新型高分子基多孔炭材料的设计制备与功能化策略

刘绍鸿; 黄俊龙; 唐友臣; 吴丁财

doi:10.11777/j.issn1000-3304.2020.20286

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新型高分子基多孔炭材料的设计制备与功能化策略

专论 | 更新时间：2024-02-20

- 新型高分子基多孔炭材料的设计制备与功能化策略
- Controllable Preparation and Functionalization Strategies of Novel Polymer-based Porous Carbon Materials
- 高分子学报 2021年52卷第7期页码：679-686
- 作者机构：
  
  中山大学化学学院聚合物复合材料及功能材料教育部重点实验室广州 510275
- 作者简介：
  
  [ "吴丁财，男，1979年生. 中山大学教授、博士生导师. 2001年在华侨大学获学士学位，专业为应用化学. 2006年在中山大学获博士学位，专业为高分子化学与物理；毕业后留校任教，历任讲师、副教授、教授. 主要从事新型功能高分子材料(特别是多孔高分子及其多孔炭材料)的结构设计、可控制备及其在能源、环境和生物医学等领域的应用研究. 目前担任中山大学聚合物复合材料及功能材料教育部重点实验室副主任，《Chinese Journal of Polymer Science》和《Energy Storage Materials》编委. 2019年获国家杰出青年科学基金资助." ]
- 基金信息：
  
  国家自然科学基金(基金号 ┣51925308;U1601206;51872336);51702370┫
- DOI：10.11777/j.issn1000-3304.2020.20286
  中图分类号：
- 纸质出版日期：2021-07-20，
  
  网络出版日期：2021-04-29，
  
  收稿日期：2020-12-28，
扫描看全文
刘绍鸿,黄俊龙,唐友臣等.新型高分子基多孔炭材料的设计制备与功能化策略[J].高分子学报,2021,52(07):679-686.

Shao-hong Liu, Jun-long Huang, You-chen Tang, Ding-cai Wu. Controllable Preparation and Functionalization Strategies of Novel Polymer-based Porous Carbon Materials[J]. ACTA POLYMERICA SINICA, 2021,52(7):679-686.
刘绍鸿,黄俊龙,唐友臣等.新型高分子基多孔炭材料的设计制备与功能化策略[J].高分子学报,2021,52(07):679-686. DOI： 10.11777/j.issn1000-3304.2020.20286.

Shao-hong Liu, Jun-long Huang, You-chen Tang, Ding-cai Wu. Controllable Preparation and Functionalization Strategies of Novel Polymer-based Porous Carbon Materials[J]. ACTA POLYMERICA SINICA, 2021,52(7):679-686. DOI： 10.11777/j.issn1000-3304.2020.20286.

摘要

多孔炭材料具有孔隙率丰富、导电率高、结构稳定以及物理化学性质可调等优点，广泛应用于能源储存与转换、吸附分离、催化、石油化工和生物医药等领域. 原料结构是影响多孔炭材料结构和性能的关键因素. 高分子理化结构丰富可调，且具有良好的成炭性和形貌继承性，是制备高性能多孔炭材料的理想原料. 本专论结合近期国内外研究进展以及我们课题组相关工作，系统总结了高分子衍生多孔炭材料的直接炭化法和模板法设计制备理论，讨论了炭骨架功能化策略，归纳了高分子的化学结构及微观形貌对多孔炭材料的孔道与骨架结构的影响规律，并展望了这一领域未来的研究方向.

Abstract

Porous carbon materials exhibit high porosity

good electronical conductivity

excellent structural stability and tunable physicochemical properties

and thus find use in a series of areas

including energy storage and conversion

adsorption and separation

catalysis

petrochemical industry

and biological medicine. The physicochemical structures of their precursors are critical to the pores and skeletons of porous carbon materials

thus significantly affecting their properties in various applications. Polymers with controllable physicochemical structures

good carbonizability and desirable morphology inheritability have been regarded as promising precursors for preparation of high-performance porous carbon materials. Recent years have witnessed continuous research breakthroughs in the customization of a series of novel porous carbon materials with various structures and functionalities

based on the precise design of polymer structures

innovation of synthesis methods

and optimization of carbonization technology. Herein

according to the recent research progresses in our group and others groups in domestic and foreign countries

this feature article summarizes the theories of direct-carbonization and templating methods for polymer-derived porous carbon materials

discusses the functionalization strategies of their carbon skeletons

and illuminates the effects of chemical structure and microcosmic morphology of polymers on pores and skeletons of porous carbon materials. Finally

an outlook is prospected with regard to the concerns and challenges for the future study on polymer-based porous carbon materials.

关键词

高分子多孔炭材料结构设计可控制备功能化

Keywords

PolymersPorous carbon materialsStructural designControllable preparationFunctionalization

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