高分子基电极材料在电化学储能中的应用进展

宋子晖; 蹇锡高; 胡方圆

doi:10.11777/j.issn1000-3304.2023.23008

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高分子基电极材料在电化学储能中的应用进展

专论 | 更新时间：2023-05-31

- 高分子基电极材料在电化学储能中的应用进展
- Progress of Polymer-based Electrode Materials in Electrochemical Energy Storage
- 高分子学报 2023年54卷第6期页码：962-975
- 作者机构：
  
  1.大连理工大学材料科学与工程学院
  2.辽宁省高性能树脂材料专业技术创新中心
  3.大连理工大学精细化工国家重点实验室大连 116024
- 作者简介：
  
  [ "胡方圆，女，1986年生，大连理工大学教授、博士生导师. 2008年毕业于大连理工大学精细化工专业，获工学学士学位；2014年在大连理工大学获高分子化学与物理专业博士学位；毕业后在大连理工大学从事博士后研究. 主要从事刚性芳杂环高分子基电化学能源材料及器件构筑，深入探究其在超级电容器、钠离子电池、锂硫电池、固态电池中的应用研究. 目前担任大连理工大学材料科学与工程学院副院长，InfoMat和SusMat青年编委，2022年获国家自然科学基金优秀青年基金资助. E-mail: hufangyuan@dlut.edu.cn" ]
- 基金信息：
  
  国家自然科学基金(基金号 52222314)
- DOI：10.11777/j.issn1000-3304.2023.23008
  中图分类号：
- 纸质出版日期：2023-06-20，
  
  网络出版日期：2023-03-26，
  
  收稿日期：2023-01-06，
  
  录用日期：2023-02-14
扫描看全文
宋子晖,蹇锡高,胡方圆.高分子基电极材料在电化学储能中的应用进展[J].高分子学报,2023,54(06):962-975.

Song Zi-hui,Jian Xi-gao,Hu Fang-yuan.Progress of Polymer-based Electrode Materials in Electrochemical Energy Storage[J].ACTA POLYMERICA SINICA,2023,54(06):962-975.
宋子晖,蹇锡高,胡方圆.高分子基电极材料在电化学储能中的应用进展[J].高分子学报,2023,54(06):962-975. DOI： 10.11777/j.issn1000-3304.2023.23008.

Song Zi-hui,Jian Xi-gao,Hu Fang-yuan.Progress of Polymer-based Electrode Materials in Electrochemical Energy Storage[J].ACTA POLYMERICA SINICA,2023,54(06):962-975. DOI： 10.11777/j.issn1000-3304.2023.23008.

摘要

高效电化学活性材料是实现高性能电化学储能设备的关键核心之一. 如何在原子层次对电极材料微观结构进行精密调控，并发展有效合成策略和方法实现的结构控制合成，以提升器件电化学性能是备受关注的科学问题和基础研究的前沿. 高分子材料理化结构丰富、官能团种类可调，已成为现代工业发展中的重要基石. 特别是刚性芳杂环高分子基材料由于含有芳杂环结构，利于高温聚合且残炭率高，在碳化后具有良好的元素、形貌继承性，因此刚性芳杂环高分子基材料近年来在电化学储能领域也得到了广泛应用. 系统总结了刚性芳杂环高分子基电极材料在超级电容器、钠离子电池、锂硫电池等电化学储能器件中的应用. 并特别介绍了本课题组通过本征掺杂方式创制出的系列元素、形貌可控的高分子基电极材料. 最后，总结并展望了高分子基材料在能源领域中未来的研究方向.

Abstract

Efficient electrochemically active materials are one of the key materials for achieving high-performance electrochemical energy storage devices. How to precisely regulate the microstructure of electrode materials at the atomic level and develop effective synthesis methods to achieve structure-controlled synthesis are scientific problems of great interest and the frontier of basic research. With the advantages of rich physical and chemical structures and adjustable functional group types

polymers have become an important type of materials in modern industrial development. In particular

rigid aromatic heterocyclic polymer-based materials have been widely used in electrochemical energy storage in recent years because they contain aromatic heterocyclic structures

facilitate high-temperature polymerization

have high residual carbon rates

and have good elemental and morphological inheritance after carbonization. In this feature article

we summarized the applications of rigid aromatic heterocyclic polymer-based electrode materials in electrochemical energy storage devices such as supercapacitors

sodium-ion batteries

and lithium-sulfur batteries. In particular

we discussed a series of elemental and morphology-controlled polymer-based electrode materials created by our group through intrinsic doping. Finally

the future research directions of polymer-based materials in the field of energy are summarized and prospected.

关键词

高分子材料超级电容器钠离子电池锂硫电池芳杂环高分子

Keywords

PolymersSupercapacitorsSodium-ion batteriesLithium-sulfur batteriesAromatic heterocyclic polymers

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