SHI Guan-yi, Jing He-sheng, Yue Jun-shi. INFLUENCE OF THE MELT TEMPERATURE ON THE CRYSTALLINE MORPHOLOGY OF POLYTETRAFLUOROETHYLENE. [J]. Acta Polymerica Sinica (4):247-251(1983)
DOI:
SHI Guan-yi, Jing He-sheng, Yue Jun-shi. INFLUENCE OF THE MELT TEMPERATURE ON THE CRYSTALLINE MORPHOLOGY OF POLYTETRAFLUOROETHYLENE. [J]. Acta Polymerica Sinica (4):247-251(1983)DOI:
INFLUENCE OF THE MELT TEMPERATURE ON THE CRYSTALLINE MORPHOLOGY OF POLYTETRAFLUOROETHYLENE
The influence of the melt temperature on the crystalline morphology of polytetra-fluoroethylene was studied by Small An.gle Light Scattering and Electron Microscope techniques. When PTFE was melt.crystallized from temperature below 400℃ under slow cooling rate
the rodlike morphology was obtained;when it Was crystallized from temperature above 455℃.the spherulitie marphology was formed.From the inteme-diate temperature range,the formed sheaflike morphology can be viewed under electron microscope:The DSC study shows that the change of morphology with melt tempera-ture is due to chain seission of macromolecules.The decrease of molecular weight of PTFE with heat-treat temperature was estimated by the measurement of heat of crystal-lization using Suwa’s relation and the deterioration of meehanieal property with the increase of heat-treat temperature was also notieed.