The self-assemble morphologies of amphiphilic diblock copolymers in dilute selective solutions confined in circular tubes and horizontal slits were investigated by self-consistent field theory (SCFT)
which were affected by the confinements
the hydrophilc-lipophilic properties of the walls and the spacing between substrates.In neutral circular tubes
with the increase of the repulsion interaction between solvent and hydrophobic blocks and the attraction interaction between solvent and hydrophilic blocks
the copolymer adsorbed on the walls assembling as mushroom shapes.The more intense the two interactions
the easier the adsorption phenomena of the amphiphilic diblock copolymers.In hydrophilic tubes
the adsorption phenomena eased
and the spherical micelles arranged regularly near the walls with the increase of the interaction between walls and hydrophilic segments of the copolymer.When the differences between the hydrophobic chain and hydrophilic chain interactions with the solvent were very large
the adsorption phenomena of the copolymers could not be eliminated
even though the adsorption interaction between the wall and the hydrophilic blocks was enhanced.In neutral horizontal substrates
as the substrate spacing was increased
amphiphilic diblock copolymers sequentially appeared as spherical micelles-mushroom-like micelles-single spherical micelles-polymer brush-double spherical micelles-symmetrical polymer brushes near the substrates.
关键词
两亲性嵌段共聚物稀溶液吸附行为自洽场理论自组装圆形孔道水平基板
Keywords
Amphiphilic diblock copolymersDilute solutionAdsorption behaviorSelf-consistent field theorySelf-assemblyCircular poresHorizontal substrates
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Related Author
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Related Institution
State Key Laboratory of Chemical Resource Engineering, Beijing Advanced Innovation Center for Soft Matter Science and Engineering, Beijing University of Chemical Technology
Department of Polymer Science and Engineering, University of Massachusetts, Amherst
Shanghai Key Laboratory of Advanced Polymeric Materials, School of Materials Science and Engineering, East China University of Science and Technology
College of Textile Science and Engineering, Jiangnan University
School of Materials Science and Engineering, East China University of Science and Technology