EFFECT OF MOLECULAR WEIGHT DISTRIBUTION ON THETEXTURE FORMATION OF AS-SPUN ISOTATICPOLYPROPYLENE FIBER
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EFFECT OF MOLECULAR WEIGHT DISTRIBUTION ON THETEXTURE FORMATION OF AS-SPUN ISOTATICPOLYPROPYLENE FIBER
Acta Polymerica SinicaIssue 1, Pages: 62-68(1984)
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Published:20 February 1984,
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FAN Qing-rong, XU Duan-fu, ZHAO De-lu, QIAN Ren-yuan. EFFECT OF MOLECULAR WEIGHT DISTRIBUTION ON THETEXTURE FORMATION OF AS-SPUN ISOTATICPOLYPROPYLENE FIBER. [J]. Acta Polymerica Sinica (1):62-68(1984)
DOI:
FAN Qing-rong, XU Duan-fu, ZHAO De-lu, QIAN Ren-yuan. EFFECT OF MOLECULAR WEIGHT DISTRIBUTION ON THETEXTURE FORMATION OF AS-SPUN ISOTATICPOLYPROPYLENE FIBER. [J]. Acta Polymerica Sinica (1):62-68(1984)DOI:
EFFECT OF MOLECULAR WEIGHT DISTRIBUTION ON THETEXTURE FORMATION OF AS-SPUN ISOTATICPOLYPROPYLENE FIBER
The effects of toolecular weight distribution on the texture formation of as.spun fibe-rs and mechanical properties of polypropylene fibers have been studied.It is shown that the texture formation of as-spun fibers is very sensitive to the presence of high molecalar wei-ght tail in the MWD of polypropylene resin.Under ordinary spinning conditions the as-spun fiber obtained from controHed degraded polypropylene resin showed smectic structu-re with low degree of oritation.However,in the presence of some high molecular weight tail incorproated to the degraded polypropylene resin gave as-spun fibers in a-crystalline modi-fication,although the viscosity average molecular weight and spinning conditions were kept the same.In addition,the birefringence of the as-spun fibers increased sharphy with increa-sing amocnt of the high molecular weight tail in the MWP.The different texture of as-spun fibers resulted in big difference in stretching behavior of the as-spun fiber and mechanical properties of drawn fibers.