聚芳醚酮可纺性和结构优化的研究进展

董大林; 宾月珍; 蹇锡高

doi:10.11777/j.issn1000-3304.2020.20130

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聚芳醚酮可纺性和结构优化的研究进展

综述 | 更新时间：2021-01-26

- 聚芳醚酮可纺性和结构优化的研究进展
- Research Progress of Poly(aryl ether ketone) on Spinnability and Structure Optimization
- 高分子学报 2020年51卷第12期页码：1321-1334
- 作者机构：
  
  1. 大连理工大学高分子材料系
  2. 辽宁省高性能树脂工程技术研究中心　大连 116024
- 作者简介：
  
  [ "宾月珍，女，1966年生，大连理工大学化工学院教授，博士生导师. 2000年于日本国立奈良女子大学取得理学博士学位， 2000 ~ 2001年日本学术振兴会博士后，2001 ~ 2006年奈良女子大学留校进行研究工作，期间赴美国国家标准与技术研究院(NIST)进行访学交流，2006年至今担任大连理工大学高分子材料系教授，主要从事高分子聚集态结构、高性能纤维、高分子/碳纳米复合材料方面的研究工作，已发表论文100余篇" ]
- 基金信息：
  
  国家自然科学基金(基金号 21374014，U1663226)资助项目
- DOI：10.11777/j.issn1000-3304.2020.20130
  中图分类号：
- 纸质出版日期：2020-10-21，
  
  网络出版日期：2020-9-2，
  
  收稿日期：2020-5-22，
  
  修回日期：2020-7-11，
扫描看全文
董大林, 宾月珍, 蹇锡高. 聚芳醚酮可纺性和结构优化的研究进展[J]. 高分子学报, 2020,51(12):1321-1334.

Da-lin Dong, Yue-zhen Bin, Xi-gao Jian. Research Progress of Poly(aryl ether ketone) on Spinnability and Structure Optimization[J]. Acta Polymerica Sinica, 2020,51(12):1321-1334.
董大林, 宾月珍, 蹇锡高. 聚芳醚酮可纺性和结构优化的研究进展[J]. 高分子学报, 2020,51(12):1321-1334. DOI： 10.11777/j.issn1000-3304.2020.20130.

Da-lin Dong, Yue-zhen Bin, Xi-gao Jian. Research Progress of Poly(aryl ether ketone) on Spinnability and Structure Optimization[J]. Acta Polymerica Sinica, 2020,51(12):1321-1334. DOI： 10.11777/j.issn1000-3304.2020.20130.

摘要

聚芳醚酮作为特种工程塑料，具有优异的耐热性、耐候性、耐溶剂性以及机械强度高等特点. 本文综述了无定型聚芳醚酮以及结晶型聚芳醚酮纤维制备的研究现状以及基于可纺性的聚合物结构优化的研究进展. 在物理改性方面，通过将聚芳醚酮与无机润滑剂、热致液晶聚酯以及热致液晶聚芳醚酮共混，聚合物合金的加工性能以及聚合物纤维的机械性能均得到提升. 在化学改性方面，通过磺化、氯甲基化、开环聚合、多元共聚、液晶基元的引入、不同侧基的引入、扭曲非共平面结构的引入以及热致液晶聚酯的引入等手段，聚合物的加工手段得到丰富，聚合物的溶解能力以及聚合物纳米纤维膜的离子传导能力得到提升. 借助化学改性，聚芳醚酮纳米纤维膜在燃料电池离子交换膜等新兴领域的应用得到拓展. 在相应领域，无定型聚芳醚酮以及结晶型聚芳醚酮的结构与性能仍有较大的提升潜力.

Abstract

As a kind of special engineering plastics

poly(aryl ether ketone) has excellent comprehensive properties

making poly(aryl ather ketone) have broad application prospects in many fields. Research progress of poly(aryl ether ketone) fibers and structure optimization of poly(aryl ether ketone) on spinnability are introduced from amorphous poly(aryl ether ketone) and crystalline poly(aryl ether ketone). There are some differences in solubility

processing methods

aggregation structure and application fields between amorphous poly(aryl ether ketone) and crystalline poly(aryl ether ketone) fibers. At present

more studies have been done on crystalline poly(aryl ether ketone) fibers than on amorphous poly(aryl ether ketone) fibers. In terms of physical modification

poly(aryl ether ketone) blends with inorganic lubricants

thermotropic liquid crystalline polyester and thermotropic liquid crystalline poly(aryl ether ketone). Processability of the blend and mechanical properties of the fibers are improved significantly. In terms of chemical modification

poly(aryl ether ketone) is modified by sulfonation

chloromethylation

ring opening polymerization

multicomponent copolymerization

introduction of mesogenic units or different side groups

introduction of twisted non-coplanar structure and introduction of thermotropic liquid crystalline polyester. Processing methods of poly(aryl ether ketone) are expanded and the solubility of poly(aryl ether ketone) is improved. Ionic conductivity of poly(aryl ether ketone) nanofiber membrane is also improved. Blending with inorganic lubricant

blending with thermotropic liquid crystalline polyester

blending with thermotropic liquid crystalline poly(aryl ether ketone)

sulfonation

introduction of different side groups and introduction of twisted non coplanar structure play an important role in crystalline poly(aryl ether ketone). While

chloromethylation

ring opening polymerization

multicomponent copolymerization and introduction of thermotropic liquid crystalline polyester play an important role in amorphous poly(aryl ether ketone). By chemical modification

the application of poly(aryl ether ketone) nanofiber membrane in ion-exchange membrane of fuel cell and many other promising fields are expanded. In corresponding fields

the structure and properties of amorphous and crystalline poly(aryl ether ketone) still have great potential for improvement. Hope this paper could provide reference for the other researchers.

关键词

聚芳醚酮纤维聚合物结构设计液晶相后功能化

Keywords

Poly(aryl ether ketone)FibersStructural optimization of polymerLiquid crystal phasePost functionalization

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