X射线晶体结构解析技术在高分子表征研究中的应用

扈健; 王梦梵; 吴婧华

doi:10.11777/j.issn1000-3304.2020.20258

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X射线晶体结构解析技术在高分子表征研究中的应用

综述 (高分子表征技术专题) | 更新时间：2023-12-20

- X射线晶体结构解析技术在高分子表征研究中的应用
- X-ray Diffraction Methodology for Crystal Structure Analysis in Characterization of Polymer
- 高分子学报 2021年52卷第10期页码：1390-1405
- 作者机构：
  
  1.青岛科技大学教育部/山东橡塑重点实验室青岛 266042
  2.北京化工大学碳纤维及复合材料教育部重点实验室北京 100029
- 作者简介：
  
  [ "扈健，男，1986年生. 2013~2016年在日本丰田工业大学获得工学博士学位；2016~2019年于青岛科技大学从事博士后研究；2019年任青岛科技大学高分子科学与工程学院特聘副教授. 主要利用广角和小角X射线散射，振动光谱等技术，从事结晶高分子各级结构表征、相变行为以及结构-性能关系的研究." ]
- 基金信息：
  
  国家自然科学基金(基金号 21704053)
- DOI：10.11777/j.issn1000-3304.2020.20258
  中图分类号：
- 纸质出版日期：2021-10-20，
  
  网络出版日期：2021-06-29，
  
  收稿日期：2020-11-28，
  
  修回日期：2020-12-31，
扫描看全文
扈健,王梦梵,吴婧华.X射线晶体结构解析技术在高分子表征研究中的应用[J].高分子学报,2021,52(10):1390-1405.

Hu Jian,Wang Meng-fan,Wu Jing-hua.X-ray Diffraction Methodology for Crystal Structure Analysis in Characterization of Polymer[J].Acta Polymerica Sinica,2021,52(10):1390-1405.
扈健,王梦梵,吴婧华.X射线晶体结构解析技术在高分子表征研究中的应用[J].高分子学报,2021,52(10):1390-1405. DOI： 10.11777/j.issn1000-3304.2020.20258.

Hu Jian,Wang Meng-fan,Wu Jing-hua.X-ray Diffraction Methodology for Crystal Structure Analysis in Characterization of Polymer[J].Acta Polymerica Sinica,2021,52(10):1390-1405. DOI： 10.11777/j.issn1000-3304.2020.20258.

摘要

高分子材料结构具有多尺度的复杂性，解析高分子材料各级微观结构并建立结构与性能之间的关系是高分子研究领域的重要目标和挑战. 对结晶性高分子而言，第一步工作就是对其晶体结构进行表征和解析，X射线衍射法是高分子晶体结构解析中最经典也是最常用的方法. 本文主要介绍X射线衍射等技术在高分子晶体解析中的基本原理和测试表征方法，总结概述近些年来晶体结构解析在高分子领域内的主要进展以及应用. 通过晶体结构解析的方法建立可靠的高分子晶体结构，不仅可以应用于新合成结晶高分子结构的解析，也可以进一步研究高分子各级结构在外场作用下的演变，探明微观结构与宏观性能之间的关系.

Abstract

Because of complicated multi-scale structure for the polymer material

studying microscopic structure of polymer and clarifying the relationship between structure and physical property are the major goal and challenge in the polymer science. For the crystalline polymer

crystal structure should be analyzed and established at first. X-ray diffraction is the most classical and conventional method for the crystal structure analysis in polymers

which gives the detailed information of molecular chain conformation

chain aggregation in the crystal lattice. This article reviews the main principles and experimental techniques of X-ray diffraction methodology

and also summarizes the progress and application in the polymer field over the past decade. By utilizing X-ray diffraction method

the crystal structure of newly synthesized crystalline polymers can be analyzed

which may help us recognize crystal phase transition and hierarchical structure evolution by the external force

and also study towards the microscopic clarification of structure-property relationship. By combining other techniques such as neutron scattering

electron diffraction

nuclear magnetic resonance

vibrational spectroscopy and computer simulation

the crystal structure of polymers with higher reliability can be established

leading us to the highly quantitative discussion from the molecular level. For this purpose

the study of polymer crystal structure is still on the way

and the contents may be helpful for the beginners and researchers.

关键词

结晶性高分子晶体结构X射线衍射结构与性能

Keywords

Crystalline polymerCrystal structureX-ray diffraction methodStructure and property

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