本征阻燃生物基环氧树脂研究进展

牛浩鑫; 王鑫; 宋磊; 胡源

doi:10.11777/j.issn1000-3304.2022.22007

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本征阻燃生物基环氧树脂研究进展

综述 | 更新时间：2024-10-08

- 本征阻燃生物基环氧树脂研究进展
- Progress on Intrinsically Flame-retardant Bio-based Epoxy Thermosets
- 高分子学报 2022年53卷第8期页码：894-905
- 作者机构：
  
  中国科学技术大学火灾科学国家重点实验室合肥 230026
- 作者简介：
  
  [ "王鑫，男，1986年生. 中国科学技术大学火灾科学国家重点实验室副研究员、硕士生导师. 2008年于安徽大学获工学学士学位，2013年于中国科学技术大学火灾科学国家重点实验室获工学博士学位. 目前在安全科学与工程等领域发表SCI收录论文150余篇，他引7500余次，H因子52. 获得国家自然科学二等奖(2017年)，入选Elsevier“中国高被引学者”榜单(2021年)和中科院青年创新促进会会员(2021年). 主要研究方向为聚合物材料火灾安全设计及阻燃机理." ]
- 基金信息：
  
  国家自然科学基金(基金号 ┣22075265);51991352┫;中国科学院青年创新促进会(2021459)
- DOI：10.11777/j.issn1000-3304.2022.22007
  中图分类号：
- 纸质出版日期：2022-08-20，
  
  网络出版日期：2022-08-15，
  
  收稿日期：2022-01-07，
  
  修回日期：2022-02-23，
- 稿件说明：
移动端阅览
牛浩鑫,王鑫,宋磊,胡源.本征阻燃生物基环氧树脂研究进展[J].高分子学报,

Niu Hao-xin,Wang Xin,Song Lei,Hu Yuan.Progress on Intrinsically Flame-retardant Bio-based Epoxy Thermosets[J].ACTA POLYMERICA SINICA,
牛浩鑫,王鑫,宋磊,胡源.本征阻燃生物基环氧树脂研究进展[J].高分子学报, DOI：10.11777/j.issn1000-3304.2022.22007.

Niu Hao-xin,Wang Xin,Song Lei,Hu Yuan.Progress on Intrinsically Flame-retardant Bio-based Epoxy Thermosets[J].ACTA POLYMERICA SINICA, DOI：10.11777/j.issn1000-3304.2022.22007.

摘要

目前绝大部分环氧树脂尤其是双酚A二缩水甘油醚型环氧单体依赖于石油资源. 由于温室气体的限制排放，采用生物基环氧树脂来替代石油基环氧树脂的发展受到越来越多的关注. 然而，与石油基环氧树脂类似，生物基环氧树脂同样面临易燃、火焰蔓延快等缺点，极大地限制了其应用. 因此，开发本征阻燃生物基环氧树脂十分重要. 本文主要探讨了由可再生资源制备本征阻燃生物基环氧树脂的最新进展和未来前景. 重点介绍了由生物基环氧单体或生物基固化剂制备的部分生物基环氧树脂的力学性能、热稳定性和阻燃性能，此外，还介绍了本征阻燃全生物基环氧树脂.最后对本征阻燃生物基环氧树脂未来发展的机遇和挑战做了简要的展望.

Abstract

Currently

most epoxy thermosets especially diglycidyl ether of bisphenol A (DGEBA)-type epoxy monomers are sourced from petroleum resources. Due to the restrictions on greenhouse gas emissions

the development of bio-based epoxy thermosets to replace petroleum-based epoxy thermosets has received more and more attention. However

like petroleum-based counterparts

bio-based epoxy thermosets are highly flammable. Therefore

the development of intrinsically flame-retardant bio-based epoxy thermosets is extremely important. The future development direction of intrinsically flame-retardant bio-based epoxy thermosets must be green and sustainable. At present

intrinsically flame-retardant bio-based epoxy thermosets still have some defects such as poor thermal stability

and there is a long way to go. Considering the development trend in this field

increasing the functionality of bio-based epoxy monomers or curing agents

improving biomass content and biodegradability are several key factors for the future development of flame-retardant bio-based epoxy thermosets with high-performance. This review mainly discusses the recent progress and prospects of the preparation of intrinsically flame-retardant bio-based epoxy thermosets from bio-based resources. The mechanical properties

thermal stability and flame retardancy of partly bio-based intrinsically flame-retardant epoxy thermosets from either bio-based epoxy monomers or bio-based curing agents are emphatically introduced. In addition

the fully bio-based flame-retardant epoxy thermosets are also introduced. Finally

the opportunities and challenges of the future development of the intrinsically flame-retardant bio-based epoxy thermosets have been briefly prospected.

关键词

生物基环氧树脂本征阻燃阻燃性能力学性能

Keywords

Bio-based epoxyIntrinsically flame-retardantFlame-retardant performancesMechanical properties

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