可持续热固性树脂的高性能和功能化设计合成

刘敬楷; 代金月; 赵伟伟; 余文杰; 刘小青

doi:10.11777/j.issn1000-3304.2021.21261

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可持续热固性树脂的高性能和功能化设计合成

专论 | 更新时间：2024-10-08

- 可持续热固性树脂的高性能和功能化设计合成
- Synthesis of Sustainable Thermosetting Resins: High Performance and Functionalization
- 高分子学报 2022年53卷第2期页码：107-118
- 作者机构：
  
  中国科学院宁波材料技术与工程研究所宁波 315201
- 作者简介：
  
  [ "刘小青，1980年生. 中国科学院宁波材料技术与工程研究所研究员，博士生导师. 2002年本科毕业于兰州大学化学系；2007年博士毕业于中国科学院化学研究所；2007年9月~2009年10月分别在新加坡南洋理工大学、美国华盛顿州立大学从事博士后研究；2009年11月到中国科学院宁波材料技术与工程研究所工作. 获浙江省杰出青年科学基金支持. 近几年负责或核心参与国家973课题、国家自然科学基金、国家重点研发计划、中国科学院专项课题等20多项科研任务. 在《Progress in Polymer Science》《Green Chemistry》《Macromolecules》等期刊上发表SCI研究论文80余篇，H-因子41，论文他引4500余次，获授权发明专利60余件. 历获中国产学研合作创新奖一等奖、中国科学院先进科技特派员一等奖、中国科学院院地合作一等奖等荣誉. 主要从事生物基高分子材料、高性能热固性树脂、环保胶黏剂的研究和开发." ]
- 基金信息：
  
  国家自然科学基金(基金号 ┣U1909220);52003282, 52003283┫;浙江省杰出青年科学基金(基金号 LR20E030001);中国科学院重点部署项目(KFZD-SW-439)
- DOI：10.11777/j.issn1000-3304.2021.21261
  中图分类号：
- 纸质出版日期：2022-02-20，
  
  网络出版日期：2021-12-01，
  
  收稿日期：2021-09-04，
  
  修回日期：2021-10-27，
- 稿件说明：
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刘敬楷,代金月,赵伟伟等.可持续热固性树脂的高性能和功能化设计合成[J].高分子学报,2022,53(02):107-119.

Liu Jing-kai,Dai Jin-yue,Zhao Wei-wei,et al.Synthesis of Sustainable Thermosetting Resins: High Performance and Functionalization[J].ACTA POLYMERICA SINICA,2022,53(02):107-119.
刘敬楷,代金月,赵伟伟等.可持续热固性树脂的高性能和功能化设计合成[J].高分子学报,2022,53(02):107-119. DOI： 10.11777/j.issn1000-3304.2021.21261.

Liu Jing-kai,Dai Jin-yue,Zhao Wei-wei,et al.Synthesis of Sustainable Thermosetting Resins: High Performance and Functionalization[J].ACTA POLYMERICA SINICA,2022,53(02):107-119. DOI： 10.11777/j.issn1000-3304.2021.21261.

摘要

传统热固性树脂的大量使用与石化资源的枯竭和环境恶化之间的矛盾日益突出，使得高性能热固性树脂的可持续发展正面临着严峻的挑战. 以可再生资源替代传统的石油化工产品用于生物基热固性树脂的合成，是实现其绿色化的重要方式之一. 除此以外，如何赋予生物基热固性树脂良好的使役性能、复杂应用环境下的多功能性、高效且高质的可回收再利用性，也是保证其可持续发展的重要内容. 早在10年前，本团队就开始了可持续热固性树脂的高性能与功能化设计合成，并致力于从原料选择、合成过程、树脂功能化、高附加值回收利用等全生命周期实现热固性树脂的可持续发展. 基于多年的研究积累和经验，本文回顾和总结了我们在生物基平台化合物筛选、树脂结构功能一体化设计和高附加值回收利用等方面的工作，展望了可持续热固性树脂的发展前景和未来趋势.

Abstract

The contradiction between the extensive usage of traditional thermosetting resin and the depletion of petrochemical resources as well as environmental pollution and deterioration has attracted more and more attention

which makes the sustainable development of high-performance thermosets face severe challenges. Taking renewable resources as feedstocks to replace traditional petrochemical products for the synthesis of bio-based thermosetting resin is one of the feasible and significant methods to achieve its green production. Besides

how to endow the bio-based thermosets with satisfied service performance and multi-functionality under different applicated environment as well as high-efficient and high-quality recyclability are also important research topics for increasing sustainability. As early as ten years ago

our team started to design and synthesize sustainable thermosetting resin

of which the high-performance and functionality were successfully realized. Aiming to further achieve the sustainable development of thermosets in the total lifecycle

we dedicated our research focus to the comprehensive improvement of the resins including renewable material selection

green manufacturing process

versatile application

and high value-added recycling. Based on our experiences

this feature article reviewed our work on the selection of bio-based platform compounds

integrative design of resin with high-performance and multi-functionality

and high value-added recycling. In the end

the prospect and future of sustainable thermosetting resins were forecasted.

关键词

可持续热固性树脂生物基功能化回收利用

Keywords

Sustainable thermosetting resinsBio-basedFunctionalizationRecycling

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