The composite fibers with electromagnetic function were prepared by using the aqueous mixture of poly(vinyl alcohol)(PVA)
poly(3
4-ethylenedioxythiophene)-poly(sodium-p-styrenesulfonate)(PEDOT-PSS) and Co doped Fe3O4 magnetic particles (Co-Fe3O4) as the spinning solution via a conventional wet spinning process.Effects of draw ratios on the structure and properties of PEDOT-PSS/Co-Fe3O4/PVA composite fibers were studied.The morphology
structure
crystallinity
thermal stability
mechanical properties
conductivity and magnetic properties of the composite fibers were studied by scanning electron microscope (SEM)
Fourier transform infrared spectrometer (FTIR)
powder X-ray diffraction (XRD)
thermogravimetric analyzer (TG)
electronic single fiber tensile strength tester (ESFTST)
four-probe conductivity meter (FPCM) and vibrating sample magnetometer (VSM).The SEM images show that the diameters of the composite fibers are in the range of 20-30 m with a rough surface and reniform cross section.And with the increase of the draw ratio
the fiber diameters decrease.FTIR spectra indicate that with the increase of the draw ratio
most absorption peaks increased indicating the increase of the orientation of polymer molecular chains along with the draw direction.The results of XRD
TG
ESFTST and FPCM present that the composite fiber' s crystal properties
thermal stability and mechanical properties are all improved with the increase of the draw ratio
and the conductivity increased multiply.However
the saturation magnetization of the composite fibers is almost independent of draw ratios
which is about 1.7 A m2/kg.When the draw ratio of the composite fiber is 4
the conductivity can reach to 2.3 S/cm
ten times the conductivity when the draw ratio is 2.
关键词
PEDOT-PSSCo-Fe3O4湿法纺丝牵伸倍率电磁功能
Keywords
PEDOT-PSSCo-Fe3O4Wet spinningDraw ratioElectromagnetic function
PEDOT-PSS/PVA Composite Conductive Textile with Electromagnetic Wave Absorption Properties Prepared by in situ Polymerization
Related Author
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Related Institution
Beijing Key Laboratory of Clothing Materials Research and Development and Assessment, School of Materials Science & Engineering, Beijing Institute of Fashion Technology
Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences