超高分子量聚<italic style="font-style: italic">α</italic>-烯烃的高效合成及其减阻性能研究

姜子豪; 李鑫源; 回立为; 康宇泽; 王菲; 蔡浩; 潘莉; 李悦生

doi:10.11777/j.issn1000-3304.2023.23247

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超高分子量聚α-烯烃的高效合成及其减阻性能研究

研究论文 | 更新时间：2024-04-16

- 超高分子量聚α-烯烃的高效合成及其减阻性能研究
- Efficient Synthesis and Drag Reduction Properties of Ultra-high Molecular Weight Poly-α-olefin
- 高分子学报 2024年55卷第4期页码：419-427
- 作者机构：
  
  1.天津大学材料科学与工程学院天津 300350
  2.廊坊开发区中油科新化工有限责任公司廊坊 065000
- 作者简介：
  
  E-mail: lilypan@tju.edu.cn
- 基金信息：
  
  国家自然科学基金(基金号 52130307)
- DOI：10.11777/j.issn1000-3304.2023.23247
  中图分类号：
- 纸质出版日期：2024-04-20，
  
  网络出版日期：2023-12-29，
  
  收稿日期：2023-10-14，
  
  录用日期：2023-11-10
- 稿件说明：
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姜子豪, 李鑫源, 回立为, 康宇泽, 王菲, 蔡浩, 潘莉, 李悦生. 超高分子量聚α-烯烃的高效合成及其减阻性能研究. 高分子学报, 2024, 55(4), 419-427

Jiang, Z. H.; Li, X. Y.; Hui, L. W.; Kang, Y. Z.; Wang, F.; Cai, H.; Pan, L.; Li, Y. S. Efficient synthesis and drag reduction properties of ultra-high molecular weight poly-α-olefin. Acta Polymerica Sinica, 2024, 55(4), 419-427
姜子豪, 李鑫源, 回立为, 康宇泽, 王菲, 蔡浩, 潘莉, 李悦生. 超高分子量聚α-烯烃的高效合成及其减阻性能研究. 高分子学报, 2024, 55(4), 419-427 DOI： 10.11777/j.issn1000-3304.2023.23247.

Jiang, Z. H.; Li, X. Y.; Hui, L. W.; Kang, Y. Z.; Wang, F.; Cai, H.; Pan, L.; Li, Y. S. Efficient synthesis and drag reduction properties of ultra-high molecular weight poly-α-olefin. Acta Polymerica Sinica, 2024, 55(4), 419-427 DOI： 10.11777/j.issn1000-3304.2023.23247.

摘要

利用第四代Ziegler-Natta催化体系——负载在MgCl

上的TiCl

为主催化剂，三乙基铝(Et

Al)为助催化剂，甲基环己基二甲氧基硅烷(CHMDMS)为外给电子体，在磁力搅拌和机械搅拌2种条件下催化1-辛烯和1-癸烯共聚合，制得了一系列高减阻性能聚

-烯烃(Poly-alpha-olefin，PAO)类减阻剂. 利用高温凝胶渗透色谱仪测得聚合物的重均分子量(

)在3×10

以上，分子量分布指数(PDI)基本在3.04以内. 进一步通过低温机械搅拌可实现更窄的聚合物分子量分布(1.27~1.90). 通过核磁共振(

C-NMR)对聚合物进行分子结构表征，结果表明得到了目标产物、无单体残留，且聚合物中单体比例与投料比基本一致. 示差扫描量热法(DSC)和X射线衍射(XRD)测试结果表明，成功合成了无结晶行为的聚合物. 热重分析(TGA)结果表明，该聚合物在氮气气氛下的热分解温度在300 ℃以上，远高于使用温度. 环路管道循环实验表明，随着聚合物分子量增加，减阻效率整体呈增加趋势，共聚物的减阻效率大于均聚物；随着单体与催化剂的摩尔比增加，减阻效率先升高后降低. 相较已有报道，减阻性能有较大提升，最高减阻率可达50%.

Abstract

Using 1-octene and 1-decene as monomers

and a catalytic system of TiCl

(a fourth-generation Ziegler-Natta catalyst) loaded on MgCl

as the main catalyst

triethylaluminium (Et

Al) as a co-catalyst

and methylcyclohexyldimethoxysilane (CHMDMS) as the external electron donor

under both magnetic stirring and mechanical stirring conditions

respectively

a series of poly-

-olefin (PAO)-based drag reducer were successfully prepared. As proven by high-temperature gel permeation chromatography

the newly obtained polymers not only had very high molecular weight

(weight average molecular weight of most of the polymers was higher than 3×10

)

but also had very narrow molecular weight distribution (polymer dispersity index was lower than 3.0 for most of the polymers)

suggesting a uniform distribution of all polymer chains. The obtained polymers were characterized by

C-nuclear magnetic resonance (

C-NMR)

differential scanning calorimetry (DSC)

thermal gravimetric analyzer (TGA) and X-ray diffraction (XRD)

respectively. It turned out that target polymers with expected composition were obtained. Most of the polymers were amorphous

making them well-soluble in oils. All polymers showed high decomposition temperature beyond 300 ℃

much higher than working temperature of drag reducers. The loop pipeline cycling experiment indicated that the drag reduction efficiency of the newly obtained polymers was greatly improved compared with those of commercial products and previous reports.

关键词

减阻剂聚α-烯烃减阻率Ziegler-Natta催化剂

Keywords

Drag reducerPoly-α-olefinDrag reduction efficiencyZiegler-Natta catalysts

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超高分子量聚α-烯烃的高效合成及其减阻性能研究

Efficient Synthesis and Drag Reduction Properties of Ultra-high Molecular Weight Poly-α-olefin

DOI：10.11777/j.issn1000-3304.2023.23247

摘要

Abstract

关键词

Keywords

references