聚合物可逆互锁网络的设计、制备和应用初探

犹阳; 容敏智; 章明秋

doi:10.11777/j.issn1000-3304.2022.22196

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聚合物可逆互锁网络的设计、制备和应用初探

专论 | 更新时间：2023-05-22

- 聚合物可逆互锁网络的设计、制备和应用初探
- Reversibly Interlocked Polymer Networks: Design, Preparation and Applications
- 高分子学报 2023年54卷第1期页码：14-36
- 作者机构：
  
  1.贵州大学材料与冶金学院贵阳 550025
  2.中山大学化学学院聚合物复合材料及功能材料教育部重点实验室广州 510275
- 作者简介：
  
  [ "容敏智，男，1961年生. 1983和1986年于天津大学分别获得学士和硕士学位，1994年于中山大学获得博士学位. 2001年起任中山大学化学院教授. 现兼任广东省复合材料学会副理事长. 围绕高分子材料学科的基础与应用科学问题，对高分子合成、共混物及树脂基复合材料等开展了广泛的研究，近年来的研究领域涉及聚合物网络的结构与性能、反应性共混及热固性树脂改性、高分子精细化学品与精细化工技术、天然纤维复合材料、自愈合型高分子材料、聚合物基纳米粒子复合材料等. E-mail: cesrmz@mail.sysu.edu.cn;" ]
  [ "章明秋，男，1961年生. 1982和1991年于中山大学分别获得学士和博士学位；1992年起任中山大学化学院教授. 长期从事高分子及高分子复合材料的科研与教学，研究方向主要包括高分子材料、高分子共混物和高分子复合材料的结构与性能关系、表征技术与功能化应用等，内容涉及高分子材料和增强聚合物复合材料的力学性能，纳米粒子表面改性和纳米粒子/高分子复合材料，植物基复合材料，复合材料中的界面结构，高分子物理，导电复合材料，减摩耐磨复合材料，自修复型智能高分子复合材料等. Email: ceszmq@mail.sysu.edu.cn" ]
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2022.22196
  中图分类号：
- 纸质出版日期：2023-01-20，
  
  网络出版日期：2022-09-27，
  
  收稿日期：2022-05-23，
  
  录用日期：2022-06-20
扫描看全文
犹阳,容敏智,章明秋.聚合物可逆互锁网络的设计、制备和应用初探[J].高分子学报,2023,54(01):14-36.

You Yang,Rong Min-zhi,Zhang Ming-qiu.Reversibly Interlocked Polymer Networks: Design, Preparation and Applications[J].ACTA POLYMERICA SINICA,2023,54(01):14-36.
犹阳,容敏智,章明秋.聚合物可逆互锁网络的设计、制备和应用初探[J].高分子学报,2023,54(01):14-36. DOI： 10.11777/j.issn1000-3304.2022.22196.

You Yang,Rong Min-zhi,Zhang Ming-qiu.Reversibly Interlocked Polymer Networks: Design, Preparation and Applications[J].ACTA POLYMERICA SINICA,2023,54(01):14-36. DOI： 10.11777/j.issn1000-3304.2022.22196.

摘要

聚合物复合体系是聚合物材料重要的应用形式，发展能够充分抑制相分离的多组分聚合物复合体系制备新技术有着重要意义. 利用动态交联聚合物网络拓扑结构的可逆变换，可以使不同交联聚合物网络间的分子链扩散与混合成为可能，待混合完全后再通过动态可逆共价键闭合来重筑交联网络，最终得到由不同子网络穿插互锁形成的均匀复合交联网络，即聚合物可逆互锁网络，其中的子网络之间没有共价键连接，具有相对的独立性. 本文由聚合物可逆互锁网络的设计制备出发，阐述了相关方法的概念、原理和所得材料的结构特点，介绍了基于聚合物可逆互锁网络策略的聚合物材料高性能化与功能化应用实例，内容包括提升和调控力学性能、宽pH水环境中的自修复、增进本征导热率、固态聚合物电解质的优化、多组分聚合物复合体系的可控分离与可控降解以及闭环循环利用等，同时分析了与聚合物互穿网络(IPNs)的区别，最后对这类材料未来可能的发展进行了分析和展望.

Abstract

Combining different polymers together to obtain multi-component polymer systems is an important and effective method for developing novel polymeric materials and regulating their properties. However

the synergistic effect between different components can hardly play its full role because of the ubiquitous phase separation. To solve this problem

we developed a novel strategy to prepare multi-component polymer systems as follows

in which phase separation can be suppressed. Firstly

two covalent adaptive networks respectively containing orthogonal reversible covalent bonds were synthesized. Next

the two single networks were dissolved in a co-solvent under proper stimulus as a result of the reversible reactions of the included reversible bonds. Accordingly

the solutions with the fragments of the single networks can be well mixed

and the latter were allowed to be reconstructed together through topological rearrangement with the assistance of inter-component secondary interactions during removal of the stimulus and co-solvent. Eventually

co-networks with relative independence

i.e.

reversibly interlocked polymer networks

were obtained. Owing to the forced miscibility effect induced by the interlocked structure

even immiscible polymer pairs can be homogeneously interlaced with each other. In this context

there would be more freedom to choose the raw materials

and versatile multi-component polymer systems with high performance and novel functionalities can be developed. The paper introduces the material design and general preparation method of reversibly interlocked polymer networks. Afterwards

the structural features of the interlocked polymer networks

and a few applications of this type of material

including enhancement and regulation of mechanical properties

wide pH range underwater self-healability

improvement of intrinsic thermal conductivity

optimization of polymeric solid phase electrolyte

and controllable isolation/degradation and close-loop recycling of multi-component polymer systems

are discussed. Lastly

the difference between the interlocked networks and interpenetrating polymer networks (IPNs) is analyzed

and the future development in this aspect is prospected.

关键词

多组分聚合物复合体系聚合物可逆互锁网络动态可逆共价键拓扑结构重排

Keywords

Multi-component polymer systemsReversibly interlocked polymer networksDynamic covalent bondsTopological rearrangement

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