有机催化CO<sub>2</sub>/环氧/酸酐交替共聚合成聚碳酸酯/聚酯及其共聚物

马钰琨; 刘绍峰; 李志波

doi:10.11777/j.issn1000-3304.2022.22112

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有机催化CO₂/环氧/酸酐交替共聚合成聚碳酸酯/聚酯及其共聚物

专论 | 更新时间：2024-10-08

- 有机催化CO₂/环氧/酸酐交替共聚合成聚碳酸酯/聚酯及其共聚物
- Organocatalytic Alternating Copolymerization of CO₂/Epoxide/Anhydride for Synthesis of Polycarbonate/Polyester Copolymers
- 高分子学报 2022年53卷第9期页码：1041-1056
- 作者机构：
  
  1.青岛科技大学，高分子科学与工程学院山东省教育厅生物基高分子材料重点实验室，青岛 266042
  2.青岛科技大学，化工学院，青岛 266042
- 作者简介：
  
  [ "刘绍峰，男，1984年生. 2005年于中南大学化学化工学院获得学士学位；2011年，中国科学院化学研究所和法国斯特拉斯堡大学获博士学位. 2011~2014年，美国西北大学化学系从事博士后研究；2015年至今，青岛科技大学高分子科学与工程学院工作，任教授、博士生导师. 主要从事聚烯烃金属催化剂和开环聚合有机催化剂的设计合成，及其制备高性能聚烯烃、聚酯等高分子材料." ]
  [ "李志波，男，1974年生. 1998和2001年于中国科学技术大学高分子科学与工程系分别获得学士学位和硕士学位；2006年于美国明尼苏达大学化学系获博士学位. 2006~2008年，美国加利福尼亚大学洛杉矶分校生物工程系博士后；2008~2014年，中国科学院化学研究所高分子物理与化学实验室工作，任研究员、博士生导师；2014年12月至今，任青岛科技大学高分子科学与工程学院教授. 主要从事可降解高分子材料的设计、合成与结构表征研究，致力于发展新的合成聚合方法和催化剂，制备高性能、高附加值的功能高分子新材料." ]
- 基金信息：
  
  国家重点研究计划(2021YFA1500095);国家自然科学基金(基金号 22031005)
- DOI：10.11777/j.issn1000-3304.2022.22112
  中图分类号：
- 纸质出版日期：2022-09-20，
  
  网络出版日期：2022-07-13，
  
  收稿日期：2022-04-04，
  
  录用日期：2022-05-07
- 稿件说明：
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马钰琨,刘绍峰,李志波.有机催化CO₂/环氧/酸酐交替共聚合成聚碳酸酯/聚酯及其共聚物[J].高分子学报,2022,53(09):1041-1056.

Ma Yu-kun,Liu Shao-feng,Li Zhi-bo.Organocatalytic Alternating Copolymerization of CO₂/Epoxide/Anhydride for Synthesis of Polycarbonate/Polyester Copolymers[J].ACTA POLYMERICA SINICA,2022,53(09):1041-1056.
马钰琨,刘绍峰,李志波.有机催化CO₂/环氧/酸酐交替共聚合成聚碳酸酯/聚酯及其共聚物[J].高分子学报,2022,53(09):1041-1056. DOI： 10.11777/j.issn1000-3304.2022.22112.

Ma Yu-kun,Liu Shao-feng,Li Zhi-bo.Organocatalytic Alternating Copolymerization of CO₂/Epoxide/Anhydride for Synthesis of Polycarbonate/Polyester Copolymers[J].ACTA POLYMERICA SINICA,2022,53(09):1041-1056. DOI： 10.11777/j.issn1000-3304.2022.22112.

摘要

发展环境友好高分子材料符合当代绿色及可持续发展的理念，同时也是解决目前环境问题的有效途径之一. 二氧化碳(CO

)来源广泛且无毒，却是造成温室效应的主要气体. 利用CO

和环氧交替共聚可以制备聚碳酸酯材料，而环氧和酸酐交替共聚则可以制备聚酯材料. 聚碳酸酯/聚酯高分子材料在人们生活的诸多方面(食品包装和生物医药等)有着广泛的应用. 有机催化剂作为一种新兴的“无金属”催化剂，在近20年中发展迅速且独具特色. 近年来，我们课题组开发了一系列有机磷腈催化剂，其碱性和分子结构可调控，能够高效地催化各类环状单体的开环聚合，制备聚酯、聚醚、聚硅氧烷、聚碳酸酯等多种高分子材料. 此外，有机磷腈催化剂与路易斯酸等相结合，能够方便地构筑组成多样化的二元有机催化体系，通过协同催化效应实现独特的催化性能. 本专论主要包括CO

/环氧交替共聚制备聚碳酸酯、环氧/酸酐交替共聚制备聚酯、混合单体三元共聚制备聚碳酸酯/聚酯共聚物3个部分. 根据催化体系的不同，分别介绍了近年来有机催化CO

/环氧/酸酐交替共聚合成聚碳酸酯/聚酯及其共聚物的研究进展，对聚合机理进行了适当的解释和讨论，并展望了该领域未来的发展，包括新型高效高选择性有机催化剂、新型单体和可持续高分子材料等方向.

Abstract

The synthesis of environment-friendly polymer materials

including polycarbonates and polyesters

supports the strategy of sustainable development

and it is also one of the feasible ways to solve the current environmental stress (greenhouse effect and white pollution

etc

.). Carbon dioxide (CO

) has a wide range of sources and is non-toxic

but it could cause the greenhouse effect. Therefore

developing efficient techniques to transform CO

into value-added chemicals is a promising solution for our sustainable society. CO

-based polycarbonate materials can be prepared by ring-opening alternating copolymerization (ROCOP) of CO

and epoxide

while polyester materials can be prepared by ROCOP of epoxide and anhydride. Organocatalysts

as a type of emerging "metal-free" catalysts

have developed rapidly in the past 20 years and exhibited unique properties and exceptional promises for various polymerization reactions. Recently

our group have developed a series of organic phosphazenes

which are a family of extremely strong

non-nucleophilic

and uncharged auxiliary bases and show remarkable potential as organocatalysts for ring-opening polymerization (ROP) of cyclic monomers. On the other hand

phosphazenes in combination with a Lewis acid

such as triethyleborane (TEB)

can easily construct diverse binary organocatalysts that exhibite excellent catalytic performances. Apparently

organocatalytic synthesis of polymer materials has become an important and hot research topic. This feature article reviews the recent progress in the field of ROCOP of CO

/epoxide/anhydride catalysed by organocatalysts followed by a proper discussion of respective polymerization mechanisms. The review includes three sub-topics

i.‍e.

ROCOP of CO

/epoxide

ROCOP of epoxide/anhydride

and terpolymerization of CO

/epoxide/anhydride. A short perspective viewpoint is provided at the end for readers who are interested in this area.

关键词

有机催化剂开环聚合交替共聚聚碳酸酯聚酯

Keywords

OrganocatalystRing-opening polymerizationAlternating copolymerizationPolycarbonatePolyeste

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有机催化CO2/环氧/酸酐交替共聚合成聚碳酸酯/聚酯及其共聚物

Organocatalytic Alternating Copolymerization of CO2/Epoxide/Anhydride for Synthesis of Polycarbonate/Polyester Copolymers

DOI：10.11777/j.issn1000-3304.2022.22112

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有机催化CO₂/环氧/酸酐交替共聚合成聚碳酸酯/聚酯及其共聚物

Organocatalytic Alternating Copolymerization of CO₂/Epoxide/Anhydride for Synthesis of Polycarbonate/Polyester Copolymers