纤维素纳米晶体手性复合材料：结构色的调控与应用

安邦; 徐明聪; 马春慧; 罗沙; 李伟; 刘守新

doi:10.11777/j.issn1000-3304.2021.21215

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纤维素纳米晶体手性复合材料：结构色的调控与应用

综述 | 更新时间：2024-10-08

- 纤维素纳米晶体手性复合材料：结构色的调控与应用
- Tuning and Application of Structural Color of Cellulose Nanocrystals Chiral Composite Materials
- 高分子学报 2022年53卷第3期页码：211-226
- 作者机构：
  
  东北林业大学生物质材料科学与技术教育部重点实验室哈尔滨 150040
- 作者简介：
  
  [ "李伟，男，1982年生. 东北林业大学材料科学与工程学院副教授、博士生导师. 2005年于东北林业大学获工学学士学位，2009年于东北林业大学获工学硕士学位，2012年于东北林业大学获工学博士学位. 主要研究方向为木质纤维素纳米晶体复合功能材料." ]
  [ "刘守新，男，1972 年生. 东北林业大学材料科学与工程学院教授、博士生导师. 1994年于锦州师范学院获理学学士学位，1997年于东北林业大学获工学硕士学位，2002年于东北林业大学获工学博士学位. 主要研究方向为生物质基炭材料、纤维素纳米晶体功能材料等." ]
- 基金信息：
  
  国家自然科学基金(基金号 ┣32071719);31890773┫;黑龙江省自然科学基金优秀青年基金(基金号 YQ2020C016)
- DOI：10.11777/j.issn1000-3304.2021.21215
  中图分类号：
- 纸质出版日期：2022-03-20，
  
  网络出版日期：2021-12-23，
  
  收稿日期：2021-08-05，
  
  录用日期：2021-10-08
- 稿件说明：
移动端阅览
安邦,徐明聪,马春慧等.纤维素纳米晶体手性复合材料：结构色的调控与应用[J].高分子学报,2022,53(03):211-226.

An Bang,Xu Ming-cong,Ma Chun-hui,et al.Tuning and Application of Structural Color of Cellulose Nanocrystals Chiral Composite Materials[J].ACTA POLYMERICA SINICA,2022,53(03):211-226.
安邦,徐明聪,马春慧等.纤维素纳米晶体手性复合材料：结构色的调控与应用[J].高分子学报,2022,53(03):211-226. DOI： 10.11777/j.issn1000-3304.2021.21215.

An Bang,Xu Ming-cong,Ma Chun-hui,et al.Tuning and Application of Structural Color of Cellulose Nanocrystals Chiral Composite Materials[J].ACTA POLYMERICA SINICA,2022,53(03):211-226. DOI： 10.11777/j.issn1000-3304.2021.21215.

摘要

结构色在自然界中扮演了重要的角色，在昆虫外骨骼、鸟类羽毛以及植物果实中广泛分布. 纤维素纳米晶体(CNCs)的水悬浮液达到一定浓度时会自组装形成左旋的手性向列液晶结构，这种手性向列结构在水分挥发后仍能保持并形成光子晶体虹彩薄膜，具有极强的手性和光子晶体的双重性质. 膜内的周期性层状结构与光线产生干涉、衍射作用，表现出复杂的虹彩色. CNCs与其他材料结合所制备的CNCs手性复合材料具有良好的力学性能，在传感器、防伪以及装饰等领域具有广阔前景. 本文讨论了CNCs手性复合材料的结构色调控以及在刺激响应、图案显示和圆偏振光学等方面的研究进展.

Abstract

Structural color plays an important role in nature and is widely distributed in insect exoskeletons

bird feathers and plant fruits. Cellulose is abundant in nature and has a huge increment annually and naturally arranges into regular structures to form a structural color in some plants. The cellulose nanocrystals (CNCs) papered by sulfuric acid hydrolysis will self-assemble to form left-handed chiral nematic structures at critical concentration in water. This chiral nematic structure can be maintained in the photonic crystal iridescent film after water volatilities

like those plants

which has dual properties of extremely strong chirality and the photonic crystals. The periodic layered structure in the film has complex interference and diffraction with the light and shows complex iridescence. These artificially prepared structural colors can be tuned by changing the source of raw materials

adjusting the assembly process

and adding other substances. The preparation process and self-assembly process of CNCs are the most commonly methods to tune structural color. Because it can be flexibly adjusted

for example

tuning the structure by changing the morphology of CNCs

the hydrolysis conditions or ultrasound

additives

time and temperature during the self-assembly process. Due to its unique optical properties

CNCS chiral composites prepared by combining CNCs with other materials to improve mechanical properties have broad application prospects in sensor and anti-counterfeiting. In the existing reports

humidity response

temperature response

organic solvent and other gas response

mechanical force response and furthermore

multiple responses have been realized. And in recent years

CNCs chiral optical devices which rely on chiral nematic phase have gradually become another important research direction. In this view

the research progress of structure color control

stimuli-response

pattern display and circularly polarized optics of CNCS composites is discussed.

关键词

纤维素纳米晶体结构色手性向列自组装圆偏振

Keywords

Cellulose nanocrystalsStructural colorChiral nematicSelf-assembleCircular polarization

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