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1.中国海洋大学材料科学与工程学院 青岛 266100
2.青岛市储能产业技术研究院 中国科学院青岛生物能源与过程研究所 青岛 266101
[ "张焕瑞,男,1987年生. 中国科学院青岛生物能源与过程研究所助理研究员. 2015年大连理工大学应用化学专业博士毕业,2017年起于中国科学院青岛生物能源与过程研究所工作. 主要从事锂离子电池聚合物电解质和粘结剂的研究" ]
[ "柳伟,男,1977年生. 中国海洋大学材料科学与工程学院教授,博士生导师. 2005年毕业于中国科学院上海硅酸盐研究所,获工学博士学位,2005~2006年,在德国马普协会固态物理化学所从事博士后研究. 2006年起于中国海洋大学材材料科学与工程学院任教. 主要从事生物质碳基复合材料和储能材料等先进功能材料的制备与功能化应用研究,主持包括国家自然科学基金面上项目等在内的项目9项" ]
[ "崔光磊,男,1973年生. 中国科学院青岛生物能源与过程研究所研究员,博士生导师. 2005年于中国科学院化学所获得有机化学博士学位,2005年9月~2009年2月先后在德国马普协会高分子所和固态所从事博士后研究. 2009年2月起于中科院青岛生物能源与过程所工作. 2009年入选中国科学院“百人计划”(终期评估优秀),2009年获山东省自然科学杰出青年基金资助,2015年入选山东省“泰山学者特聘专家”,2016年获国家自然科学杰出青年基金资助. 主要从事低成本高效能源储存与转换器件的研究,作为负责人和主要参与者承担国家自然科学杰出青年基金、国家973计划、863计划、国家自然科学基金面上项目、省部级及中科院先导专项、企业横向项目等多项科研项目" ]
纸质出版日期:2021-3-3,
网络出版日期:2020-12-14,
收稿日期:2020-9-2,
修回日期:2020-10-2,
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刘智, 董甜甜, 张焕瑞, 柳伟, 崔光磊. 锂离子电池高电压正极粘结剂的研究进展[J]. 高分子学报, 2021,52(3):235-252.
Zhi Liu, Tian-tian Dong, Huan-rui Zhang, Wei Liu, Guang-lei Cui. Advances of High-voltage Cathode Binders for Lithium Ion Batteries[J]. Acta Polymerica Sinica, 2021,52(3):235-252.
刘智, 董甜甜, 张焕瑞, 柳伟, 崔光磊. 锂离子电池高电压正极粘结剂的研究进展[J]. 高分子学报, 2021,52(3):235-252. DOI: 10.11777/j.issn1000-3304.2020.20207.
Zhi Liu, Tian-tian Dong, Huan-rui Zhang, Wei Liu, Guang-lei Cui. Advances of High-voltage Cathode Binders for Lithium Ion Batteries[J]. Acta Polymerica Sinica, 2021,52(3):235-252. DOI: 10.11777/j.issn1000-3304.2020.20207.
锂离子电池在高电压下会导致严重的电解液分解以及不稳定的正极与电解质界面问题,严重制约高电压正极材料的商业化. 粘结剂不仅可以将正极活性材料和导电炭紧密粘结在集流体上,还对构建电解质与正极之间的多尺度相容性界面起积极作用,因此,粘结剂的优化可以有效解决上述难题. 本文提出了高电压锂离子电池正极粘结剂需具备的必要条件,如:粘结性能和机械性能优异,具有出色的电化学稳定性和热力学稳定性以及良好的离子和电子传输能力等. 综述了近些年来高电压正极粘结剂的研究及发展现状,通过天然粘结剂和合成粘结剂对目前已报道的高电压粘结剂进行了评述,介绍了各种粘结剂对电极的粘结性能和包覆以及对锂离子电池性能的影响机制,重点阐述了粘结剂分子结构中的极性基团与活性物质间的相互作用,如氢键和离子-偶极相互作用,并讨论了设计开发高电压正极粘结剂的途径以及展望了高电压正极粘结剂的发展前景.
Lithium ion batteries (LIBs) generally suffer from severe electrolyte decomposition and the unstable cathode and electrolyte interface (CEI) during high voltage cycling
seriously impeding their practical applications. Binders can not only tightly bind the cathode active materials and conductive carbons onto the current collector
but also play a positive role in the construction of multi-scale compatible CEI. Thus
theoretically
the optimization of binders can effectively solve the above problems. In this review
we present the requirements of high voltage cathode binders
including excellent adhesion and mechanical properties
electrochemical stability and thermal stability
as well as good ion and electron transport capacity
review the high voltage cathode binders reported at present through natural binders and synthetic binders and summarize the recent research progress and development status of binders for high voltage LIBs along with the action mechanisms of various binders on the bonding and coating of electrodes and the performance of LIBs. Furthermore
we elaborate the interactions between the polar groups of binders and the cathode active particles
such as hydrogen bonding and ion dipole interaction. Finally
some perspectives and directions on future development of state-of-the-art binders for high voltage LIBs are discussed.
锂离子电池高电压正极粘结剂天然粘结剂合成粘结剂
Lithium ion batteryHigh voltage cathodeBinderNatural binderSynthetic binder
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