Bao-shun Hou, Yu-dong Zheng, Lina Yue, Cai Wang, Kun Qiao, Li-ying Cui, Bo-wen Yang. Effects of Degree of Acetalization and Pore Structure on Water Absorbency and Mechanical Properties of Polyvinyl Formal (PVF) Porous Material. [J]. Acta Polymerica Sinica (6):657-666(2015)
DOI:
Bao-shun Hou, Yu-dong Zheng, Lina Yue, Cai Wang, Kun Qiao, Li-ying Cui, Bo-wen Yang. Effects of Degree of Acetalization and Pore Structure on Water Absorbency and Mechanical Properties of Polyvinyl Formal (PVF) Porous Material. [J]. Acta Polymerica Sinica (6):657-666(2015) DOI: 10.11777/j.issn1000-3304.2015.14381.
Effects of Degree of Acetalization and Pore Structure on Water Absorbency and Mechanical Properties of Polyvinyl Formal (PVF) Porous Material
Polyvinyl formal (PVF) porous material was fabricated by mechanical stirring after adding surfactant in this research
and the acetalation performance and pore structure of PVF influenced by changing degree of HCHO and SDS (sodium dodecyl sulfate) were studied.Furthermore
the mechanism of mechanical properties and absorbency influenced by acetalation performance and pore structure was discussed.The study shows that
the change of acetalation of PVF influences the absorbency
the crosslinking density
the molecular chain gaps
the proportion of hard segment and the VDW (Van der Waals'force) of PVF.Besides
the sudy shows that the change of pore structure alters the amount of capillaries in the PVF
the specific surface area and the water holding capacity
also the relative density and stress concentration.All of these changes influened by acetaltion and pore structure result in the changing of absorbency and mechanical properties of PVF.High performance PVF porous material with good absorbency and mechanical properties can be prepared through controlling the degree of acetalation and pore structure.As a result
the PVF porous material in the hygrometric state can achieve excellent meananical properties and acetalation performance
with the best water absorption rate of 1627%.Meanwhile
the PVF porous material possesses well rebound resilience.
关键词
PVF多孔材料缩醛度孔隙结构使用性能
Keywords
PVF porous materialDegree of acetalationPore structurePerformance