CHARGE TRANSFER PHENOMENON BETWEEN FULLERENE AND POLYMER CONTAINING ELECTRON ACCEPTING CHROMOPHORE

QIU Jian; YAO Guangqing; ZHOU Xihuang; LI Fumian

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CHARGE TRANSFER PHENOMENON BETWEEN FULLERENE AND POLYMER CONTAINING ELECTRON ACCEPTING CHROMOPHORE

Research Bulletin | 更新时间：2021-03-19

- CHARGE TRANSFER PHENOMENON BETWEEN FULLERENE AND POLYMER CONTAINING ELECTRON ACCEPTING CHROMOPHORE
- Acta Polymerica Sinica Issue 3, Pages: 367-370(1997)
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- Published：20 June 1997，
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QIU Jian, YAO Guangqing, ZHOU Xihuang, LI Fumian. CHARGE TRANSFER PHENOMENON BETWEEN FULLERENE AND POLYMER CONTAINING ELECTRON ACCEPTING CHROMOPHORE. [J]. Acta Polymerica Sinica (3):367-370(1997)
DOI：

QIU Jian, YAO Guangqing, ZHOU Xihuang, LI Fumian. CHARGE TRANSFER PHENOMENON BETWEEN FULLERENE AND POLYMER CONTAINING ELECTRON ACCEPTING CHROMOPHORE. [J]. Acta Polymerica Sinica (3):367-370(1997) DOI：

摘要

Ｃ６０与含受电子生色基团聚合物的电荷转移现象邱健姚光庆周锡煌李福绵（北京大学化学与分子工程学院北京１００８７１）关键词Ｃ６０

聚［Ｎ（４氰基苯基）丙烯酰胺］

电荷转移现象

荧光光谱随着对球壳烯性质的深入认识

球壳烯与电子给、受体的电荷转移现象日益引起人们的兴趣．在小分子领域

人们发现Ｃ６０作为受电子体能与给电子的小分子芳香胺类

如二甲苯胺（ＤＭＡ）、二乙苯胺（ＤＥＡ）［１

２］等形成较?...

Abstract

A polymer containing electron accepting chromophore

i.e.poly (N4-cyanophenyl acrylamide) was synthesized.When C60 was added to the solution of P(CPAA)

the fluorescence intensity of the latter was decreased regularly.An upward curvature was found in the Stern Volmer plot

which indicated not only the formation of exciplex but also the formation of charge transfer complex in the ground state (CTC).Both mechanisms of charge transfer were verified by the measurement of fluorescence life time and UV absorption spectra

respectively.The eletron-accepting ability of C60 was tested to be almost as strong as that of DMT

which was compatible with their ionization potentials.

关键词

Ｃ６０聚［Ｎ-（４-氰基苯基）丙烯酰胺］电荷转移现象荧光光谱

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