溶液加工大面积有机太阳电池材料与器件

张凯

doi:10.11777/j.issn1000-3304.2022.22055

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溶液加工大面积有机太阳电池材料与器件

专论 | 更新时间：2024-10-08

- 溶液加工大面积有机太阳电池材料与器件
- Solution-processed Large Area Organic Solar Cells Materials and Devices
- 高分子学报 2022年53卷第7期页码：737-751
- 作者机构：
  
  华南理工大学发光材料与器件国家重点实验室广州 510640
- 作者简介：
  
  [ "张凯，男，1986年生. 2010年毕业于四川大学，同年进入华南理工大学攻读博士学位，师从曹镛教授. 2015年博士毕业，加入发光材料与器件国家重点实验室工作至今. 以第一/通讯作者身份在《Adv Mater》《Nat Commun》《Joule》等刊物发表SCI论文四十余篇. 主持国家自然科学基金优秀青年基金项目、面上项目、广东省杰出青年基金项目等. 主要从事溶液加工高性能有机光伏器件研究." ]
- 基金信息：
  
  国家自然科学基金(基金号21875073;52122307)
- DOI：10.11777/j.issn1000-3304.2022.22055
  中图分类号：
- 纸质出版日期：2022-07-20，
  
  网络出版日期：2022-05-13，
  
  收稿日期：2022-02-26，
  
  录用日期：2022-03-22
- 稿件说明：
移动端阅览
张凯.溶液加工大面积有机太阳电池材料与器件[J].高分子学报,2022,53(07):737-751.

Zhang Kai.Solution-processed Large Area Organic Solar Cells Materials and Devices[J].ACTA POLYMERICA SINICA,2022,53(07):737-751.
张凯.溶液加工大面积有机太阳电池材料与器件[J].高分子学报,2022,53(07):737-751. DOI： 10.11777/j.issn1000-3304.2022.22055.

Zhang Kai.Solution-processed Large Area Organic Solar Cells Materials and Devices[J].ACTA POLYMERICA SINICA,2022,53(07):737-751. DOI： 10.11777/j.issn1000-3304.2022.22055.

摘要

有机太阳电池是一类以有机光电材料为核心的新型光伏技术，具有重量轻、颜色可调、可低成本溶液加工、可实现柔性和半透明等突出优点，在建筑-光伏一体化、半透明车窗、便携式移动充电等领域具有独特的应用潜力. 随着有机太阳电池在新材料方面的进步以及器件物理方面的发展，有机太阳电池效率实现了多次突破. 与此同时，面向商业应用的大面积有机太阳电池模组的开发也越来越受到研究人员的关注. 本文围绕溶液加工大面积有机太阳电池材料与器件，主要介绍了我们在领域内的工作进展，包括大面积均匀阴极界面层的构筑，印刷加工活性层过度聚集行为的抑制，新型印刷加工器件结构的探索等. 最后讨论了有机太阳电池模组存在的问题，并对其未来发展进行了展望.

Abstract

In the past few years

the performance of laboratory-scale organic solar cells (OSCs) have experienced very fast development

especially with the development of non-fullerene acceptor. However

there are still challenges on the way to realizing efficient module devices

such as the low compatibility of the thickness-sensitive interlayer and active layer with large area coating techniques

the tremendous power loss on enlarged electrode

the frequent need for toxic solvents

tedious optimization processes used during device fabrication

etc

. To achieve high-performance large area PSC modules

we have carried out a series of studies. For the interlayer

we have developed simple and efficient approaches to achieving large a

rea cathode interlayer using electrostatic layer-by-layer self-assembly and

in situ

self-assembly processes.

-type doping was also developed to obtain printable large area cathode interlayer. In terms of active layer

one of the main obstacles for printing ideal active layer comes from the excessive aggregation of film during printing. In this case

we have employed solvent engineering

third component strategy

molecular engineering and device structure engineering to overcome the excessive aggregation of active layer during printing and obtained high performance modules. On the basis of these results

non-halogen solvent dimethylbenzene processed large-area module with an active area of 18 cm

and efficiency over 14% was obtained. Finally

the existing problems and development directions of this field are discussed and forecasted.

关键词

有机太阳电池大面积模组界面层活性层聚集器件结构

Keywords

Organic solar cellLarge-area moduleInterlayerActive layer aggregationDevice structure

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