STUDIES ON THE POLYMERIZATION OF FUNCTIONAL MONOMERS CONTAINING AMINO GROUPS——Ⅲ. Polymerization of 4-(N, N-Dimethylaminobenzyl) Methacrylate Initiated by Lauroyl Peroxide
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Research Bulletin|更新时间:2021-03-19
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STUDIES ON THE POLYMERIZATION OF FUNCTIONAL MONOMERS CONTAINING AMINO GROUPS——Ⅲ. Polymerization of 4-(N, N-Dimethylaminobenzyl) Methacrylate Initiated by Lauroyl Peroxide
LI Fu-mian, Ye Wei-peng, FENG Xin-de. STUDIES ON THE POLYMERIZATION OF FUNCTIONAL MONOMERS CONTAINING AMINO GROUPS——Ⅲ. Polymerization of 4-(N, N-Dimethylaminobenzyl) Methacrylate Initiated by Lauroyl Peroxide. [J]. Acta Polymerica Sinica (5):397-400(1982)
DOI:
LI Fu-mian, Ye Wei-peng, FENG Xin-de. STUDIES ON THE POLYMERIZATION OF FUNCTIONAL MONOMERS CONTAINING AMINO GROUPS——Ⅲ. Polymerization of 4-(N, N-Dimethylaminobenzyl) Methacrylate Initiated by Lauroyl Peroxide. [J]. Acta Polymerica Sinica (5):397-400(1982)DOI:
STUDIES ON THE POLYMERIZATION OF FUNCTIONAL MONOMERS CONTAINING AMINO GROUPS——Ⅲ. Polymerization of 4-(N, N-Dimethylaminobenzyl) Methacrylate Initiated by Lauroyl Peroxide
N-dimethylaminobenzyl)methacrylate (DMABMA) initiated by LPO has been studied. The rate equation of the polymerization which was determined at 20
30
40 and 50℃ was found to be Rp=Kp [DMABMA]1.5 [LPO]0.5
and the overall activation energy of this polymerization system was determined as 12.2 Kcal/mol. Owing to the above results and the monomer containing tertiary aromatic amino group
the redox nature of LPO with the monomer itself has been suggested.