流变技术在高分子表征中的应用：如何正确地进行剪切流变测试

刘双; 曹晓; 张嘉琪; 韩迎春; 赵欣悦; 陈全

doi:10.11777/j.issn1000-3304.2020.20230

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流变技术在高分子表征中的应用：如何正确地进行剪切流变测试

综述 (高分子表征技术专题) | 更新时间：2021-03-05

- 流变技术在高分子表征中的应用：如何正确地进行剪切流变测试
- Toward Correct Measurements of Shear Rheometry
- 高分子学报 2021年52卷第4期页码：406-422
- 作者机构：
  
  1.中国科学院长春应用化学研究所高分子物理与化学国家重点实验室　长春 130022
  2.中国科学技术大学应用化学与工程学院　合肥 230026
- 作者简介：
  
  [ "陈全，男，1981年生. 中国科学院长春应用化学研究所研究员. 本科和硕士毕业于上海交通大学，2011年在日本京都大学取得工学博士学位，之后赴美国宾州州立大学继续博士后深造. 于2015年回国成立独立课题组，同年当选中国流变学学会专业委员会委员；于2016年获美国TA公司授予的Distinguished Young Rheologist Award (2~3人/年)，同年入选2016年中组部QR计划青年项目；于2017年获基金委优青项目资助；于2019年入选中国化学会高分子学科委员会委员，同年获得日本流变学会奖励赏(1~2人/年)，目前担任《Nihon Reoroji Gakkaishi》(日本流变学会志)和《高分子学报》编委" ]
- 基金信息：
  
  国家自然科学基金(基金号 21790343)和中国科学院科研仪器设备研制项目(项目号 YJKYYQ20190084)资助()
- DOI：10.11777/j.issn1000-3304.2020.20230
  中图分类号：
- 纸质出版日期：2021-4-3，
  
  网络出版日期：2021-1-8，
  
  收稿日期：2020-10-14，
  
  修回日期：2020-12-3，
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刘双, 曹晓, 张嘉琪, 韩迎春, 赵欣悦, 陈全. 流变技术在高分子表征中的应用：如何正确地进行剪切流变测试[J]. 高分子学报, 2021,52(4):406-422.

Shuang Liu, Xiao Cao, Jia-qi Zhang, Ying-chun Han, Xin-yue Zhao, Quan Chen. Toward Correct Measurements of Shear Rheometry[J]. Acta Polymerica Sinica, 2021,52(4):406-422.
刘双, 曹晓, 张嘉琪, 韩迎春, 赵欣悦, 陈全. 流变技术在高分子表征中的应用：如何正确地进行剪切流变测试[J]. 高分子学报, 2021,52(4):406-422. DOI： 10.11777/j.issn1000-3304.2020.20230.

Shuang Liu, Xiao Cao, Jia-qi Zhang, Ying-chun Han, Xin-yue Zhao, Quan Chen. Toward Correct Measurements of Shear Rheometry[J]. Acta Polymerica Sinica, 2021,52(4):406-422. DOI： 10.11777/j.issn1000-3304.2020.20230.

摘要

流变学是高分子加工和应用的重要基础，流变学表征对于深入理解高分子流动行为非常重要，获取的流变参数可用于指导高分子加工. 本文首先总结了剪切流变测试中的基本假设：(1)设置的应变施加在样品上，(2)应力来源于样品自身的响应和(3)施加的流场为纯粹的剪切流场；之后具体阐述了这些假设失效的情形和所导致的常见的实验错误；最后，通过结合一些实验实例具体说明如何培养良好的测试习惯和获得可靠的测试结果.

Abstract

Rheology is an important tool for characterizing polymeric materials. The knowledge of polymer dynamics obtained from rheological measurements can guide the processing of polymeric materials. Nevertheless

it is a challenging task to conduct precise measurements on shear rheometers. First

we summarize the basic assumptions of rheological measurements: (1) the applied strain is on the sample

(2) the stress reflects sample’s own stress response

and (3) the flow field is purely the shear flow. Second

we highlight the conditions under which the above assumptions become invalid

which leads to incorrect measurements. For example

the first assumption is violated when compliance of the equipment or the wall-slip becomes non-negligible

the second assumption is violated when either inertia of the equipment

that of the sample

or the interfacial tension contributes non-negligibly to the overall torque

and the third assumption is violated when there is the secondary flow

shear-banding

or edge fracture. We show some examples of the incorrect measurements owing to these violations of the assumptions. Finally

we stress the importance of good experimental practice in rheological experiments.

关键词

流变学剪切流场剪切流变测试

Keywords

RheologyShear flow fieldShear rheology measurement

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