基于热活化敏化荧光机制的有机发光二极管材料与器件

张海; 张东东; 段炼

doi:10.11777/j.issn1000-3304.2022.22446

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基于热活化敏化荧光机制的有机发光二极管材料与器件

专论 | 更新时间：2023-05-31

- 基于热活化敏化荧光机制的有机发光二极管材料与器件
- Materials and Devices of Thermally Activated Sensitized Fluorescence Organic Light-emitting Diodes
- 高分子学报 2023年54卷第6期页码：943-961
- 作者机构：
  
  有机光电子与分子工程教育部重点实验室清华大学化学系北京 100084
- 作者简介：
  
  [ "张东东，男，1989年生. 2011年，吉林大学获学士学位；2016年，清华大学化学系获博士学位；2019年至今，清华大学化学系有机光电子与分子工程教育部重点实验室工作，任助理研究员. 2016年获清华大学优秀博士学位论文奖，2019年获中国科协“青年人才托举工程”项目资助，2022年获国家自然科学基金优秀青年科学基金资助. 主要从事有机高分子发光材料的合成化学与性能研究. E-mail: ddzhang@mail.tsinghua.edu.cn" ]
- 基金信息：
  
  国家自然科学基金(基金号52222308;51903137┫资助项目‍)
- DOI：10.11777/j.issn1000-3304.2022.22446
  中图分类号：
- 纸质出版日期：2023-06-20，
  
  网络出版日期：2023-03-10，
  
  收稿日期：2022-12-26，
  
  录用日期：2023-01-19
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张海,张东东,段炼.基于热活化敏化荧光机制的有机发光二极管材料与器件[J].高分子学报,2023,54(06):943-961.

Zhang Hai,Zhang Dong-dong,Duan Lian.Materials and Devices of Thermally Activated Sensitized Fluorescence Organic Light-emitting Diodes[J].ACTA POLYMERICA SINICA,2023,54(06):943-961.
张海,张东东,段炼.基于热活化敏化荧光机制的有机发光二极管材料与器件[J].高分子学报,2023,54(06):943-961. DOI： 10.11777/j.issn1000-3304.2022.22446.

Zhang Hai,Zhang Dong-dong,Duan Lian.Materials and Devices of Thermally Activated Sensitized Fluorescence Organic Light-emitting Diodes[J].ACTA POLYMERICA SINICA,2023,54(06):943-961. DOI： 10.11777/j.issn1000-3304.2022.22446.

摘要

热活化敏化荧光(TSF)被称作有机发光二极管(OLED)“第四代发光技术”，是以热活化延迟荧光材料作为敏化剂，高效发光的荧光材料作为掺杂染料，通过二者之间高效的Förster能量传递实现100%激子利用，突破了三线态高效上转换与单线态高效辐射跃迁之间的矛盾. 本文围绕TSF-OLED器件的发光效率、寿命及光色等核心指标，针对激子的调控和利用这一关键科学问题，重点介绍了我们课题组近年来在TSF技术的机理研究、高效稳定敏化剂及窄光谱材料的设计开发以及高性能器件的构筑等方面的研究工作. 最后讨论了TSF技术所存在的挑战和未来发展前景.

Abstract

Thermally activated sensitized fluorescence (TSF) with thermally activated delayed fluorescence materials (TADF) as sensitizers and highly efficient conventional fluorescent dopants (CFD) as emitters was called the "fourth-generation luminescence technology" of organic light-emitting diodes (OLEDs)

which can achieve 100% exciton utilization with low efficiency roll-off and narrowband emission simultaneously

compared with the traditional TADF emitters. The functionally separated materials of TSF-OLEDs are connected with each other by the rapid Förster energy transfer between sensitizer and dopant

further breaking the trade-off between effective up-conversion of triplet and impressive radiative decay of singlet. Herein

focusing on the keystone about how to realize the precise modulation and efficient utilization of excitons generated from carriers recombination

we systematically summarize the recent research progress of TSF in our group from the perspective of the efficiency

lifetime and purity of TSF-OLEDs. Starting from the luminescent mechanism of the TSF-OLEDs

we display some methods which can restrict the energy loss pathways to improve efficiency and suppress efficiency roll-off. Meanwhile

a series of sensitizers with through-space charge transfer characteristic and high stability of blue emission

and the designing strategies of many narrowband emitters including BN-MR

BODIPY and Indolocarbazole are illustrated. In addition

the construction of white-emission devices with high performance is demonstreted. Finally

the challenges and opportunities for the future development in TSF-OLEDs are also discussed.

关键词

热活化敏化荧光热活化延迟荧光敏化剂窄光谱染料

Keywords

Thermally activated sensitized fluorescenceThermally activated delayed fluorescenceSensitizerNarrowband emitter

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Wang X.; Zhang Y. W.; Dai H. Y.; Li G. M.; Liu M. H.; Meng G. Y.; Zeng X.; Huang T. Y.; Wang L.; Peng Q.; Yang D. Z.; Ma D. G.; Zhang D. D.; Duan L. Mesityl-functionalized multi-resonance organoboron delayed fluorescent frameworks with wide-range color tunability for narrowband OLEDs. Angew. Chem. Int. Ed., 2022, 61(38), e202206916. doi:10.1002/anie.202206916http://dx.doi.org/10.1002/anie.202206916

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Zhang C.; Lu Y.; Liu Z. Y.; Zhang Y. W.; Wang X. W.; Zhang D. D.; Duan L. A π-D and π-A exciplex-forming host for high-efficiency and long-lifetime single-emissive-layer fluorescent white organic light-emitting diodes. Adv. Mater., 2020, 32(42), e2004040. doi:10.1002/adma.202004040http://dx.doi.org/10.1002/adma.202004040

Zhang C.; Zhang D. D.; Bin Z. Y.; Liu Z. Y.; Zhang Y. W.; Lee H.; Kwon J. H.; Duan L. Color-tunable all-fluorescent white organic light-emitting diodes with a high external quantum efficiency over 30% and extended device lifetime. Adv. Mater., 2022, 34(22), e2103102. doi:10.11777/j.issn1000-3304.2022.22446http://dx.doi.org/10.11777/j.issn1000-3304.2022.22446

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