基于葫芦[10]脲的超分子水凝胶的制备及其在H<sub>2</sub>O<sub>2</sub>检测中的应用研究

刘元勋; 刘洋; 杨汉; 陈侣; 张雄志; 刘思敏

doi:10.11777/j.issn1000-3304.2021.21062

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基于葫芦[10]脲的超分子水凝胶的制备及其在H₂O₂检测中的应用研究

研究论文 | 更新时间：2023-12-20

- 基于葫芦[10]脲的超分子水凝胶的制备及其在H₂O₂检测中的应用研究
- Supramolecular Hydrogel Based on Cucurbit[10]uril and Its Application for H₂O₂ Detection
- 高分子学报 2021年52卷第10期页码：1361-1367
- 作者机构：
  
  1.武汉科技大学，化学与化工学院，武汉 430081
  2.武汉科技大学，耐火材料与冶金国家重点实验室，武汉 430081
- 作者简介：
  
  E-mail: zhangxiongzhi@wust.edu.cn
  liusimin@wust.edu.cn
- 基金信息：
  
  国家自然科学基金(基金号 ┣21801199);21871216┫
- DOI：10.11777/j.issn1000-3304.2021.21062
  中图分类号：
- 纸质出版日期：2021-10-20，
  
  网络出版日期：2021-07-06，
  
  收稿日期：2021-03-02，
  
  修回日期：2021-04-02，
扫描看全文
刘元勋,刘洋,杨汉等.基于葫芦[10]脲的超分子水凝胶的制备及其在H₂O₂检测中的应用研究[J].高分子学报,2021,52(10):1361-1367.

Liu Yuan-xun,Liu Yang,Yang Han,et al.Supramolecular Hydrogel Based on Cucurbit[10]uril and Its Application for H₂O₂ Detection[J].ACTA POLYMERICA SINICA,2021,52(10):1361-1367.
刘元勋,刘洋,杨汉等.基于葫芦[10]脲的超分子水凝胶的制备及其在H₂O₂检测中的应用研究[J].高分子学报,2021,52(10):1361-1367. DOI： 10.11777/j.issn1000-3304.2021.21062.

Liu Yuan-xun,Liu Yang,Yang Han,et al.Supramolecular Hydrogel Based on Cucurbit[10]uril and Its Application for H₂O₂ Detection[J].ACTA POLYMERICA SINICA,2021,52(10):1361-1367. DOI： 10.11777/j.issn1000-3304.2021.21062.

摘要

以丙烯酰胺(AM)与客体单元二茂铁衍生物(G)在引发剂作用下共聚形成P(AM-G)聚合物. 基于客体分子与主体分子葫芦[10]脲之间的动态主-客体相互作用为交联点制备了超分子水凝胶. 采用核磁、扫描电镜及流变等测试方法对水凝胶的结构、形貌以及自修复性能等进行研究. 结果表明超分子水凝胶为3D多孔结构的弹性体，CB[10]

的引入有利于在聚合物网络中提供交联点，并且本研究中的超分子水凝胶可在没有任何外部刺激的情况下进行自修复. 在水凝胶制备后，二茂铁的固有催化活性仍然得以保留，其良好的催化活性可应用于H

的检测，检测限为2.5×10

-4

mol/L. 本研究为超分子水凝胶功能化提供了一种新的方法，在生物技术和环境化学等领域具有潜在应用.

Abstract

Acrylamide (AM) was copolymerized with guest units ferrocene derivative (G) to produce P(AM-G) in the presence of initiator. Subsequently

supramolecular hydrogel was fabricated by dynamic host-guest interaction between the guest unit and host molecule cucurbit[10]uril (CB[10]

). The structure

morphology

and self-healing properties of hydrogel were investigated by

H-NMR spectra

scanning electron microscopy

rheological tests

etc

. The supramolecular hydrogel presents a 3D network porous structure with elastic characteristic. The dynamic CB[10] host-guest interactions contribute to the formation of crosslinking networks. The obtained supramolecular hydrogel can be self-healing without the assistance of any external stimulus. Investigations on the catalytic properties of the hydrogel show that the intrinsic catalytic activity of the ferrocene can still be preserved after

in situ

fabrication within a hydrogel matrix. The hydrogel exhibited good catalytic activity and provided a sensitive response toward H

with a detection limit of 2.5×10

-4

mol/L. This process provides a novel method for the production of functional supramolecular hydrogels with various potential applications in biotechnology and environmental chemistry.

关键词

超分子水凝胶主客体相互作用葫芦[10]脲自修复H2O2检测

Keywords

Supramolecular hydrogelsHost-guest interactionsCucurbit[10]urilSelf-healingH2O2 detection

references

Yang Y W, Sun Y L, Song N. Acc Chem Res, 2014, 47(7): 1950-1960. doi:10.1021/ar500022fhttp://dx.doi.org/10.1021/ar500022f

Lu W, Le X, Zhang J, Huang Y, Chen T. Chem Soc Rev, 2017, 46(5): 1284-1294. doi:10.1039/c6cs00754fhttp://dx.doi.org/10.1039/c6cs00754f

Voorhaar L, Hoogenboom R. Chem Soc Rev, 2016, 45(14): 4013-4031. doi:10.1039/c6cs00130khttp://dx.doi.org/10.1039/c6cs00130k

Feng Qian(冯茜), Zhang Kunyu(张琨雨), Li Rui(李睿), Bian Liming(边黎明). Acta Polymerica Sinica(高分子学报), 2021, 52(1): 1-15

Yu G, Jie K, Huang F H. Chem Rev, 2015, 115(15): 7240-7303. doi:10.1021/cr5005315http://dx.doi.org/10.1021/cr5005315

Tian Xueqi(田雪琪), Zuo Minzan(左旻瓒), Niu Pengbo(牛蓬勃), Wang Kaiya(王开亚), Hu Xiaoyu(胡晓玉). Chinese J Org Chem(有机化学), 2020, 40(7): 1823-1834. doi:10.6023/cjoc202003066http://dx.doi.org/10.6023/cjoc202003066

Yang L, Tan X, Wang Z, Zhang X. Chem Rev, 2015, 115(15): 7196-7239. doi:10.1021/cr500633bhttp://dx.doi.org/10.1021/cr500633b

Jin J, Cai L, Jia Y G, Liu S, Chen Y, Ren L. J Mater Chem B, 2019, 7(10): 1637-1651. doi:10.1039/c8tb02547ahttp://dx.doi.org/10.1039/c8tb02547a

Zheng J, Xiao P, Liu W, Zhang J, Huang Y, Chen T. Macromol Rapid Commun, 2016, 37(3): 265-270. doi:10.1002/marc.201500571http://dx.doi.org/10.1002/marc.201500571

Li Yixuan(李懿轩), Sun Junqi(孙俊奇). Acta Polymerica Sinica(高分子学报), 2020, 51(8): 791-803. doi:10.11777/j.issn1000-3304.2020.20062http://dx.doi.org/10.11777/j.issn1000-3304.2020.20062

Ma Q, Zhang M, Yao C, Du Y, Yang D. Chem Eng J, 2020, 394: 124894. doi:10.1016/j.cej.2020.124894http://dx.doi.org/10.1016/j.cej.2020.124894

Wei Z, Yang J H, Zhou J, Xu F, Zrínyi M, Dussault P H, OsadaY, Chen Y M. Chem Soc Rev, 2014, 43(23): 8114-8131. doi:10.1039/c4cs00219ahttp://dx.doi.org/10.1039/c4cs00219a

Wang S, Xu Z, Wang T, Xiao T, Hu X Y, Shen Y Z, Wang L. Nat Commun, 2018, 9: 1737. doi:10.1038/s41467-018-03827-3http://dx.doi.org/10.1038/s41467-018-03827-3

Ma X, Zhao Y. Chem Rev, 2015, 115(15): 7794-7839. doi:10.1021/cr500392whttp://dx.doi.org/10.1021/cr500392w

Bhattacharya S, Samanta S K. Chem Rev, 2016, 116(19): 11967-12028. doi:10.1021/acs.chemrev.6b00221http://dx.doi.org/10.1021/acs.chemrev.6b00221

Mehwish N, Dou X, Zhao Y, Feng C L. Mater Horiz, 2019, 6(1): 14-44. doi:10.1039/c8mh01130chttp://dx.doi.org/10.1039/c8mh01130c

Jiang Z, Tan M L, Taheri M, Yan Q, Tsuzuki T, Gardiner M G, Diggle B, Connal L A. Angew Chem Int Ed, 2020, 59(18): 7049-7056. doi:10.1002/anie.201916058http://dx.doi.org/10.1002/anie.201916058

Zhang B, He J, Shi M, Liang Y, Guo B. Chem Eng J, 2020, 400: 125994. doi:10.1016/j.cej.2020.125994http://dx.doi.org/10.1016/j.cej.2020.125994

Chen L, Chen Y, Zhang Y, Liu Y. Angew Chem Int Ed, 2021, 60(14): 7654-7658. doi:10.1002/anie.202017001http://dx.doi.org/10.1002/anie.202017001

Xia D, Wang P, Ji X, Khashab N M, Sessler J L, Huang F H. Chem Rev, 2020, 120(13): 6070-6123. doi:10.1021/acs.chemrev.9b00839http://dx.doi.org/10.1021/acs.chemrev.9b00839

Xiao T, Xu L, Zhou L, Sun X Q, Lin C, Wang L. J Mater Chem B, 2019, 7(10): 1526-1540. doi:10.1039/c8tb02339ehttp://dx.doi.org/10.1039/c8tb02339e

Zhao Q, Chen Y, Li S H, Liu Y. Chem Commun, 2018, 54(2): 200-203. doi:10.1039/c7cc08822ahttp://dx.doi.org/10.1039/c7cc08822a

Wang K P, Chen Y, Liu Y. Chem Commun, 2015, 51(9): 1647-1649. doi:10.1039/c4cc08721fhttp://dx.doi.org/10.1039/c4cc08721f

Wang H, Zhu C N, Zeng H, Ji X, XieT,Yan X, Wu Z L, Huang F H. Adv Mater, 2019, 31(12): 1807328. doi:10.1002/adma.201807328http://dx.doi.org/10.1002/adma.201807328

Li Yawen(李亚雯), Ao Wantong(敖宛彤), Jin Huilin(金慧琳), Cao Liping(曹利平). Prog Chem(化学进展), 2019, 31(01): 133-145

Lagona J, Mukhopadhyay P, Chakrabarti S, Isaacs L. Angew Chem Int Ed, 2005, 44(31): 4844-4870. doi:10.1002/anie.200460675http://dx.doi.org/10.1002/anie.200460675

Masson E, Ling X, Joseph R, Kyeremeh-Mensah L, Lu X. RSC Adv, 2012, 2(4): 1213-1247. doi:10.1039/c1ra00768hhttp://dx.doi.org/10.1039/c1ra00768h

Shetty D, Khedkar J K, Park K M, Kim K. Chem Soc Rev, 2015, 44(23): 8747-8761. doi:10.1039/c5cs00631ghttp://dx.doi.org/10.1039/c5cs00631g

Assaf K I, Nau W M. Chem Soc Rev, 2015, 44(2): 394-418. doi:10.1039/c4cs00273chttp://dx.doi.org/10.1039/c4cs00273c

Yang X R, Liu F B, Zhao Z Y, Liang F, Zhang H J, Liu S M. Chin Chem Lett, 2018, 29(11): 1560-1566. doi:10.1016/j.cclet.2018.01.032http://dx.doi.org/10.1016/j.cclet.2018.01.032

Barrow S J, Kasera S, Rowland M J, del Barrio J, Scherman O A. Chem Rev, 2015, 115(22): 12320-12406. doi:10.1021/acs.chemrev.5b00341http://dx.doi.org/10.1021/acs.chemrev.5b00341

Yan X, Wang F, Zheng B, Huang F. Chem Soc Rev, 2012, 41(18): 6042-6065. doi:10.1039/c2cs35091bhttp://dx.doi.org/10.1039/c2cs35091b

Yang L, Tan X, Wang Z, Zhang X. Chem Rev, 2015, 115(15): 7196-7239. doi:10.1021/cr500633bhttp://dx.doi.org/10.1021/cr500633b

Chen K, Liang L, Zhang Y Q,Zhu Q J, Xue S F, Tao Z. Inorg Chem, 2011, 50(16): 7754-7760. doi:10.1021/ic200902ghttp://dx.doi.org/10.1021/ic200902g

Park K M, Yang J A, Jung H, Yeom J, Park J S, Park K H, Hoffman A S, Hahn S K, Kim K. ACS Nano, 2012, 6(4): 2960-2968. doi:10.1021/nn204123phttp://dx.doi.org/10.1021/nn204123p

Jung H, Park J S, Yeom J, Selvapalam N, Park K M, OhK,Yang J A, Park K H, Hahn S K, Kim K, Biomacromolecules, 2014, 15(3): 707-714. doi:10.1021/bm401123mhttp://dx.doi.org/10.1021/bm401123m

ChenH,Hou S, Ma H, Li X, Tan Y B. Sci Rep, 2016, 6: 20722. doi:10.1038/srep20722http://dx.doi.org/10.1038/srep20722

Zou L, Braegelman A S, Webber M J. ACS Appl Mater Interfaces 2019, 11(6): 5695-5700. doi:10.1021/acsami.8b22151http://dx.doi.org/10.1021/acsami.8b22151

Appel E A, Biedermann F, Rauwald U, Jones S T, Zayed J M, Scherman O A. J Am Chem Soc, 2010, 132(40): 14251-14260. doi:10.1021/ja106362whttp://dx.doi.org/10.1021/ja106362w

Appel E A, Loh X J, Jones X T, Biedermann F, Dreiss C A, Scherman O A. J Am Chem Soc, 2012, 134(28): 11767-11773. doi:10.1021/ja3044568http://dx.doi.org/10.1021/ja3044568

Tan C S Y, Liu J, Groombridge A S, Barrow S J, Dreiss C A, Scherman O A. Adv Funct Mater, 2018, 28(7): 1702994. doi:10.1002/adfm.201702994http://dx.doi.org/10.1002/adfm.201702994

Kuang S J, Hu Z X, Zhang H, Zhang X Z, Liang F, Zhao Z Y, Liu S M. Chem Commun, 2018, 54(17): 2169-2172. doi:10.1039/c8cc00593ahttp://dx.doi.org/10.1039/c8cc00593a

Yang X R, Zhao Z Y, Zhang X Z, Liu S M. Sci China Chem, 2018, 61: 787-791. doi:10.1007/s11426-017-9173-4http://dx.doi.org/10.1007/s11426-017-9173-4

Fan L, Zhang Q, Wang K, Li F, Niu L. J Mater Chem, 2012, 22(13): 6165-6170. doi:10.1039/c2jm15411khttp://dx.doi.org/10.1039/c2jm15411k

Gu H, Mu S, Qiu G, Liu X, Zhang L, Yuan Y, Astruc D. Coord Chem Rev, 2018, 364: 51-85. doi:10.1016/j.ccr.2018.03.013http://dx.doi.org/10.1016/j.ccr.2018.03.013

Zainul A, Wang L, Yu H, Saleem M, Akram M, Khalid H, Abbasi N M, Yang X. J Colloid Interface Sci, 2017, 487: 38-51

Ding Y, Zhao Y, Li Y, Goodenough J B, Yu G. Energy Environ Sci, 2017, 10(2): 491-497. doi:10.1039/c6ee02057ghttp://dx.doi.org/10.1039/c6ee02057g

Divyapriya G, Srinivasan R, Nambi I M, Senthilnathan J. Electrochim Acta, 2018, 283: 858-870. doi:10.1016/j.electacta.2018.06.186http://dx.doi.org/10.1016/j.electacta.2018.06.186

Duan Q, Cao Y, Li Y, Hu X, Xiao T, Lin C, Pan Y, Wang L. J Am Chem Soc, 2013, 135(28): 10542-10549. doi:10.1021/ja405014rhttp://dx.doi.org/10.1021/ja405014r

Wang Y, Yin W, Ke W, Chen W, He C, Ge Z. Biomacromolecules, 2018, 19(6): 1990-1998. doi:10.1021/acs.biomac.7b01777http://dx.doi.org/10.1021/acs.biomac.7b01777

Deng Y Y, Yin H, Zhao Z, Wang R B, Liu S M. Supramol Chem, 2018, 30(8): 706-712. doi:10.1080/10610278.2018.1455977http://dx.doi.org/10.1080/10610278.2018.1455977

Hu X C, Liu F B, Zhang X Z, Zhao Z Y, Liu S M. Chem Sci, 2020, 11(18): 4779-4785. doi:10.1039/d0sc00409jhttp://dx.doi.org/10.1039/d0sc00409j

Tang B, Zhao J, Jiao Y, Xu J F, Zhang X. Chem Commun, 2019, 55(94): 14127-14130. doi:10.1039/c9cc06877ehttp://dx.doi.org/10.1039/c9cc06877e

Yang Q, Wang P, Zhao C, Wang W, Yang J, Liu Q. Macromol Rapid Commun, 2017, 38(6): 1600741. doi:10.1002/marc.201600741http://dx.doi.org/10.1002/marc.201600741

Du X, Zhou J, Shi J, Xu B. Chem Rev, 2015, 115(24): 13165-13307. doi:10.1021/acs.chemrev.5b00299http://dx.doi.org/10.1021/acs.chemrev.5b00299

Hu J, Hiwatashi K, Kurokawa K, Liang S M, Wu Z L, Gong J P. Macromolecules, 2011, 44(19): 7775-7781. doi:10.1021/ma2016248http://dx.doi.org/10.1021/ma2016248

Eslahi N, Abdorahim M, Simchi A. Biomacromolecules, 2016, 17(11): 3441-3463. doi:10.1021/acs.biomac.6b01235http://dx.doi.org/10.1021/acs.biomac.6b01235

Xu X, Jerca V V, Hoogenboom R. Macromol Rapid Commun, 2020, 41(4): 1900457. doi:10.1002/marc.201900457http://dx.doi.org/10.1002/marc.201900457

Zhang Y, Liang L, Chen Y, Chen X M, Liu Y. Soft Matter, 2019, 15(1): 73-77. doi:10.1039/c8sm02203hhttp://dx.doi.org/10.1039/c8sm02203h

Zhang X Z, Liu Y X, Wen J W, Zhao Z Y, Chen H X, Liu X H, Liu S M. Soft Matter, 2020, 16(14): 3416-3424. doi:10.1039/d0sm00271bhttp://dx.doi.org/10.1039/d0sm00271b

Song S, Liu Y, Song A, Zhao Z, Lu H, Hao J. J Colloid Interface Sci, 2017, 506: 46-57. doi:10.1016/j.jcis.2017.07.029http://dx.doi.org/10.1016/j.jcis.2017.07.029

Zhang Q M, Berg D, Duan J, Mugo S M, Serpe M J. ACS Appl Mater Interfaces, 2016, 8(40): 27264-27269. doi:10.1021/acsami.6b11462http://dx.doi.org/10.1021/acsami.6b11462

Gao Y, Wei Z, Li F, Yang Z, Chen Y, Zrinyi M, Osada Y. Green Chem, 2014, 16(3): 1255-1261. doi:10.1039/c3gc41535jhttp://dx.doi.org/10.1039/c3gc41535j

Lu J, Zhang H, Li S, Guo S, Shen L, Zhou T, Zhong H, Wu L, Meng Q, Zhang Y. Inorg Chem, 2020, 59(5): 3152-3159. doi:10.1021/acs.inorgchem.9b03512http://dx.doi.org/10.1021/acs.inorgchem.9b03512

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Supramolecular Hydrogel Based on Cucurbit[10]uril and Its Application for H2O2 Detection

DOI：10.11777/j.issn1000-3304.2021.21062

摘要

Abstract

关键词

Keywords

references

基于葫芦[10]脲的超分子水凝胶的制备及其在H₂O₂检测中的应用研究

Supramolecular Hydrogel Based on Cucurbit[10]uril and Its Application for H₂O₂ Detection