基于二氧化碳响应的聚合物及复合材料的构建与功能

周硕; 杨松铭; 袁金颖

doi:10.11777/j.issn1000-3304.2023.23113

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基于二氧化碳响应的聚合物及复合材料的构建与功能

专论 | 更新时间：2023-09-25

- 基于二氧化碳响应的聚合物及复合材料的构建与功能
- Construction and Function of CO₂-Switchable Polymers and Composites
- 高分子学报 2023年54卷第10期页码：1409-1425
- 作者机构：
  
  1.清华大学，化学系有机光电子与分子工程教育部重点实验室，北京 100084
  2.清华大学，致理书院，北京 100084
- 作者简介：
  
  [ "袁金颖，女，1965年生. 清华大学化学系教授，博士生导师. 1987、1990和2000年分别本科、硕士和博士毕业于中国科学技术大学，1993~1997年在合肥工业大学任讲师. 2000~2002年在北京大学化学与分子工程学院进行博士后研究. 2002年加入清华大学化学系任副教授，2011年晋升为教授，2016年受聘为清华大学长聘教授. 2008年获得清华大学教学成果一等奖和研究生良师益友奖，2013年获得北京市科学技术奖一等奖，2016年入选清华大学纪念梅贻琦学术论文奖. 主要从事基于活性/可控聚合的响应型聚合物合成、聚合诱导组装和智能高分子材料的研究." ]
- 基金信息：
  
  国家自然科学基金(基金号 ┣22071131);52273106┫
- DOI：10.11777/j.issn1000-3304.2023.23113
  中图分类号：
- 纸质出版日期：2023-10-20，
  
  网络出版日期：2023-08-30，
  
  收稿日期：2023-04-25，
  
  录用日期：2023-07-11
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周硕,杨松铭,袁金颖.基于二氧化碳响应的聚合物及复合材料的构建与功能[J].高分子学报,2023,54(10):1409-1425.

Zhou Shuo,Yang Song-ming,Yuan Jin-ying.Construction and Function of CO₂-Switchable Polymers and Composites[J].ACTA POLYMERICA SINICA,2023,54(10):1409-1425.
周硕,杨松铭,袁金颖.基于二氧化碳响应的聚合物及复合材料的构建与功能[J].高分子学报,2023,54(10):1409-1425. DOI： 10.11777/j.issn1000-3304.2023.23113.

Zhou Shuo,Yang Song-ming,Yuan Jin-ying.Construction and Function of CO₂-Switchable Polymers and Composites[J].ACTA POLYMERICA SINICA,2023,54(10):1409-1425. DOI： 10.11777/j.issn1000-3304.2023.23113.

摘要

响应聚合物是一类可以对CO

气体和溶液做出响应的聚合物. 与CO

反应后聚合物的亲疏水和电荷等性质发生改变，通过氩气、氮气或空气的通入，或略微加热，可以实现CO

的去除，使聚合物及复合材料性质完全或部分恢复. 本文回顾了基于CO

响应的聚合物及复合材料的近年发展，从化学结构与响应基团出发介绍了不同类型的响应聚合物，包括脒基类、叔胺基类、胍基类和咪唑类，并对常见CO

响应聚合物的单体进行了总结. 介绍了CO

响应聚合物的不同功能，从组装体的角度出发讨论了囊泡、球形胶束和复合组装体及其他形貌的不同性质，同时逐级深入，总结了乳胶、气凝胶与水凝胶、功能表面与纳米纤维膜、有机无机杂化材料与复合材料和荧光传感与监测体系的构建及效果. 最后对于该领域还需继续探索优化的问题进行了讨论与总结，对未来的发展方向进行了展望.

Abstract

-responsive polymers are a class of polymers that can respond to CO

gases and solutions. The reaction with CO

changes the properties of the polymer such as hydrophobicity and charge. By introducing argon

nitrogen and air

or by slightly heating

can be removed and the properties of the polymer and composite material can be fully or partially restored. This review summarizes the recent development of CO

-responsive polymers and composites

introduces different types of responsive polymers from chemical structures and responsive groups

including amidines

tertiary amines

guanidines and imidazoles

and summarizes the monomers of common CO

-responsive polymers. The different functions of CO

-responsive polymers are introduced. Different properties of vesicles

spherical micelles and composite assemblies and other morphologies are discussed from the viewpoint of assemblies

while the construction and effects of emulsions

aerogels and hydrogels

functional surfaces and nanofiber membranes

organic-inorganic hybrid materials and composites

and fluorescence sensing and monitoring systems are summarized progressively. Finally

the problems that need to be explored and optimized in this field are discussed

and the future development direction is foreseen.

关键词

CO2响应环境响应聚合物组装体亲疏水性传感

Keywords

CO2-switchableEnvironmental responsePolymer assembliesHydrophobic and hydrophilic performanceSensor

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