共轭聚合物水凝胶的制备与应用进展

余明清; 廖耀祖; 朱美芳

doi:10.11777/j.issn1000-3304.2020.20186

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共轭聚合物水凝胶的制备与应用进展

综述 | 更新时间：2021-01-26

- 共轭聚合物水凝胶的制备与应用进展
- Progress in Preparation and Applications of Conjugated Polymer Hydrogels
- 高分子学报 2021年52卷第2期页码：113-123
- 作者机构：
  
  东华大学材料科学与工程学院纤维材料改性国家重点实验室　上海 201600
- 作者简介：
  
  [ "廖耀祖，男，1982年生. 东华大学纤维材料改性国家重点实验室、材料科学与工程学院教授/博士生导师，先后在美国加州大学洛杉矶分校、英国布里斯托大学、德国柏林工业大学学习工作6年时间. 入选上海市曙光学者、上海市浦江学者、德国洪堡学者以及欧洲玛丽居里学者奖励计划等. 主要从事共轭聚合物及其框架材料的精准制备与传感检测、吸附分离、清洁能源开发等基础应用研究" ]
- 基金信息：
  
  国家自然科学基金 (基金号 51873036，51673039) 资助项目()
- DOI：10.11777/j.issn1000-3304.2020.20186
  中图分类号：
- 纸质出版日期：2021-2-3，
  
  网络出版日期：2020-9-24，
  
  收稿日期：2020-8-7，
  
  修回日期：2020-8-29，
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余明清, 廖耀祖, 朱美芳. 共轭聚合物水凝胶的制备与应用进展[J]. 高分子学报, 2021,52(2):113-123.

Ming-qing Yu, Yao-zu Liao, Mei-fang Zhu. Progress in Preparation and Applications of Conjugated Polymer Hydrogels[J]. Acta Polymerica Sinica, 2021,52(2):113-123.
余明清, 廖耀祖, 朱美芳. 共轭聚合物水凝胶的制备与应用进展[J]. 高分子学报, 2021,52(2):113-123. DOI： 10.11777/j.issn1000-3304.2020.20186.

Ming-qing Yu, Yao-zu Liao, Mei-fang Zhu. Progress in Preparation and Applications of Conjugated Polymer Hydrogels[J]. Acta Polymerica Sinica, 2021,52(2):113-123. DOI： 10.11777/j.issn1000-3304.2020.20186.

摘要

共轭聚合物水凝胶是利用共轭聚合物制备的水凝胶材料，兼备水凝胶的力学性质、溶胀性质和共轭聚合物优异的电化学特性. 共轭聚合物水凝胶的制备方法多样，主要有原位聚合、直接填充、物理交联和化学交联等. 同时，在面对环境和能源领域的应用挑战时，共轭聚合物水凝胶具备良好的发展潜能，可广泛应用于药物释放、能量转换、能量储存、传感器、组织损伤修复和污水处理等诸多领域. 本文系统归纳了共轭聚合物水凝胶的制备方法和应用，对其研究目前存在的主要问题以及未来发展方向进行了分析.

Abstract

Polymer hydrogels are cross-linked polymeric materials with three-dimensional networks that can maintain 1000%−2000% of deformation under certain stress. Conjugated polymer hydrogels (CPHs) are the hydrogels made from conjugated polymers. From the point of view of molecular structure

CPHs exhibit an inherent rigidity and extended

bond of conjugated polymers

which can synergize the advantages of organic semiconductors and hydrogel networks. By means of physical and chemical doping

CPHs also display adjustable electroconductive properties. Therefore

CPHs combine the good mechanical properties

swelling properties of hydrogels and the excellent electrochemical properties of conjugated polymers. A diversity of methods have been applied to prepare CPHs. Owing to their unique properties mentioned

CPHs have been widely used in many fields such as drug release

energy conversion

energy storage

sensors

tissue damage repair and sewage treatment. Over decades

various new types of CPHs have been successfully synthesized

and their water absorption capacity

electrical conductivity and other properties have been continuously optimized. At present

CPHs are mainly prepared through

in situ

polymerization

direct filling

physical crosslinking and chemical crosslinking

etc

. Chemical modifications and functionalization are also applied to adjust the properties of CPHs

which amplify their functionalities and applications. In this review

the preparation methods and applications of CPHs are systematically summarized

and the main issues existing in this research and the future development direction are analyzed.

关键词

共轭聚合物水凝胶功能聚合物制备方法功能应用

Keywords

Conjugated polymer hydrogelsFunctional polymersPreparation methodsFunctional applications

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