自由基交替共聚法制备酰亚胺基微孔有机聚合物

戴晓璇; 雷育杰; 李士俊; 马星宇; 陈旺治; 李磊

doi:10.11777/j.issn1000-3304.2023.23085

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自由基交替共聚法制备酰亚胺基微孔有机聚合物

研究论文 | 更新时间：2023-09-25

- 自由基交替共聚法制备酰亚胺基微孔有机聚合物
  增强出版
- Preparation of Imide-based Microporous Organic Polymers by Alternating Free Radical Copolymerization
- 高分子学报 2023年54卷第10期页码：1486-1497
- 作者机构：
  
  厦门大学材料学院厦门 361005
- 作者简介：
  
  E-mail: lilei@xmu.edu.cn
- 基金信息：
  
  国家自然科学基金(基金号 22075234)
- DOI：10.11777/j.issn1000-3304.2023.23085
  中图分类号：
- 纸质出版日期：2023-10-20，
  
  网络出版日期：2023-07-11，
  
  收稿日期：2023-03-30，
  
  录用日期：2023-05-18
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戴晓璇,雷育杰,李士俊等.自由基交替共聚法制备酰亚胺基微孔有机聚合物[J].高分子学报,2023,54(10):1486-1497.

Dai Xiao-xuan,Lei Yu-jie,Li Shi-jun,et al.Preparation of Imide-based Microporous Organic Polymers by Alternating Free Radical Copolymerization[J].ACTA POLYMERICA SINICA,2023,54(10):1486-1497.
戴晓璇,雷育杰,李士俊等.自由基交替共聚法制备酰亚胺基微孔有机聚合物[J].高分子学报,2023,54(10):1486-1497. DOI： 10.11777/j.issn1000-3304.2023.23085.

Dai Xiao-xuan,Lei Yu-jie,Li Shi-jun,et al.Preparation of Imide-based Microporous Organic Polymers by Alternating Free Radical Copolymerization[J].ACTA POLYMERICA SINICA,2023,54(10):1486-1497. DOI： 10.11777/j.issn1000-3304.2023.23085.

摘要

通过Friedel-Crafts 烷基化反应发生的超交联聚合会产生大量腐蚀性气体以及废弃的Lewis酸催化剂. 为了实现微孔有机聚合物的绿色制备工艺，选用3类双马来酰亚胺单体与4种乙烯基醚单体进行自由基共聚，制备了12种新型酰亚胺基超交联微孔有机聚合物材料. 通过反应单体之间形成电荷转移配合物，可以实现自由基交替共聚. 得到的多孔聚合物具有可预测的分子结构和高比表面积(591 m

/g)，表现出优异的CO

吸附选择性(74.38)，在CO

捕获和气体分离方面具有良好的应用前景. 本研究拓展了自由基共聚超交联微孔聚合物构筑单元的选择范围，对微孔有机聚合物绿色制备具有参考价值.

Abstract

Hyper-crosslinked organic microporous polymers (HOMPs) are constructed by connecting aromatic building blocks with short carbon bridges

without lab-cost work and expensive catalysts in comparison with metal organic frameworks (MOFs)

covalent organic frameworks (COFs) and conjugated microporous polymers (CMPs) counterparts. Usually

hyper-cross-linking processes

via

Friedel-Craft alkylation reaction produce a large number of corrosive gases during reaction process and waste Lewis acid catalysts after polymerization. In order to achieve greener preparation protocol

in this study

three bismaleimide monomers (

-PBM

-PBM and DBM) and four vinyl ethers (DOE

DVE

TVE and TAE) are employed as building blocks for radical polymerization

and twelve cross-linked porous polyimides have been successfully prepared. Thanks to the opposite polarity structure

the alternating copolymerization between the above donor and acceptor monomers is very likely to occur due to the formation of charge-transfer complexes

endowing the obtained polymers with predictable and controllable molecular architectures. In addition

only trace amounts of initiator are required for radical copolymerization and no by-products are generated

which greatly simplify the post-processing of the polymers. The highly polar imine rings and abundant microporous structure provide the products good thermal stability

high specific surface area (591 m

/g)

and excellent CO

selectivity (74.38). This study benefits for exploring new building blocks to construct microporous polymers and probe their practical applications.

关键词

自由基交替共聚微孔聚酰亚胺超交联聚合物CO2捕获和存储

Keywords

Radical alternating copolymerizationPorous polyimidesHyper-crosslinked polymersCarbon dioxide (CO2) capture and storage

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