动态硼酸酯键管控邻苯二酚基团与功能黏附性高分子设计

武彤; 何柳; 郑丹丹; 吴小玲; 罗伟昂; 袁丛辉; 戴李宗

doi:10.11777/j.issn1000-3304.2022.22061

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动态硼酸酯键管控邻苯二酚基团与功能黏附性高分子设计

专论 | 更新时间：2024-10-08

- 动态硼酸酯键管控邻苯二酚基团与功能黏附性高分子设计
- Dynamic Boronate Ester Bond Manipulating Catechol Groups for the Design of Functional Adhesive Polymers
- 高分子学报 2022年53卷第7期页码：796-811
- 作者机构：
  
  厦门大学材料学院福建省防火阻燃材料重点实验室厦门 361005
- 作者简介：
  
  [ "袁丛辉，男，1983年生. 厦门大学材料学院教授. 2006和2009年毕业于华侨大学材料科学与工程学院，分别获学士和硕士学位；2013年毕业于厦门大学材料学院，获博士学位，师从戴李宗教授；2011~2012年美国马萨诸塞州立大学(阿默斯特)化学系联合培养博士研究生，师从S. Thayumanavan教授. 2020年获福建省自然科学基金杰青项目资助，2021年获国家自然科学基金优秀青年科学基金资助. 主要从事智能高分子、固体表面聚合物程控黏附领域的研究，包括刺激-响应水凝胶、聚合物-无机杂化材料、智能/软体机器人等." ]
  lzdai@xmu.edu.cn
- 基金信息：
  
  国家自然科学基金优秀青年科学基金项目(基金号 52122313);重点项目(基金号 52033008);面上项目(基金号 52173045);厦门大学基本科研业务费(基金号 20720210039)
- DOI：10.11777/j.issn1000-3304.2022.22061
  中图分类号：
- 纸质出版日期：2022-07-20，
  
  网络出版日期：2022-06-06，
  
  收稿日期：2022-02-28，
  
  录用日期：2022-04-06
- 稿件说明：
移动端阅览
武彤,何柳,郑丹丹等.动态硼酸酯键管控邻苯二酚基团与功能黏附性高分子设计[J].高分子学报,2022,53(07):796-811.

Wu Tong,He Liu,Zheng Dan-dan,et al.Dynamic Boronate Ester Bond Manipulating Catechol Groups for the Design of Functional Adhesive Polymers[J].ACTA POLYMERICA SINICA,2022,53(07):796-811.
武彤,何柳,郑丹丹等.动态硼酸酯键管控邻苯二酚基团与功能黏附性高分子设计[J].高分子学报,2022,53(07):796-811. DOI： 10.11777/j.issn1000-3304.2022.22061.

Wu Tong,He Liu,Zheng Dan-dan,et al.Dynamic Boronate Ester Bond Manipulating Catechol Groups for the Design of Functional Adhesive Polymers[J].ACTA POLYMERICA SINICA,2022,53(07):796-811. DOI： 10.11777/j.issn1000-3304.2022.22061.

摘要

“黏附”是一种普遍存在的多尺度相互作用，其实质是界面处化学键、氢键或范德华力等的形成. 近年来，在贻贝仿生的基础上将黏性因子邻苯二酚基团嵌入到动态硼酸酯聚合物中，成为了功能黏附性高分子的重要发展方向. 本专论从分子黏附、微/纳表面黏附和宏观表面黏附3个尺度，介绍硼酸酯键管控邻苯二酚基团在高分子材料功能化方面的研究进展. 分子黏附，主要讨论硼酸酯聚合物中邻苯二酚基团与分子或离子相互作用规律及其对材料形貌和刺激响应性能的调控；微/纳表面黏附，论述硼酸酯聚合物体系超分子驱动力和组装机制，介绍其在微/纳材料功能化改性方面的研究进展；宏观表面黏附，讨论硼酸酯键管控邻苯二酚基团与黏附性能调控的关联规律，介绍硼酸酯聚合物功能黏附材料在宏观组装、攀爬机器人领域的应用. 最后，从新型硼酸酯聚合物设计、动态键精准管控和器件化应用的角度，对该领域未来前景和发展趋势做出了展望.

Abstract

"Adhesion" is essentially the formation of chemical bonds

hydrogen bonds or van der Waals forces at the interface

which is considered as a universal multi-scale interaction. In recent years

on the basis of mussel biomimetic

incorporation of catechol groups into the dynamic boronate ester polymers

has become an important developing direction of functional polymer adhesives. This feature article focuses on the molecular adhesion

micro/nano surface adhesion and macroscopic surface adhesion

as well as introduces the research progress in the functionalization of polymer materials related to the manipulation of catechol groups by using boronate ester bonds. For molecular adhesion

the interaction between catechol groups and guest molecules or ions in the boronate ester polymers

and the corresponding material morphology control and stimuli-responsive behavior are discussed. For micro/nano surface adhesion

the supramolecular driving forces and self-assembly mechanism of boronate ester polymers are analyzed

and the related application in the modification of micro/nano materials is introduced. For macroscopic surface adhesion

the relationship between the manipulation of catechol groups by using boronate ester bonds and the control of adhesion performance is discussed

and the application of boronate ester polymer adhesives in the field of macro-assembly and climbing robot is introduced. Finally

the future and development trend of this field are prospected from the perspective of new boronate ester polymers

precise control over dynamic bonds

and device design and applications.

关键词

硼酸酯聚合物邻苯二酚基聚合物贻贝仿生表界面调控智能高分子

Keywords

Boronate ester polymerCatechol-based polymerMussel-inspired bionicsSurface and interface controlIntelligent polymer

references

Bravo L. Nutr Rev, 1998, 56(11): 317-333. doi:10.1111/j.1753-4887.1998.tb01670.xhttp://dx.doi.org/10.1111/j.1753-4887.1998.tb01670.x

Leri M, Scuto M, Ontario M L, Calabrese V, Calabrese E J, Bucciantini M, Stefani M. Int J Mol Sci, 2020, 21(4): 1250. doi:10.3390/ijms21041250http://dx.doi.org/10.3390/ijms21041250

Sedó J, Saiz-Poseu J, Busqué F, Ruiz-Molina D. Adv Mater, 2013, 25(5): 653-701. doi:10.1002/adma.201202343http://dx.doi.org/10.1002/adma.201202343

Faure E, Falentin-Daudré C, Jérôme C, Lyskawa J, Fournier D, Woisel P, Detrembleur C. Prog Polym Sci, 2013, 38(1): 236-270. doi:10.1016/j.progpolymsci.2012.06.004http://dx.doi.org/10.1016/j.progpolymsci.2012.06.004

Zhang W, Wang R, Sun Z, Zhu X, Zhao Q, Zhang T, Cholewinski A, Yang F, Zhao B, Pinnaratip R, Forooshani P K, Lee B P. Chem Soc Rev, 2020, 49(2): 433-464. doi:10.1039/c9cs00285ehttp://dx.doi.org/10.1039/c9cs00285e

Waite J H, Tanzer M L. Science, 1981, 212(4498): 1038-1040. doi:10.1126/science.212.4498.1038http://dx.doi.org/10.1126/science.212.4498.1038

Benedict C V, Waite J H J. J Morphol, 1986, 189(2): 171-181. doi:10.1002/jmor.1051890207http://dx.doi.org/10.1002/jmor.1051890207

Lee B P, Messersmith P B, Israelachvili J N, Waite J H. Annu Rev Mater Res, 2011, 41: 99-132. doi:10.1146/annurev-matsci-062910-100429http://dx.doi.org/10.1146/annurev-matsci-062910-100429

Patil N, Jérôme C, Detrembleur C. Prog Polym Sci, 2018, 82: 34-91. doi:10.1016/j.progpolymsci.2018.04.002http://dx.doi.org/10.1016/j.progpolymsci.2018.04.002

Lee H, Dellatore S M, Miller W M, Messersmith P B. Science, 2007, 318(5849): 426-430. doi:10.1126/science.1147241http://dx.doi.org/10.1126/science.1147241

Lin Q, Gourdon D, Sun C, Holten-Andersen N, Anderson T H, Waite J H, Israelachvili J N. Proc Natl Acad Sci USA, 2007, 104(10): 3782-3786. doi:10.1073/pnas.0607852104http://dx.doi.org/10.1073/pnas.0607852104

Lee H, Scherer N F, Messersmith P B. Proc Natl Acad Sci USA, 2006, 103(35): 12999-13003. doi:10.1073/pnas.0605552103http://dx.doi.org/10.1073/pnas.0605552103

Ahn B K. J Am Chem Soc, 2017, 139(30): 10166-10171. doi:10.1021/jacs.6b13149http://dx.doi.org/10.1021/jacs.6b13149

Kubo Y, Nishiyabu R, James T D. Chem Commun, 2015, 51(11): 2005-2020. doi:10.1039/c4cc07712ahttp://dx.doi.org/10.1039/c4cc07712a

Zhang C, Wu B, Zhou Y, Zhou F, Liu W, Wang Z. Chem Soc Rev, 2020, 49(11): 3605-3637. doi:10.1039/c9cs00849ghttp://dx.doi.org/10.1039/c9cs00849g

Dai Q, Geng H, Yu Q, Hao J, Cui J. Theranostics, 2019, 9(11): 3170-3190. doi:10.7150/thno.31847http://dx.doi.org/10.7150/thno.31847

Wang H, Wang C, Zou Y, Hu J, Li Y, Cheng Y. Giant, 2020, 3: 100022. doi:10.1016/j.giant.2020.100022http://dx.doi.org/10.1016/j.giant.2020.100022

Lee H, Lee B P, Messersmith P B. Nature, 2007, 448: 338-341. doi:10.1038/nature05968http://dx.doi.org/10.1038/nature05968

Ye Q, Zhou F, Liu W. Chem Soc Rev, 2011, 40(7): 4244-4258. doi:10.1039/c1cs15026jhttp://dx.doi.org/10.1039/c1cs15026j

Ran Y, Liu Y, Sun H, Zhang H, Dong H, Yang Y, Zhao N, Xu J. Appl Surf Sci, 2021, 565: 150566. doi:10.1016/j.apsusc.2021.150566http://dx.doi.org/10.1016/j.apsusc.2021.150566

White J D, Wilker J J. Macromolecules, 2011, 44(13): 5085-5088. doi:10.1021/ma201044xhttp://dx.doi.org/10.1021/ma201044x

Jiménez N, Ruipérez F, González de San Román E, Asua J M, Ballard N. Macromolecules, 2022, 55(1): 49-64. doi:10.1021/acs.macromol.1c02103http://dx.doi.org/10.1021/acs.macromol.1c02103

Yu J, Wei W, Danner E, Ashley R K, Israelachvili J N, Waite J H. Nat Chem Biol, 2011, 7: 588-590. doi:10.1038/nchembio.630http://dx.doi.org/10.1038/nchembio.630

Liu Y, Ai K, Lu L. Chem Rev, 2014, 114(9): 5057-5115. doi:10.1021/cr400407ahttp://dx.doi.org/10.1021/cr400407a

Bull S D, Davidson M G, van den Elsen J M H, Fossey J S, Jenkins A T A, Jiang Y B, Kubo Y, Marken F, Sakurai K, Zhao J, James T D. Acc Chem Res, 2013, 46(2): 312-326. doi:10.1021/ar300130whttp://dx.doi.org/10.1021/ar300130w

Brooks W L A, Sumerlin B S. Chem Rev, 2016, 116(3): 1375-1397. doi:10.1021/acs.chemrev.5b00300http://dx.doi.org/10.1021/acs.chemrev.5b00300

He Liu(何柳), Wei Wenkang(魏文康), Luo Yu(罗雨), Xu Yiting(许一婷), Zeng Birong(曾碧榕), Luo Weiang(罗伟昂), Chen Guorong(陈国荣), Yuan Conghui(袁丛辉), Dai Lizong(戴李宗). Chinese Science Bulletin(科学通报), 2021, 66(10): 1208-1219. doi:10.1360/tb-2020-1328http://dx.doi.org/10.1360/tb-2020-1328

Lorand J P, Edwards J O. J Org Chem, 1959, 24(6): 769-774. doi:10.1021/jo01088a011http://dx.doi.org/10.1021/jo01088a011

Springsteen G, Wang B. Tetrahedron, 2002, 58(26): 5291-5300. doi:10.1016/s0040-4020(02)00489-1http://dx.doi.org/10.1016/s0040-4020(02)00489-1

Yan J, Springsteen G, Deeter S, Wang B. Tetrahedron, 2004, 60(49): 11205-11209. doi:10.1016/j.tet.2004.08.051http://dx.doi.org/10.1016/j.tet.2004.08.051

Yuan C, Chang Y, Mao J, Yu S, Luo W, Xu Y, Thayumanavan S, Dai L. J Mater Chem B, 2015, 3(14): 2858-2866. doi:10.1039/c4tb01880jhttp://dx.doi.org/10.1039/c4tb01880j

Yuan C, Hong B, Chang Y, Mao J, Li Y, Xu Y, Zeng B, Luo W, Gérard J F, Dai L. ACS Appl Mater Interfaces, 2017, 9(17): 14700-14708. doi:10.1021/acsami.7b02252http://dx.doi.org/10.1021/acsami.7b02252

Wu X, Li Z, Chen X X, Fossey J S, James T D, Jiang Y B. Chem Soc Rev, 2013, 42(20): 8032-8048. doi:10.1039/c3cs60148jhttp://dx.doi.org/10.1039/c3cs60148j

Ma R, Shi L. Polym Chem, 2014, 5(5): 1503-1518. doi:10.1039/c3py01202fhttp://dx.doi.org/10.1039/c3py01202f

Yang Bohan(杨伯涵), Zhao Waiou(赵外鸥), Li Caijin(李采金), Li Yapeng(李亚鹏), Wang Jingyuan(王静媛). Acta Polymerica Sinica(高分子学报), 2014, (5): 636-642. doi:10.3724/SP.J.1105.2014.13336http://dx.doi.org/10.3724/SP.J.1105.2014.13336

Côté A P, Benin A I, Ockwig N W, OʹKeeffe M, Matzger A J, Yaghi O M. Science, 2005, 310(5751): 1166-1170 doi:10.1126/science.1120411http://dx.doi.org/10.1126/science.1120411

Li L, Yuan C, Dai L, Thayumanavan S. Macromolecules, 2014, 47(17): 5869-5876. doi:10.1021/ma5015808http://dx.doi.org/10.1021/ma5015808

Iwasawa N, Takahagi H. J Am Chem Soc, 2007, 129(25): 7754-7755. doi:10.1021/ja072319qhttp://dx.doi.org/10.1021/ja072319q

Liu C, Shen W, Li B, Li T, Chang H, Cheng Y. Chem Mater, 2019, 31(6): 1956-1965. doi:10.1021/acs.chemmater.8b04672http://dx.doi.org/10.1021/acs.chemmater.8b04672

Yuan C, Wu T, Mao J, Chen T, Li Y, Li M, Xu Y, Zeng B, Luo W, Yu L, Zheng G, Dai L. J Am Chem Soc, 2018, 140(24): 7629-7636. doi:10.1021/jacs.8b03010http://dx.doi.org/10.1021/jacs.8b03010

Huang J, Liu Y, Yang Y, Zhou Z, Mao J, Wu T, Liu J, Cai Q, Peng C, Xu Y, Zeng B, Luo W, Chen G, Yuan C, Dai L. Sci Robot, 2021, 6(53): eabe1858. doi:10.1126/scirobotics.abe1858http://dx.doi.org/10.1126/scirobotics.abe1858

Li L, Yuan C, Zhou D, Ribbe A E, Kittilstved K R, Thayumanavan S. Angew Chem, 2015, 127(44): 13183-13187. doi:10.1002/ange.201505242http://dx.doi.org/10.1002/ange.201505242

Mao J, Li Y, Cai Q, Tang Z, Yang Y, Yuan C, Xu Y, Zeng B, Luo W, Kuo S, Dai L. Chem Eng J, 2021, 405: 126690. doi:10.1016/j.cej.2020.126690http://dx.doi.org/10.1016/j.cej.2020.126690

Wu Y, Cai Q, Li Y, Liu H, Mao J, Lu Z, Zeng B, Xu Y, Yuan C, Dai L. J Alloy Compd, 2020, 824: 153655. doi:10.1016/j.jallcom.2020.153655http://dx.doi.org/10.1016/j.jallcom.2020.153655

Wu T, Hong J, Lu Z, Wu H, Wu C, Tang Z, Liu X, Zeng B, Xu Y, Chen G, Yuan C, Dai L. Appl Catal B-Environ, 2021, 285: 119795. doi:10.1016/j.apcatb.2020.119795http://dx.doi.org/10.1016/j.apcatb.2020.119795

Lee B P, Konst S. Adv Mater, 2014, 26(21): 3415-3419. doi:10.1002/adma.201306137http://dx.doi.org/10.1002/adma.201306137

Lee B P, Narkar A, Wilharm R. Sensor Actuat B-Chem, 2016, 227: 248-254. doi:10.1016/j.snb.2015.12.038http://dx.doi.org/10.1016/j.snb.2015.12.038

Golden E B, Lam P Y, Kardosh A, Gaffney K J, Cadenas E, Louie S G, Petasis N A, Chen T C, Schönthal A H. Blood, 2009, 113(23): 5927-5937. doi:10.1182/blood-2008-07-171389http://dx.doi.org/10.1182/blood-2008-07-171389

Wang C, Sang H, Wang Y, Zhu F, Hu X, Wang X, Wang X, Li Y, Cheng Y. Nano Lett, 2018, 18(11): 7045-7051. doi:10.1021/acs.nanolett.8b03015http://dx.doi.org/10.1021/acs.nanolett.8b03015

Liu R, Guo Y, Odusote G, Qu F, Priestley R D. ACS Appl Mater Interfaces, 2013, 5(18): 9167-9171. doi:10.1021/am402585yhttp://dx.doi.org/10.1021/am402585y

Moulay S. Polym Rev, 2014, 54(3): 436-513. doi:10.1080/15583724.2014.881373http://dx.doi.org/10.1080/15583724.2014.881373

Zhao Han(赵晗), Shang Qing(尚晴), Yang Meng(杨萌), Jin Shuai(金帅), Wang Yangyang(王洋洋), Zhao Ning(赵宁), Yin Pinxiao(尹品晓), Ding Cailing(丁彩玲), Xu Jian(徐坚). Acta Polymerica Sinica(高分子学报), 2020, 51(3): 287-294. doi:10.11777/j.issn1000-3304.2019.19208http://dx.doi.org/10.11777/j.issn1000-3304.2019.19208

Ejima H, Richardson J J, Liang K, Best J P, van Koeverden M P, Such G K, Cui J, Caruso F. Science, 2013, 341(6142): 154-157. doi:10.1126/science.1237265http://dx.doi.org/10.1126/science.1237265

Wei Q, Achazi K, Liebe H, Schulz A, Noeske P L M, Grunwald I, Haag R. Angew Chem Int Ed, 2014, 53(43):11650-11655. doi:10.1002/anie.201407113http://dx.doi.org/10.1002/anie.201407113

Li D, Yang Z, Yang J, Xu X, Wang X, Wang J, Wang W, Yang X, Chen J, Zhao N, Xu J. Chem Eng J, 2022, 429: 132363. doi:10.1016/j.cej.2021.132363http://dx.doi.org/10.1016/j.cej.2021.132363

Chang Y, Yuan C, Li Y, Liu C, Wu T, Zeng B, Xu Y, Dai L. J Mater Chem A, 2017, 5(4): 1672-1678. doi:10.1039/c6ta09239jhttp://dx.doi.org/10.1039/c6ta09239j

Zhang H, Mao J, Li M, Cai Q, Li W, Huang C, Yuan C, Xu Y, Zeng B, Dai L. Compos Part A-Appl S, 2020, 130: 105751. doi:10.1016/j.compositesa.2019.105751http://dx.doi.org/10.1016/j.compositesa.2019.105751

Liu S, Pan J, Liu J, Ma Y, Qiu F, Mei L, Zeng X, Pan G. Small, 2018, 14(13): 1703968. doi:10.1002/smll.201703968http://dx.doi.org/10.1002/smll.201703968

Guo J, Sun H, Alt K, Tardy B L, Richardson J J, Suma T, Ejima H, Cui J, Hagemeyer C E, Caruso F. Adv Healthc Mater, 2015, 4(12): 1796-1801. doi:10.1002/adhm.201500332http://dx.doi.org/10.1002/adhm.201500332

Narkar A R, Kendrick C, Bellur K, Leftwich T, Zhang Z, Lee B P. Soft Matter, 2019, 15(27): 5474-5482. doi:10.1039/c9sm00649dhttp://dx.doi.org/10.1039/c9sm00649d

Peng H, Wang D, Fu S. Compos Part B-Eng, 2021, 215: 108742. doi:10.1016/j.compositesb.2021.108742http://dx.doi.org/10.1016/j.compositesb.2021.108742

Cheng M, Zhang Q, Shi F. Chinese J Polym Sci, 2018, 36: 306-321. doi:10.1007/s10118-018-2069-zhttp://dx.doi.org/10.1007/s10118-018-2069-z

Yang J, Bai R, Chen B, Suo Z. Adv Funct Mater, 2020, 30(2): 1901693. doi:10.1002/adfm.201901693http://dx.doi.org/10.1002/adfm.201901693

Cheng M, Shi F. Chem-Eur J, 2020, 26(68): 15763-15778. doi:10.1002/chem.202001881http://dx.doi.org/10.1002/chem.202001881

Saiz-Poseu J, Mancebo-Aracil J, Nador F, Busqué F, Ruiz-Molina D. Angew Chem Int Ed, 2019, 58(3): 696-714. doi:10.1002/anie.201801063http://dx.doi.org/10.1002/anie.201801063

Narkar A R, Barker B, Clisch M, Jiang J, Lee B P. Chem Mater, 2016, 28(15): 5432-5439. doi:10.1021/acs.chemmater.6b01851http://dx.doi.org/10.1021/acs.chemmater.6b01851

Narkar A R, Lee B P. Langmuir, 2018, 34(32): 9410-9417. doi:10.1021/acs.langmuir.8b00373http://dx.doi.org/10.1021/acs.langmuir.8b00373

Graule M A, Chirarattananon P, Fuller S B, Jafferis N T, Ma K Y, Spenko M, Kornbluh R, Wood R J. Science, 2016, 352(6288): 978-982. doi:10.1126/science.aaf1092http://dx.doi.org/10.1126/science.aaf1092

Fujita M, Ikeda S, Fujimoto T, Shimizu T, Ikemoto S, Miyamoto T. Adv Robotics, 2018, 32(6): 283-296. doi:10.1080/01691864.2018.1447238http://dx.doi.org/10.1080/01691864.2018.1447238

Jiang H, Hawkes E W, Fuller C, Estrada M A, Suresh S A, Abcouwer N, Han A K, Wang S, Ploch C J, Parness A, Cutkosky M R. Sci Robot, 2017, 2(7): eaan4545. doi:10.1126/scirobotics.aan4545http://dx.doi.org/10.1126/scirobotics.aan4545

Bhuiyan M S A, Liu B, Manuel J, Zhao B, Lee B P. Biomacromolecules, 2021, 22(9): 4004-4015. doi:10.1021/acs.biomac.1c00802http://dx.doi.org/10.1021/acs.biomac.1c00802

Zhang Y S, Khademhosseini A. Science, 2017, 356(6337): eaaf3627. doi:10.1126/science.aaf3627http://dx.doi.org/10.1126/science.aaf3627

Liu J, Huang J, Cai Q, Yang Y, Luo W, Zeng B, Xu Y, Yuan C, Dai L. ACS Appl Mater Interfaces, 2020, 12(18): 20479-20489. doi:10.1021/acsami.0c03224http://dx.doi.org/10.1021/acsami.0c03224

Zhang Y Z, Lee K H, Anjum D H, Sougrat R, Jiang Q, Kim H, Alshareef H N. Sci Adv, 2018, 4(6): eaat0098. doi:10.1126/sciadv.aat0098http://dx.doi.org/10.1126/sciadv.aat0098

Shan M, Gong C, Li B, Wu G. Polym Chem, 2017, 8(19): 2997-3005. doi:10.1039/c7py00519ahttp://dx.doi.org/10.1039/c7py00519a

Chen J, Su Q, Guo R, Zhang J, Dong A, Lin C, Zhang J. Macromol Chem Phys, 2017, 218(15): 1700166. doi:10.1002/macp.201770046http://dx.doi.org/10.1002/macp.201770046

Nakahata M, Mori S, Takashima Y, Hashidzume A, Yamaguchi H, Harada A. ACS Macro Lett, 2014, 3(4): 337-340. doi:10.1021/mz500035whttp://dx.doi.org/10.1021/mz500035w

Xia N N, Rong M Z, Zhang M Q. J Mater Chem A, 2016, 4(37): 14122-14131. doi:10.1039/c6ta05121ahttp://dx.doi.org/10.1039/c6ta05121a

Lu J, Zhuang W, Li L, Zhang B, Yang L, Liu D, Yu H, Luo R, Wang Y. ACS Appl Mater Interfaces, 2019, 11(10): 10337-10350. doi:10.1021/acsami.9b01253http://dx.doi.org/10.1021/acsami.9b01253

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