一种基于有机共晶的光控晶体管

甄淳; 李舒豫; 张伊晗; 李飞; 姜梦佳; 张小涛; 胡文平

doi:10.11777/j.issn1000-3304.2021.21329

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一种基于有机共晶的光控晶体管

研究论文 | 更新时间：2024-10-08

- 一种基于有机共晶的光控晶体管
  增强出版
- Phototransistor Based on Organic Cocorystals
- 高分子学报 2022年53卷第4期页码：396-404
- 作者机构：
  
  1.天津市分子光电科学重点实验室天津大学理学院天津 300072
  2.天津大学分子聚集态科学研究院天津 300072
  3.青藏高原资源化学与生态环境保护国家民委重点实验室青海民族大学西宁 810007
  4.天津大学-新加坡国立大学福州联合学院天津大学国际校区福州 350207
- 作者简介：
  
  E-mail: zhangxt@tju.edu.cn;
  E-mail: huwp@tju.edu.cn
- 基金信息：
  
  国家重点研发计划项目(2017YFA0204503);国家自然科学基金(基金号 ┣91833306;21875158);51633006, 51703159, 51733004┫
- DOI：10.11777/j.issn1000-3304.2021.21329
  中图分类号：
- 纸质出版日期：2022-04-20，
  
  网络出版日期：2022-01-20，
  
  收稿日期：2021-10-30，
  
  修回日期：2021-12-09，
- 稿件说明：
移动端阅览
甄淳,李舒豫,张伊晗等.一种基于有机共晶的光控晶体管[J].高分子学报,2022,53(04):396-404.

Zhen Chun,Li Shu-yu,Zhang Yi-han,et al.Phototransistor Based on Organic Cocorystals[J].ACTA POLYMERICA SINICA,2022,53(04):396-404.
甄淳,李舒豫,张伊晗等.一种基于有机共晶的光控晶体管[J].高分子学报,2022,53(04):396-404. DOI： 10.11777/j.issn1000-3304.2021.21329.

Zhen Chun,Li Shu-yu,Zhang Yi-han,et al.Phototransistor Based on Organic Cocorystals[J].ACTA POLYMERICA SINICA,2022,53(04):396-404. DOI： 10.11777/j.issn1000-3304.2021.21329.

摘要

以9

10-二苯乙炔基蒽(BPEA)作为给体分子，均苯四甲酸二酰亚胺(PMD)作为受体分子，通过溶液法制备了一种新型的电荷转移共晶BPEA-PMD. 共晶结构中，给受体分子以2:1的摩尔比呈现混合堆积模式. 通过一系列的表征，发现了其独特的光电性质，BPEA-PMD共晶分子表现出红色荧光发射特性并且兼具P型传输性能，其空穴迁移率可达8.33×10

-2

·V

-1

·s

-1

. 基于其优异的电学性能，制备了共晶光响应晶体管器件，其光响应度(

)为1.67×10

A·W

-1

，这证明了有机共晶在光电探测器方面的巨大应用潜力.

Abstract

A novel charge transfer cocrystal BPEA-PMD was prepared by

solution method using 9

‍10-diphenylacetylene anthracene (BPEA) as donor molecule and pyromellitic diimide (PMD) as acceptor molecule. The D-A cocrystals show a mixed stacking mode with a molar ratio of 2:1. A series of spectral analyses prove that there is a charge transfer characteristic in the BPEA-PMD cocrystals

which narrows the band gap of the cocrystals and further makes the cocrystals system show excellent photoelectric properties. BPEA-PMD cocrystals exhibit red fluorescence emission

and the PL lifetime is 1.14 ns

showing a single exponential decay process

which indicates that the luminescence process of BPEA-PMD cocrystals is derived from only one excited state. In addition

BPEA-PMD cocrystals display p-type transport properties with hole mobility up to 8.33×10

-2

·V

-1

·s

-1

. Based on its excellent electrical properties

photoresponsive transistors device was prepared. Under the illumination of 450 nm light

the source-drain current of the phototransistors based on BPEA-PMD increases significantly. Moreover

photosensitivity (

)

photoresponsivity (

)

and detectivity (

) are several key parameters for evaluating the photoelectric detection capability. The phototransistors for BPEA-PMD cocrystals demonstrate the

max

of 37.38

max

of 1.67×10

A·W

-1

and

max

of 2.06×10

Jones

which proves the great potential of the organic cocrystals in the application of photoelectric detectors.

关键词

有机共晶电荷转移红色荧光P型传输光响应

Keywords

Organic cocrystalsCharge transferRed fluorescenceP-type transportPhotoresponse

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