talens P. Food Bioprocess Technol , 2012 . 5 ( 6 ): 2058 - 2076 . DOI:10.1007/s11947-012-0835-4http://doi.org/10.1007/s11947-012-0835-4 .

Arvanitoyannis I, Nakayama A, Aiba S I. Carbohydr Polym , 1998 . 36 ( 2-3 ): 105 - 119 . DOI:10.1016/S0144-8617(98)00017-4http://doi.org/10.1016/S0144-8617(98)00017-4 .

Arvanitoyannis I S. Polym Rev , 1999 . C39 ( 2 ): 205 - 271 . DOI:10.1081/MC-100101420http://doi.org/10.1081/MC-100101420 .

Hughes T, Hoover R, Liu Q, Donner E, Chibbar R, Jaiswal S. Food Res Int , 2009 . 42 ( 5-6 ): 627 - 635 . DOI:10.1016/j.foodres.2009.01.008http://doi.org/10.1016/j.foodres.2009.01.008 .

Liu H, Xie F, Yu L, Chen L, Li L. Prog Polym Sci , 2009 . 34 ( 12 ): 1348 - 1368 . DOI:10.1016/j.progpolymsci.2009.07.001http://doi.org/10.1016/j.progpolymsci.2009.07.001 .

Chen P, Yu L, Chen L, Li X. Starch-Stärke , 2006 . 58 ( 12 ): 611 - 615 . DOI:10.1002/star.200500529http://doi.org/10.1002/star.200500529 .

Liu P, Chen L, Corrigan P A, Yu L, Liu Z. Int J Food Eng , 2008 . 4 ( 7 ): 8 DOI:10.2202/1556-3758.1510http://doi.org/10.2202/1556-3758.1510 .

Chen P, Yu L, Simon G, Petinakis E, Dean K, Chen L. J Cereal Sci , 2009 . 50 ( 2 ): 241 - 247 . DOI:10.1016/j.jcs.2009.06.001http://doi.org/10.1016/j.jcs.2009.06.001 .

Liu H, Yu L, Simon G, Zhang X, Dean K, Chen L. Carbohydr Res , 2009 . 344 ( 3 ): 350 - 354 . DOI:10.1016/j.carres.2008.11.014http://doi.org/10.1016/j.carres.2008.11.014 .

Liu H, Yu L, Simon G, Dean K, Chen L. Carbohydr Polym , 2009 . 77 ( 3 ): 662 - 669 . DOI:10.1016/j.carbpol.2009.02.010http://doi.org/10.1016/j.carbpol.2009.02.010 .

Chen P, Yu L, Simon G P, Liu X, Dean K, Chen L. Carbohydr Polym , 2011 . 83 ( 4 ): 1975 - 1983 . DOI:10.1016/j.carbpol.2010.11.001http://doi.org/10.1016/j.carbpol.2010.11.001 .

Atwell W. Cereal Foods World , 1988 . 33 ( 3 ): 306 - 311 . DOI:10.1002/btpr.5420040108http://doi.org/10.1002/btpr.5420040108 .

Lelievre J. J Appl Polym Sci , 1974 . 18 (1 ): 293 - 296 . DOI:10.1002/app.1974.070180124http://doi.org/10.1002/app.1974.070180124 .

Liu H, Yu L, Xie F, Chen L. Carbohydr Polym , 2006 . 65 ( 3 ): 357 - 363 . DOI:10.1016/j.carbpol.2006.01.026http://doi.org/10.1016/j.carbpol.2006.01.026 .

Chen P, Yu L, Kealy T, Chen L, Li L. Carbohydr Polym , 2007 . 68 ( 3 ): 495 - 501 . DOI:10.1016/j.carbpol.2006.11.002http://doi.org/10.1016/j.carbpol.2006.11.002 .

Liu X, Yu L, Liu H, Chen L, Li L. Polym Degrad Stabil , 2008 . 93 ( 1 ): 260 - 262 . DOI:10.1016/j.polymdegradstab.2007.09.004http://doi.org/10.1016/j.polymdegradstab.2007.09.004 .

Liu P, Yu L, Wang X, Li D, Chen L, Li X. J Cereal Sci , 2010 . 51 ( 3 ): 388 - 391 . DOI:10.1016/j.jcs.2010.02.007http://doi.org/10.1016/j.jcs.2010.02.007 .

Liu X, Yu L, Xie F, Li M, Chen L, Li X. Starch-Stärke , 2010 . 62 ( 3-4 ): 139 - 146 . DOI:10.1002/star.200900202http://doi.org/10.1002/star.200900202 .

Liu H, Li M, Chen P, Yu L, Chen L, Tong Z. Cereal Chem , 2010 . 87 ( 2 ): 144 - 149 . DOI:10.1094/CCHEM-87-2-0144http://doi.org/10.1094/CCHEM-87-2-0144 .

Lan C, Liu H, Chen P, Yu L, Chen L, Li X, Zhang X. Int J Food Eng , 2010 . 6 ( 4 ): 11 DOI:10.2202/1556-3758.1905http://doi.org/10.2202/1556-3758.1905 .

Qiao D, Yu L, Liu H, Zou W, Xie F, Simon G, Petinakis E, Shen Z, Chen L. Carbohydr Polym , 2016 . 144 271 - 281 . DOI:10.1016/j.carbpol.2016.02.064http://doi.org/10.1016/j.carbpol.2016.02.064 .

Sullivan J W, Johnson J A. Cereal Chem , 1964 . 41 ( 2 ): 73 - 77.

Liu X, Yu L, Liu H, Chen L, Li L. Cereal Chem , 2009 . 86 ( 4 ): 383 - 385 . DOI:10.1094/CCHEM-86-4-0383http://doi.org/10.1094/CCHEM-86-4-0383 .

Yu L, Christie G. Carbohydr Polym , 2001 . 46 ( 2 ): 179 - 184 . DOI:10.1016/S0144-8617(00)00301-5http://doi.org/10.1016/S0144-8617(00)00301-5 .

Liu H, Xie F, Chen L, Yu L, Dean K, Bateman S. Int J Food Eng , 2005 . 1 ( 1 ): 3 DOI:10.2202/1556-3758.1004http://doi.org/10.2202/1556-3758.1004 .

Liu H, Yu L, Chen L, Li L. Carbohydr Polym , 2007 . 69 ( 4 ): 756 - 762 . DOI:10.1016/j.carbpol.2007.02.011http://doi.org/10.1016/j.carbpol.2007.02.011 .

Liu P, Yu L, Liu H, Chen L, Li L. Carbohydr Polym , 2009 . 77 ( 2 ): 250 - 253 . DOI:10.1016/j.carbpol.2008.12.027http://doi.org/10.1016/j.carbpol.2008.12.027 .

Liu H, Yu L, Dean K, Simon G, Petinakis E, Chen L. Carbohydr Polym , 2009 . 75 ( 3 ): 395 - 400 . DOI:10.1016/j.carbpol.2008.07.034http://doi.org/10.1016/j.carbpol.2008.07.034 .

Xie F, Liu W C, Liu P, Wang J, Halley P J, Yu L. Starch-Stärke , 2010 . 62 ( 7 ): 350 - 357 . DOI:10.1002/star.200900258http://doi.org/10.1002/star.200900258 .

Liu H, Yu L, Tong Z, Chen L. Starch-Stärke , 2010 . 62 ( 10 ): 524 - 529 . DOI:10.1002/star.201000017http://doi.org/10.1002/star.201000017 .

Xie F, Liu H, Chen P, Xue T, Chen L, Yu L, Corrigan P. Int J Food Eng , 2007 . 2 ( 5 ): 6 DOI:10.2202/1556-3758.1162http://doi.org/10.2202/1556-3758.1162 .

Xie F, Yu L, Chen L, Li L. Carbohydr Polym , 2008 . 72 ( 2 ): 229 - 234 . DOI:10.1016/j.carbpol.2007.08.007http://doi.org/10.1016/j.carbpol.2007.08.007 .

Xue T, Yu L, Xie F, Chen L, Li L. Food Hydrocolloids , 2008 . 22 ( 6 ): 973 - 978 . DOI:10.1016/j.foodhyd.2007.05.008http://doi.org/10.1016/j.foodhyd.2007.05.008 .

Su B, Xie F, Li M, Corrigan P A, Yu L, Li X, Chen L. Int J Food Eng , 2009 . 5 ( 1 ): 7 DOI:10.2202/1556-3758.1617http://doi.org/10.2202/1556-3758.1617 .

Xie F, Yu L, Su B, Liu P, Wang J, Liu H, Chen L. J Cereal Sci , 2009 . 49 ( 3 ): 371 - 377 . DOI:10.1016/j.jcs.2009.01.002http://doi.org/10.1016/j.jcs.2009.01.002 .

Wang J, Yu L, Xie F, Chen L, Li X, Liu H. Starch-Stärke , 2010 . 62 ( 12 ): 667 - 675 . DOI:10.1002/star.201000059http://doi.org/10.1002/star.201000059 .

Li M, Liu P, Zou W, Yu L, Xie F, Pu H, Liu H, Chen L. J Food Eng , 2011 . 106 ( 1 ): 95 - 101 . DOI:10.1016/j.jfoodeng.2011.04.021http://doi.org/10.1016/j.jfoodeng.2011.04.021 .

Liu X, Wang Y, Yu L, Tong Z, Chen L, Liu H, Li X. Starch-Stärke , 2013 . 65 ( 1-2 ): 48 - 60 . DOI:10.1002/star.201200198http://doi.org/10.1002/star.201200198 .

Liu X, Ma H, Yu L, Chen L, Tong Z, Chen P. J Therm Anal Calorim , 2014 . 115 ( 1 ): 659 - 665 . DOI:10.1007/s10973-013-3354-2http://doi.org/10.1007/s10973-013-3354-2 .

Olkku J, Rha C. Food Chem , 1978 . 3 ( 4 ): 293 - 317 . DOI:10.1016/0308-8146(78)90037-7http://doi.org/10.1016/0308-8146(78)90037-7 .

Lim M H, Wu H, Reid D S. J Sci Food Agric , 2000 . 80 ( 12 ): 1757 - 1762 . DOI:10.1002/1097-0010(20000915)80:12<1757::AID-JSFA703>3.0.CO;2-Yhttp://doi.org/10.1002/1097-0010(20000915)80:12<1757::AID-JSFA703>3.0.CO;2-Y .

Liao Lisha(廖丽莎), Liu Hongsheng(刘宏生), Liu Xingxun(刘兴训), Chen Ling(陈玲), Yu Long(余龙), Chen Pei(陈佩). Acta Polymerica Sinica(高分子学报) , 2014 . ( 6 ): 761 - 773 . DOI:10.3724/SP.J.1105.2014.13450http://doi.org/10.3724/SP.J.1105.2014.13450 .

Tester R F, Debon S J. Int J Biol Macromol , 2000 . 27 ( 1 ): 1 - 12 . DOI:10.1016/S0141-8130(99)00121-Xhttp://doi.org/10.1016/S0141-8130(99)00121-X .

Burros B C, Young L A, Carroad P A. J Food Sci , 1987 . 52 ( 5 ): 1372 - 1376 . DOI:10.1111/j.1365-2621.1987.tb14085.xhttp://doi.org/10.1111/j.1365-2621.1987.tb14085.x .

Wen L F, Rodis P, Wasserman B. Cereal Chem , 1990 . 67 ( 3 ): 268 - 275.

Lai L, Kokini J. Biotechnol Prog , 1991 . 7 ( 3 ): 251 - 266 . DOI:10.1021/bp00009a009http://doi.org/10.1021/bp00009a009 .

Colonna P, Doublier J, Melcion J, de Monredon F, Mercier C. Cereal Chem , 1984 . 61 ( 6 ): 538 - 543.

Davidson V, Paton D, Diosady L, Larocque G. J Food Sci , 1984 . 49 ( 2 ): 453 - 458 . DOI:10.1111/j.1365-2621.1984.tb12441.xhttp://doi.org/10.1111/j.1365-2621.1984.tb12441.x .

Willett J, Millard M, Jasberg B. Polymer , 1997 . 38 ( 24 ): 5983 - 5989 . DOI:10.1016/S0032-3861(97)00155-9http://doi.org/10.1016/S0032-3861(97)00155-9 .

Carvalho A J F, Zambon M D, Curvelo A AS, Gandini A. Polym Degrad Stabil , 2003 . 79 ( 1 ): 133 - 138 . DOI:10.1016/S0141-3910(02)00265-3http://doi.org/10.1016/S0141-3910(02)00265-3 .

Baltá Calleja F, Rueda D, Secall T, Bayer R, Schlimmer M. J Macromol Sci Part B-Phys , 1999 . 38 ( 4 ): 461 - 469 . DOI:10.1080/00222349908212444http://doi.org/10.1080/00222349908212444 .

Xie F, Yu L, Liu H, Chen L. Starch-Stärke , 2006 . 58 ( 3-4 ): 131 - 139 . DOI:10.1002/star.200500407http://doi.org/10.1002/star.200500407 .

Moad G. Prog Polym Sci , 2011 . 36 ( 2 ): 218 - 237 . DOI:10.1016/j.progpolymsci.2010.11.002http://doi.org/10.1016/j.progpolymsci.2010.11.002 .

Qiao D, Zou W, Liu X, Yu L, Chen L, Liu H, Zhang N. Starch-Stärke , 2012 . 64 ( 10 ): 821 - 825 . DOI:10.1002/star.201200044http://doi.org/10.1002/star.201200044 .

Qiao D, Ma H, Yu L, Liu H, Zou W, Chen L, Chen P. Int Polym Process , 2014 . 29 ( 2 ): 252 - 259 . DOI:10.3139/217.2847http://doi.org/10.3139/217.2847 .

Qiao D, Bao X, Liu H, Liu X, Chen L, Yu L, Zhang X, Chen P. Chinese J Polym Sci , 2014 . 32 ( 10 ): 1348 - 1356 . DOI:10.1007/s10118-014-1516-8http://doi.org/10.1007/s10118-014-1516-8 .

Bao X, Yu L, Shen S, Simon G P, Liu H, Chen L. Carbohydr Polym , 2019 . 219 395 - 404 . DOI:10.1016/j.carbpol.2019.05.034http://doi.org/10.1016/j.carbpol.2019.05.034 .

Bao X, Yu L, Simon G P, Shen S, Xie F, Liu H, Chen L, Zhong L. Carbohydr Polym , 2018 . 192 1 - 9 . DOI:10.1016/j.carbpol.2018.03.040http://doi.org/10.1016/j.carbpol.2018.03.040 .

Dufresne A, Dupeyre D, Vignon M R. J Appl Polym Sci , 2000 . 76 ( 14 ): 2080 - 2092 . DOI:10.1002/(SICI)1097-4628(20000628)76:14<2080::AID-APP12>3.0.CO;2-Uhttp://doi.org/10.1002/(SICI)1097-4628(20000628)76:14<2080::AID-APP12>3.0.CO;2-U .

Wollerdorfer M, Bader H. Ind Crop Prod , 1998 . 8 ( 2 ): 105 - 112 . DOI:10.1016/S0926-6690(97)10015-2http://doi.org/10.1016/S0926-6690(97)10015-2 .

Ali A, Yu L, Liu H, Khalid S, Meng L, Chen L. J Appl Polym Sci , 2017 . 134 ( 32 ): 45159 DOI:10.1002/app.45159http://doi.org/10.1002/app.45159 .

Mendes C, Adnet F, Leite M, Furtado C G, Sousa A. Cell Chem Technol , 2015 . 49 ( 9-10 ): 727 - 735.

Chen Y, Yu L, Ge X, Liu H, Ali A, Wang Y, Chen L. Int J Biol Macromol , 2019 . 129 944 - 951 . DOI:10.1016/j.ijbiomac.2019.02.045http://doi.org/10.1016/j.ijbiomac.2019.02.045 .

Arvanitoyannis I, Kalichevsky M, Blanshard J M, Psomiadou E. Carbohydr Polym , 1994 . 24 ( 1 ): 1 - 15 . DOI:10.1016/0144-8617(94)90111-2http://doi.org/10.1016/0144-8617(94)90111-2 .

Arvanitoyannis I, Psomiadou E, Nakayama A, Aiba S, Yamamoto N. Food Chem , 1997 . 60 ( 4 ): 593 - 604 . DOI:10.1016/S0308-8146(97)00038-1http://doi.org/10.1016/S0308-8146(97)00038-1 .

Zhang N, Liu H, Yu L, Liu X, Zhang L, Chen L, Shanks R. Carbohydr Polym , 2013 . 92 ( 1 ): 455 - 461 . DOI:10.1016/j.carbpol.2012.09.048http://doi.org/10.1016/j.carbpol.2012.09.048 .

Zhang N, Liu X, Yu L, Shanks R, Petinaks E, Liu H. Carbohydr Polym , 2013 . 95 ( 2 ): 649 - 653 . DOI:10.1016/j.carbpol.2013.03.045http://doi.org/10.1016/j.carbpol.2013.03.045 .

Zhang N, Shanks R, Liu X, Yu L. Adv Mater Res , 2014 . 106 - 109.

Zhang Liang(张良), Wang Yanfei(王燕斐), Liu Hongsheng(刘宏生), Zhang Nuozi(张诺滋), Liu Xingxun(刘兴训), Chen Ling(陈玲), Yu Long(余龙). Acta Polym Sinica(高分子学报) , 2013 . ( 1 ): 1 - 10.

Zhang L, Wang Y, Liu H, Yu L, Liu X, Chen L, Zhang N. Carbohydr Polym , 2013 . 98 ( 1 ): 73 - 79 . DOI:10.1016/j.carbpol.2013.05.070http://doi.org/10.1016/j.carbpol.2013.05.070 .

Liu X, Wang Y, Zhang N, Shanks R A, Liu H, Tong Z, Chen L, Yu L. Chinese J Polym Sci , 2014 . 32 ( 1 ): 108 - 114 . DOI:10.1007/s10118-014-1377-1http://doi.org/10.1007/s10118-014-1377-1 .

Ali A, Chen Y, Liu H, Yu L, Baloch Z, Khalid S, Zhu J, Chen L. Int J Biol Macromol , 2019 . 129 1120 - 1126 . DOI:10.1016/j.ijbiomac.2018.09.068http://doi.org/10.1016/j.ijbiomac.2018.09.068 .

Xie F, Pollet E, Halley P J, Avérous L. Prog Polym Sci , 2013 . 38 ( 10-11 ): 1590 - 1628 . DOI:10.1016/j.progpolymsci.2013.05.002http://doi.org/10.1016/j.progpolymsci.2013.05.002 .

Chivrac F, Angellier-Coussy H, Guillard V, Pollet E, Avérous L. Carbohydr Polym , 2010 . 82 ( 1 ): 128 - 135 . DOI:10.1016/j.carbpol.2010.04.036http://doi.org/10.1016/j.carbpol.2010.04.036 .

Chivrac F, Gueguen O, Pollet E, Ahzi S, Makradi A, Averous L. Acta Biomater , 2008 . 4 ( 6 ): 1707 - 1714 . DOI:10.1016/j.actbio.2008.05.002http://doi.org/10.1016/j.actbio.2008.05.002 .

Chivrac F, Pollet E, Averous L. Mat Sci Eng R , 2009 . 67 ( 1 ): 1 - 17 . DOI:10.1016/j.mser.2009.09.002http://doi.org/10.1016/j.mser.2009.09.002 .

Dean K, Yu L. Biodegradable Polymers. Cambridge: Woodhead, 2005. 289 – 309

Dean K, Yu L, Wu D Y. Compos Sci Technol , 2007 . 67 ( 3-4 ): 413 - 421 . DOI:10.1016/j.compscitech.2006.09.003http://doi.org/10.1016/j.compscitech.2006.09.003 .

Dean K M, Do M D, Petinakis E, Yu L. Compos Sci Technol , 2008 . 68 ( 6 ): 1453 - 1462 . DOI:10.1016/j.compscitech.2007.10.037http://doi.org/10.1016/j.compscitech.2007.10.037 .

Dean K M, Petinakis E, Goodall L, Miller T, Yu L, Wright N. Carbohydr Polym , 2011 . 86 ( 2 ): 652 - 658 . DOI:10.1016/j.carbpol.2011.05.003http://doi.org/10.1016/j.carbpol.2011.05.003 .

Duan Q, Jiang T, Xue C, Liu H, Liu F, Alee M, Ali A, Chen L, Yu L. Int J Biol Macromol , 2020 . 150 16 - 22 . DOI:10.1016/j.ijbiomac.2020.01.283http://doi.org/10.1016/j.ijbiomac.2020.01.283 .

Teixeira E d M, Pasquini D, Curvelo A A, Corradini E, Belgacem M N, Dufresne A. Carbohydr Polym , 2009 . 78 ( 3 ): 422 - 431 . DOI:10.1016/j.carbpol.2009.04.034http://doi.org/10.1016/j.carbpol.2009.04.034 .

Robles E, Salaberria A M, Herrera R, Fernandes S C, Labidi J. Carbohydr Polym , 2016 . 144 41 - 49 . DOI:10.1016/j.carbpol.2016.02.024http://doi.org/10.1016/j.carbpol.2016.02.024 .

Liu D, Zhong T, Chang P R, Li K, Wu Q. Bioresour Technol , 2010 . 101 ( 7 ): 2529 - 2536 . DOI:10.1016/j.biortech.2009.11.058http://doi.org/10.1016/j.biortech.2009.11.058 .

Roohani M, Habibi Y, Belgacem N M, Ebrahim G, Karimi A N, Dufresne A. Eur Polym J , 2008 . 44 ( 8 ): 2489 - 2498 . DOI:10.1016/j.eurpolymj.2008.05.024http://doi.org/10.1016/j.eurpolymj.2008.05.024 .

Soykeabkaew N, Laosat N, Ngaokla A, Yodsuwan N, Tunkasiri T. Compos Sci Technol , 2012 . 72 ( 7 ): 845 - 852 . DOI:10.1016/j.compscitech.2012.02.015http://doi.org/10.1016/j.compscitech.2012.02.015 .

Alves J, Dos Reis K, Menezes E, Pereira F, Pereira J. Carbohydr Polym , 2015 . 115 215 - 222 . DOI:10.1016/j.carbpol.2014.08.057http://doi.org/10.1016/j.carbpol.2014.08.057 .

El Miri N, Abdelouahdi K, Barakat A, Zahouily M, Fihri A, Solhy A, El Achaby M. Carbohydr Polym , 2015 . 129 156 - 167 . DOI:10.1016/j.carbpol.2015.04.051http://doi.org/10.1016/j.carbpol.2015.04.051 .

Li X, Qiu C, Ji N, Sun C, Xiong L, Sun Q. Carbohydr Polym , 2015 . 121 155 - 162 . DOI:10.1016/j.carbpol.2014.12.040http://doi.org/10.1016/j.carbpol.2014.12.040 .

Li M, Li D, Wang L-j, Adhikari B. Carbohydr Polym , 2015 . 117 957 - 963 . DOI:10.1016/j.carbpol.2014.10.023http://doi.org/10.1016/j.carbpol.2014.10.023 .

Panaitescu D M, Frone A N, Ghiurea M, Chiulan I. Ind Crop Prod , 2015 . 70 170 - 177 . DOI:10.1016/j.indcrop.2015.03.028http://doi.org/10.1016/j.indcrop.2015.03.028 .

Ali A, Xie F, Yu L, Liu H, Meng L, Khalid S, Chen L. Compos Pt B-Eng , 2018 . 133 122 - 128 . DOI:10.1016/j.compositesb.2017.09.017http://doi.org/10.1016/j.compositesb.2017.09.017 .

Amer M S, Ganapathiraju S. J Appl Polym Sci , 2001 . 81 ( 5 ): 1136 - 1141 . DOI:10.1002/app.1536http://doi.org/10.1002/app.1536 .

Hine P, Olley R, Ward I. Compos Sci Technol , 2008 . 68 ( 6 ): 1413 - 1421 . DOI:10.1016/j.compscitech.2007.11.003http://doi.org/10.1016/j.compscitech.2007.11.003 .

Manninen M, Päivärinta U, Pätiälä H, Rokkanen P, Taurio R, Tamminmäki M, Törmälä P. J Mater Sci-Mater Med , 1992 . 3 ( 4 ): 245 - 251 . DOI:10.1007/BF00705288http://doi.org/10.1007/BF00705288 .

Suuronen R, Wessman L, Mero M, Törmälä P, Vasenius J, Partio E, Vihtonen K, Vainionpää, S. J Mater Sci-Mater Med , 1992 . 3 ( 4 ): 288 - 292 . DOI:10.1007/BF00705295http://doi.org/10.1007/BF00705295 .

Gao C, Yu L, Liu H, Chen L. Prog Polym Sc , 2012 . 37 ( 6 ): 767 - 780 . DOI:10.1016/j.progpolymsci.2011.09.005http://doi.org/10.1016/j.progpolymsci.2011.09.005 .

Gao C, Meng L, Yu L, Simon G P, Liu H, Chen L, Petinakis S. Compos Sci Technol , 2015 . 117 392 - 397 . DOI:10.1016/j.compscitech.2015.07.006http://doi.org/10.1016/j.compscitech.2015.07.006 .

Lan C, Yu L, Chen P, Chen L, Simon G, Zhang X. Macro Mater Eng , 2010 . 295 ( 11 ): 1025 - 1030 . DOI:10.1002/mame.201000186http://doi.org/10.1002/mame.201000186 .

Stading M, Hermansson A M, Gatenholm P. Carbohydr Polym , 1998 . 36 ( 2-3 ): 217 - 224 . DOI:10.1016/S0144-8617(98)00025-3http://doi.org/10.1016/S0144-8617(98)00025-3 .

Bie P, Liu P, Yu L, Li X, Chen L, Xie F. Carbohydr Polym , 2013 . 98 ( 1 ): 959 - 966 . DOI:10.1016/j.carbpol.2013.07.004http://doi.org/10.1016/j.carbpol.2013.07.004 .

Prasad S, Gupta S C, Tyagi A K, Aggarwal B B. Biotechnol Adv , 2014 . 32 ( 6 ): 1053 - 1064 . DOI:10.1016/j.biotechadv.2014.04.004http://doi.org/10.1016/j.biotechadv.2014.04.004 .

Vásconez M B, Flores S K, Campos C A, Alvarado J, Gerschenson L N. Food Res Int , 2009 . 42 ( 7 ): 762 - 769 . DOI:10.1016/j.foodres.2009.02.026http://doi.org/10.1016/j.foodres.2009.02.026 .

Hayrapetyan H, Hazeleger W C, Beumer R R. Food Control , 2012 . 23 ( 1 ): 66 - 72 . DOI:10.1016/j.foodcont.2011.06.012http://doi.org/10.1016/j.foodcont.2011.06.012 .

Khalid S, Yu L, Feng M, Meng L, Bai Y, Ali A, Liu H, Chen L. Food Packag Shelf Life , 2018 . 18 71 - 79 . DOI:10.1016/j.fpsl.2018.08.008http://doi.org/10.1016/j.fpsl.2018.08.008 .

Xie F, Yu L, Liu H, Dean K. Int Polym Process , 2006 . 21 ( 4 ): 379 - 385 . DOI:10.3139/217.0119http://doi.org/10.3139/217.0119 .

Yu L, Dean K, Yuan Q, Chen L, Zhang X. J Appl Polym Sci , 2007 . 103 ( 2 ): 812 - 818 . DOI:10.1002/app.25184http://doi.org/10.1002/app.25184 .

Dean K, Yu L, Bateman S, Wu D Y. J Appl Polym Sci , 2007 . 103 ( 2 ): 802 - 811 . DOI:10.1002/app.25149http://doi.org/10.1002/app.25149 .

Petinakis E, Liu X, Yu L, Way C, Sangwan P, Dean K, Bateman S, Edward G. Polym Degrad Stabil , 2010 . 95 ( 9 ): 1704 - 1707 . DOI:10.1016/j.polymdegradstab.2010.05.027http://doi.org/10.1016/j.polymdegradstab.2010.05.027 .

Liu X, Khor S, Petinakis E, Yu L, Simon G, Dean K, Bateman S. Thermochim Acta , 2010 . 509 ( 1-2 ): 147 - 151 . DOI:10.1016/j.tca.2010.06.015http://doi.org/10.1016/j.tca.2010.06.015 .

Yu L, Petinakis E, Dean K, Liu H, Yuan Q. J Appl Polym Sci , 2011 . 119 ( 4 ): 2189 - 2195 . DOI:10.1002/app.32949http://doi.org/10.1002/app.32949 .

Olsson E, Menzel C, Johansson C, Andersson R, Koch K, Järnström L. Carbohydr Polym , 2013 . 98 ( 2 ): 1505 - 1513 . DOI:10.1016/j.carbpol.2013.07.040http://doi.org/10.1016/j.carbpol.2013.07.040 .

Reddy N, Yang Y. Food Chem , 2010 . 118 ( 3 ): 702 - 711 . DOI:10.1016/j.foodchem.2009.05.050http://doi.org/10.1016/j.foodchem.2009.05.050 .

Sreedhar B, Chattopadhyay D, Karunakar M S H, Sastry A. J Appl Polym Sci , 2006 . 101 ( 1 ): 25 - 34 . DOI:10.1002/app.23145http://doi.org/10.1002/app.23145 .

Šimkovic I, Hricovini M, Mendichi R, van Soest J J. Carbohydr Polym , 2004 . 55 ( 3 ): 299 - 305 . DOI:10.1016/j.carbpol.2003.10.002http://doi.org/10.1016/j.carbpol.2003.10.002 .

Hirsch J B, Kokini J L. Cereal Chem , 2002 . 79 ( 1 ): 102 - 107 . DOI:10.1094/CCHEM.2002.79.1.102http://doi.org/10.1094/CCHEM.2002.79.1.102 .

Zhou J, Zhang J, Ma Y, Tong J. Carbohydr Polym , 2008 . 74 ( 3 ): 405 - 410 . DOI:10.1016/j.carbpol.2008.03.006http://doi.org/10.1016/j.carbpol.2008.03.006 .

Ge X, Yu L, Liu Z, Liu H, Chen Y, Chen L. Int J Biol Macromol , 2019 . 125 370 - 375 . DOI:10.1016/j.ijbiomac.2018.11.239http://doi.org/10.1016/j.ijbiomac.2018.11.239 .

Meng L, Li S, Yang W, Simons R, Yu L, Liu H, Chen L. ACS Sustain Chem Eng , 2019 . 7 ( 10 ): 9506 - 9514 . DOI:10.1021/acssuschemeng.9b00909http://doi.org/10.1021/acssuschemeng.9b00909 .

Meng L, Liu H, Yu L, Duan Q, Chen L, Liu F, Shao Z, Shi K, Lin X. Ind Crop Prod , 2019 . 134 43 - 49 . DOI:10.1016/j.indcrop.2019.03.056http://doi.org/10.1016/j.indcrop.2019.03.056 .

Duan Q, Meng L, Liu H, Yu L, Lu K, Khalid S, Chen L. J Polym Environ , 2019 . 27 ( 1 ): 158 - 164 . DOI:10.1007/s10924-018-1323-3http://doi.org/10.1007/s10924-018-1323-3 .

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