聚酰亚胺薄膜材料的各向异性导热行为研究与进展

高梦岩; 王畅鸥; 贾妍; 翟磊; 莫松; 何民辉; 范琳

doi:10.11777/j.issn1000-3304.2021.21094

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聚酰亚胺薄膜材料的各向异性导热行为研究与进展

综述 | 更新时间：2023-12-20

- 聚酰亚胺薄膜材料的各向异性导热行为研究与进展
- Research Progress in Anisotropic Thermal Conduction Behavior of Polyimide Films
- 高分子学报 2021年52卷第10期页码：1283-1297
- 作者机构：
  
  1.中国科学院化学研究所极端环境高分子材料重点实验室北京 100190
  2.中国科学院大学化学科学学院北京 100049
- 作者简介：
  
  [ "翟磊，男，1985年生. 2007年毕业于青岛科技大学获得学士学位，2012年于中国科学院化学研究所高分子化学与物理专业获得博士学位，2012~2017年于中海油研究总院任高级工程师、项目高级主管，2018年至今在中国科学院化学研究所极端环境高分子材料重点实验室工作. 主要从事电子及微电子用功能性聚酰亚胺材料的基础与应用研究，近些年围绕柔性显示、高频通信、先进半导体及集成电路等应用需求与技术挑战，先后开展了高透明、低介电损耗、低膨胀、高导热、低温酰亚胺化等系列高性能聚酰亚胺材料的结构设计与性能研究工作. 已发表学术论文18篇，申请/授权国家发明专利20余项." ]
  [ "范琳，女，1964年生. 1989年毕业于北京化工大学高分子材料专业获得硕士学位，1989~1994年于(原)化工部北京化工研究院任工程师，1999年于日本千叶大学物质科学专攻获博士学位，1999~2002年在日本千叶大学电子光情报基盘技术研究中心从事博士后研究. 2002年至今，中国科学院化学研究所研究员，2021年担任中国电工技术学会绝缘材料与绝缘技术专业委员会委员. 先后获得中国科学院院地合作奖(2013年)、中国产学研合作创新成果奖(2013年)、工信部技术发明二等奖(2014年)等. 研究方向为高性能和功能性聚酰亚胺材料，重点开展聚酰亚胺材料的分子设计与制备方法、聚合物结构与性能调控、材料成型方法与环境使役性等基础研究，并针对微电子和柔性显示领域开展聚酰亚胺材料应用研究和产业化技术研究." ]
- 基金信息：
  
  北京市自然科学基金(基金号 2202068)
- DOI：10.11777/j.issn1000-3304.2021.21094
  中图分类号：
- 纸质出版日期：2021-10-20，
  
  网络出版日期：2021-08-04，
  
  收稿日期：2021-03-24，
  
  修回日期：2021-04-09，
扫描看全文
高梦岩,王畅鸥,贾妍等.聚酰亚胺薄膜材料的各向异性导热行为研究与进展[J].高分子学报,2021,52(10):1283-1297.

Gao Meng-yan,Wang Chang-ou,Jia Yan,et al.Research Progress in Anisotropic Thermal Conduction Behavior of Polyimide Films[J].ACTA POLYMERICA SINICA,2021,52(10):1283-1297.
高梦岩,王畅鸥,贾妍等.聚酰亚胺薄膜材料的各向异性导热行为研究与进展[J].高分子学报,2021,52(10):1283-1297. DOI： 10.11777/j.issn1000-3304.2021.21094.

Gao Meng-yan,Wang Chang-ou,Jia Yan,et al.Research Progress in Anisotropic Thermal Conduction Behavior of Polyimide Films[J].ACTA POLYMERICA SINICA,2021,52(10):1283-1297. DOI： 10.11777/j.issn1000-3304.2021.21094.

摘要

聚酰亚胺薄膜材料在集成电路、光电显示、柔性电子等领域具有广泛应用，然而其较差的导热性能越来越无法满足器件的快速散热需求. 在保持耐热、力学等优势性能基础上，发展新一代高导热各向异性的聚酰亚胺薄膜材料成为国内外研究的重点. 本文系统总结了聚酰亚胺本征薄膜及聚酰亚胺/导热填料复合薄膜在各向异性导热行为方面的研究进展，重点从聚酰亚胺分子结构设计、各向异性导热机理、填料取向排列、基体相态结构等方面进行了详细介绍. 通过对非晶型与液晶型两类聚酰亚胺结构特点的分析，阐述了聚酰亚胺本征薄膜的分子结构与各向异性导热性能的关系；介绍了基于导热填料取向排列和基于基体相分离结构两类复合薄膜的填料取向与导热通路构建方法，深入分析了导热填料在基体中的分散形态对薄膜各向异性导热行为的影响，最后对导热聚酰亚胺薄膜材料面临的挑战进行了总结与展望.

Abstract

Polyimide films are widely used in the fields of advanced integrated circuits

optoelectronic displays

flexible functional electronics

etc

. With the further development of application

the poor thermal conductivity of polyimide film is unable to meet the rapid heat dissipation requirements of electronic devices. In order to improve the thermal conductivity of films and maintain the superior performance of polyimide materials

a new generation of anisotropic polyimide films with high thermal conductivity has become the focus of research. Due to the obvious anisotropy in the structure or properties of polyimides and thermally conductive fillers

the thermal conductivity behavior of both polyimide intrinsic films and polyimide-based composite films mostly shows significant anisotropy. The molecular structures and chain aggregation of polyimides

orientation arrangement of thermally conductive fillers

as well as the matrix morphology will all exert an important impact on the thermal conductivity and their anisotropic behavior of films. Here

we systematically summarize the research progress on anisotropic thermal conduction behavior of polyimide intrinsic films and polyimide-based composite films. The molecular structure design of polyimides

anisotropic heat conduction mechanism

filler orientation and matrix phase structures are discussed in detail. The effect of structural characteristics of polyimide intrinsic films on their thermal conductivity in different directions is presented

and the related research results of amorphous polyimides and liquid crystalline polyimides are respectively introduced. Composite films based on the orientation arrangement of thermally conductive fillers are described

and the other polyimide-based composite films with the matrix phase separation structures are also concluded. The relationship between the orientation or dispersed state of thermally conductive fillers in the matrix and the anisotropic thermal conduction behavior of two types composite films are particularly investigated. Finally

the challenges of polyimide-based film materials with high anisotropic thermal conduction are summarized and the prospects of the future work are outlooked.

关键词

聚酰亚胺本征薄膜复合薄膜导热行为各向异性

Keywords

PolyimideIntrinsic filmsComposite filmsThermal conduction behaviorAnisotropy

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