Wei-sheng Guan, Han-xiong Huang, Bin Wang. DESIGN AND MANIPULATION OF MICROSTRUCTURES ON MICROINJECTION-COMPRESSION MOLDED SUPERHYDROPHOBIC SURFACES[J]. Acta Polymerica Sinica, 2013,(10):1285-1290.
Microstructures in the dual- and three-level hierarchical templates are replicated on the surfaces of large-sized polypropylene (PP) samples using microinjection-compression molding (-ICM) in a single step.Results indicate that the single- and dual-level structured surfaces can be molded via the former template under lower and higher compression forces
respectively.The single-level micro blade structure yields an increase in static contact angle (CA) from the intrinsic value of the PP (85.0) to 134.2 on the molded surface.The dual-level structure involving micro blades and micro pyramids results in the lotus-leaf effect (CA150
rolling angle RA5) on the surface.The 250 m diameter micro columns
the top surfaces of which show the aforementioned dual-level microstructure
are uniformly distributed on the three-level hierarchical surface molded via the later template.The CA and RA values on this surface are 164.5 and above 90
respectively.Thus a functional surface displaying the petal effect is obtained.The high level of RA is resulted from the localized noncomposite wetting state near the upper edge of micro columns.This work gives an insight into the design
manipulation and mass production of superhydrophobic surface.