可逆失活自由基聚合制备含氟聚合物的研究进展

韩善涛; 许梦丽; 陈茂

doi:10.11777/j.issn1000-3304.2024.24017

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可逆失活自由基聚合制备含氟聚合物的研究进展

综述 | 更新时间：2024-09-25

- 可逆失活自由基聚合制备含氟聚合物的研究进展
- Research Progress on Preparing Fluoropolymers via Reversible Deactivation Radical Polymerization
- 高分子学报 2024年55卷第7期页码：841-855
- 作者机构：
  
  复旦大学高分子科学系聚合物分子工程国家重点实验室上海 200433
- 作者简介：
  
  [ "陈茂，男，教授，博士生导师. 2002~2011年就读于武汉大学，先后获得学士、博士学位. 2012~2016年在美国麻省理工学院(MIT)从事博士后科研工作，2016年担任MIT研究科学家. 同年加入复旦大学高分子科学系、聚合物分子工程国家重点实验室，青年研究员. 2021年任复旦大学教授. 课题组研究方向主要包括：(1) 探索新型聚合方法，可控合成含氟聚合物；(2) 发展流动化学、机器学习方法用于助力高分子合成；(3) 开发用于新能源领域的含氟高分子材料. 2019年获得Thieme Chemistry Journals Award，2021年获得ACS PMSE Young Investigator Award和Pioneering Investigation by Polymer Chemistry. 目前以通讯作者/第一作者发表论文70余篇，被引用3000余次." ]
- 基金信息：
  
  国家自然科学基金(基金号 22171051)
- DOI：10.11777/j.issn1000-3304.2024.24017
  中图分类号：
- 纸质出版日期：2024-07-20，
  
  网络出版日期：2024-04-23，
  
  收稿日期：2024-01-17，
  
  录用日期：2024-02-06
- 稿件说明：
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韩善涛, 许梦丽, 陈茂. 可逆失活自由基聚合制备含氟聚合物的研究进展. 高分子学报, 2024, 55(7), 841-855

Han, S. T.; Xu, M. L.; Chen, M. Research progress on preparing fluoropolymers via reversible deactivation radical polymerization. Acta Polymerica Sinica, 2024, 55(7), 841-855
韩善涛, 许梦丽, 陈茂. 可逆失活自由基聚合制备含氟聚合物的研究进展. 高分子学报, 2024, 55(7), 841-855 DOI： 10.11777/j.issn1000-3304.2024.24017.

Han, S. T.; Xu, M. L.; Chen, M. Research progress on preparing fluoropolymers via reversible deactivation radical polymerization. Acta Polymerica Sinica, 2024, 55(7), 841-855 DOI： 10.11777/j.issn1000-3304.2024.24017.

摘要

含氟聚合物具有许多优异的理化性能，在化工、新能源、生物医药等领域取得重要应用. 可逆失活自由基聚合反应(RDRP)是实现聚合物精准合成的重要手段. 然而，含氟烯烃单体的RDRP报道相对较少. 本综述对侧链含氟聚合物和主链含氟聚合物的可控合成进展进行介绍，简述了含氟丙烯酸酯、含氟苯乙烯、三氟氯乙烯、四氟乙烯、偏氟乙烯、六氟丙烯、全氟烯基醚等单体的RDRP案例，总结了该领域面临的挑战. 鉴于众多前沿领域对定制化合成含氟聚合物提出了迫切需求，发展含氟聚合物的可控合成方法将有助于拓宽含氟聚合物范围，推动开发高性能含氟聚合物材料.

Abstract

Fluoropolymers possess many outstanding physical and chemical properties

allowing applications in aerospace

defense

chemicals

new energy

biomedicine

etc

. Reversible deactivation radical polymerization (RDRP) is among the important methods for realizing precise synthesis of polymers. However

compared with the (methyl)acrylate and styrene derivatives

RDRPs of fluorinated monomers are very limited. Recently

a growing number of research reports demonstrated that the precise regulation of polymer structures contributes to improving properties of polymers

promoting the development of high-end materials. Herein

this review focuses on RDRPs of fluorinated monomers

introduces the research advancements of the controlled synthesis of side-chain and main-chain fluorinated polymers

and summarizes the RDRP reports of fluorinated acrylates

fluorinated styrene

chlorotrifluoroethylene

tetrafluoroethylene

vinylidene fluoride

hexafluoropropylene

and perfluoroalkyl vinyl ethers. Given the urgent need for customized synthesis of fluorinated polymers in many frontier fields

the development of controlled synthesis methods for fluorinated polymers will not only contribute to regulating the structural scope of fluorinated polymers but also facilitate the production of high-performance fluorinated polymer materials. This review serves as a valuable resource for researchers working in the field of fluorinated polymers

providing an overview of the current state of the art and briefly illustrating the prospects and challenges for the RDRP of fluorinated monomers.

关键词

含氟聚合物含氟烯烃可控失活自由基聚合活性聚合

Keywords

FluoropolymersFluoroalkenesReversible deactivation radical polymerization (RDRP)Living polymerization

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