铁、钴金属配合物催化1,3-二烯烃聚合研究进展

侯森垚; 郝修歌; 姜辉; 郝新奇; 宋毛平

doi:10.11777/j.issn1000-3304.2022.22153

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铁、钴金属配合物催化1,3-二烯烃聚合研究进展

综述 | 更新时间：2023-05-22

- 铁、钴金属配合物催化1,3-二烯烃聚合研究进展
- Progress in the Polymerization of 1,3-Diene Catalyzed by Fe and Co Metal Complexes
- 高分子学报 2023年54卷第2期页码：186-205
- 作者机构：
  
  郑州大学化学学院郑州 450001
- 作者简介：
  
  [ "姜辉，男，1988 年生. 郑州大学化学学院直聘副教授，硕士生导师. 2010 年本科毕业于郑州大学化学系. 2016 年于中国农业大学应用化学系获博士学位. 2014~2016 年获国家留学基金委全额资助在美国宾夕法尼亚大学化学系访问学习. 2016~2019 年，南方科技大学化学系博士后. 2019 年入职郑州大学化学学院. 主要研究兴趣：金属及有机小分子催化串联反应，烯烃聚合反应研究." ]
  [ "宋毛平，男，1957 年生. 1981 年本科毕业于郑州大学化学系. 1992 年毕业于南京大学化学系有机化学专业，获博士学位. 1996~1998 年在美国堪萨斯大学化学系从事博士后研究.2001~2002 年，美国马里兰大学高级访问学者. 现任郑州大学化学学院二级教授、博士生导师、郑州大学分子选控构筑与应用研究所首席顾问、河南省跨世纪学术带头人、河南省省管优秀专家，享受国务院政府特殊津贴. 曾任第十届国家督学、中国化学会理事、河南省化学会理事长.主要从事催化与不对称反应、金属有机化学，迄今在《J. Am. Chem. Soc.》《Angew. Chem. Int. Ed.》《Chem. Sci.，Acs Catal.》《Org. Lett.》《Adv. Synth. Catal.》等刊物上发表学术论文120 余篇. 主持包括NSFC-河南联合基金重点支持项目，国家自然科学基金面上项目等多项国家级科研项目，授权发明专利20 余项.反应研究." ]
- 基金信息：
  
  国家自然科学基金(基金号 ┣21803059);U1904212, U2004191┫;河南省自然科学基金(基金号 ┣202300410477);222300420294┫;中国博士后基金(基金号 2020M672260)
- DOI：10.11777/j.issn1000-3304.2022.22153
  中图分类号：
- 纸质出版日期：2023-02-20，
  
  网络出版日期：2022-11-17，
  
  收稿日期：2022-07-20，
  
  录用日期：2022-10-08
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侯森垚,郝修歌,姜辉等.铁、钴金属配合物催化1,3-二烯烃聚合研究进展[J].高分子学报,2023,54(02):186-205.

Hou Sen-yao,Hao Xiu-ge,Jiang Hui,et al.Progress in the Polymerization of 1,3-Diene Catalyzed by Fe and Co Metal Complexes[J].ACTA POLYMERICA SINICA,2023,54(02):186-205.
侯森垚,郝修歌,姜辉等.铁、钴金属配合物催化1,3-二烯烃聚合研究进展[J].高分子学报,2023,54(02):186-205. DOI： 10.11777/j.issn1000-3304.2022.22153.

Hou Sen-yao,Hao Xiu-ge,Jiang Hui,et al.Progress in the Polymerization of 1,3-Diene Catalyzed by Fe and Co Metal Complexes[J].ACTA POLYMERICA SINICA,2023,54(02):186-205. DOI： 10.11777/j.issn1000-3304.2022.22153.

摘要

3-二烯烃类单体聚合物性能优异，在橡胶工业中占据重要地位. 以1

3-丁二烯为单体的顺丁橡胶在工业中可生产多种橡胶制品，以异戊二烯为单体的异戊橡胶因其结构与天然橡胶相似，在一些领域可替代天然橡胶. 1

3-二烯类聚烯烃材料的发展大大依赖于聚烯烃催化剂的不断创新. 在过去的10年中，铁、钴催化剂因其原材料廉价、配位类型丰富、合成简便、性质稳定等优良特性受到了广泛关注. 通过对催化剂的配体结构进行合理设计和调整，能控制聚合物的微观结构、分子量，从而改变聚合产物的性能. 本文综述了近10年来铁、钴配合物催化1

3-二烯烃聚合的研究进展，详细讨论了催化剂结构对催化活性、聚合物分子量、聚合物微观结构和聚合物分子量分布的影响.

Abstract

Polymers of 1

3-diene monomers have excellent properties and play an important role in rubber industry. Polymers of 1

3-diene monomers is synthesized from 1

3-butadiene

and it can be fabricated into a variety of rubber products

while isoprene rubber can replace natural rubber in some fields due to its similar chemical structure with natural rubber. The key to the polymerization of 1

3-diene monomers is the catalyst. In the past decade

iron and cobalt catalysts have received much attention due to their excellent properties such as inexpensive raw materials

abundant ligand types

simple synthesis and stable properties. Rational design and synthesis of the catalyst structures has enabled good control over the stereoselectivity

molecular weight

and thus improve their performance of the polymerization product. This paper reviews the research progress of iron and cobalt complex-catalyzed 1

3-diene polymerization in the last decade and discusses in detail the influence of catalyst structure on catalytic activity

polymer molecular weight

polymer microstructure and polymer molecular weight dispersity.

关键词

铁配合物钴配合物13-二烯异戊二烯13-丁二烯

Keywords

Iron complexesCobalt complexes13-DieneIsoprene13-Butadiene

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