Preparation of Carboxyl-terminated Modified Polyether Polysiloxane and Its Supramolecular Construction, Film Morphology and Application Performance

Qiu-feng An; Jia-yan Pan; Jie Zhao

doi:10.11777/j.issn1000-3304.2016.15324

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Preparation of Carboxyl-terminated Modified Polyether Polysiloxane and Its Supramolecular Construction, Film Morphology and Application Performance

Research Article | 更新时间：2021-03-19

- Preparation of Carboxyl-terminated Modified Polyether Polysiloxane and Its Supramolecular Construction, Film Morphology and Application Performance
- Acta Polymerica Sinica Issue 6, Pages: 822-830(2016)
- 作者机构：
  
  陕西科技大学教育部轻化工助剂化学与技术重点实验室西安 710021
- 作者简介：
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2016.15324
  CLC：
- Published：2016-6，
  
  Received：26 November 2015，
  
  Revised：29 January 2016，
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Qiu-feng An, Jia-yan Pan, Jie Zhao. Preparation of Carboxyl-terminated Modified Polyether Polysiloxane and Its Supramolecular Construction, Film Morphology and Application Performance. [J]. Acta Polymerica Sinica (6):822-830(2016)
DOI：

Qiu-feng An, Jia-yan Pan, Jie Zhao. Preparation of Carboxyl-terminated Modified Polyether Polysiloxane and Its Supramolecular Construction, Film Morphology and Application Performance. [J]. Acta Polymerica Sinica (6):822-830(2016) DOI： 10.11777/j.issn1000-3304.2016.15324.

摘要

采用聚醚胺封端聚硅氧烷(BPEAS)与马来酸酐(MAn)开环反应

合成了端羧基聚醚聚硅氧烷(CPSA)

分别以CPSA为阴离子构建基元、杀菌性长碳链季铵基聚醚聚硅氧烷(QPEPS)为阳离子构建基元

以异丙醇为介质

通过静电作用进行超分子自组装

构建了一种新型超分子CPSA/QPEPS.通过红外光谱(FTIR)、核磁共振氢谱(

H-NMR)对CPSA的结构进行表征

用白度仪、柔软度仪、织物折皱弹性仪、接触角仪、酶标仪等仪器对超分子CPSA/QPEPS的应用性能进行了研究

并用场发射扫描电镜(FESEM)、原子力显微镜(AFM)等对CPSA/QPEPS的膜形貌进行了观察.结果表明当

(QPEPS)/

(CPSA)=1:1时

经CPSA/QPEPS整理过的棉织物

其弯曲刚度显著降低

静态吸水时间仅为4.39 s

且织物对大肠杆菌和金黄色葡萄球菌的抑菌率分别达到了71%.其次

超分子CPSA/QPEPS具有良好的成膜性

AFM观察其膜表面呈现出连续的山脉状形貌

在5μm×5μm扫描范围内CPSA/QPEPS膜的表面均方根粗糙度(

)达到了2.57 nm.

Abstract

A carboxyl-terminated polyether polysiloxane (CPSA) was synthesized by the ring-opening reaction between polyether amino terminated polydimethylsiloxane (BPEAS) and maleic anhydride (MAn). In the isopropanol media

the novel supramolecular CPSA/QPEPS was prepared by electrostatic interactions of supramolecular self-assembly

which were formed between CPSA with negative charges and long carbon chain quaternary ammonium modified polyether polysiloxane QPEPS with positive charges. The chemical structures of the carboxyl-terminated polyether polysiloxane (CPSA) were characterized by FTIR

H-NMR. Then

the application performances of CPSA/QPEPS were investigated by HY-BDY

contact angle

softness tester

microplate reader

X-ray photoelectron spectroscopy (XPS). Finally

the morphology of CPSA/QPEPS was observed by field emission scanning electron microscopy (FESEM) and atomic force microscopy (AFM)

respectively. The results indicated that

when the mass ratio of QPEPS to CPSA was 1:1

the bending rigidity (BR) and the softness of fabric treated by CPSA/QPEPS were decreased and increased

respectively. The wetting time of the treated fabric was only 4.39 s

moreover

the inhibition rate against both

E. coli

and

S. Aureus

of the treated fabric reached 71%. Also

the CPSA/QPEPS exhibited a favorable film-forming properties. The surface of CPSA/QPEPS films shows a continuous mountain-like morphology and the root mean square roughness (

) of the CPSA/QPEPS film achieved 2.57 nm

via

5 μm × 5 μm scanning field.

关键词

聚醚聚硅氧烷超分子膜形貌织物杀菌

Keywords

Polyether-modified polysiloxaneSupermoleculeFilm morphologyTextileAntibacterial activity

references

Jiacong Shen . Supramolecular Layered Structures-Assembly and Functionalization , : Beijing Science Press , 2004 . 9 - 24.

沈家骢 . 超分子层状结构-组装与功能 , : 北京科学出版社 , 2004 . 9 - 24.

Q F An , G Yang , Q J Wang , L X Huang . J Appl Polym Sci , 2008 . 110 2595 - 2600.

K Yoshiro , I Nobuo , M Taki , F Kazuko , K Keiji , F Taketoshi . J Mater Chem , 2003 . 13 2058 - 2060.

N E Botterhuis , Beek D J M van , Gemert G M L van , A W Bosman , R P Sijbesma . J Polym Sci,Part A:Polym Chem , 2008 . 46 3877 - 3883.

C Racles , M Cazacu . J Appl Polym Sci , 2008 . 109 4000 - 4009.

L Iannarelli , R Nisticò , P Avetta , M Lazzari , G Magnacca , P Calza , D Fabbri , D Scalarone . Eur Polym J , 2015 . 62 108 - 115.

J Y Ouyang , Y Pan , S Q Zhou , S H Goh . Polymer , 2006 . 47 6140 - 6148.

J Alauzun , A Mehdi , C Reyé , R J P Corriu . J Am Chem Soc , 2005 . 127 11204 - 11205.

B Y Chow , D W Mosley , J M Jacobson . Langmuir , 2005 . 21 ( 11 ): 4782 - 4785.

C Costa , V Franciscob , S G Silva , L C D M.Vale , L García-Río . Colloid Surface A , 2015 . 480 71 - 78.

J K Tae , S K Min . Textile Res , 2001 . 71 ( 4 ): 295 - 300.

Qiufeng An , Guangwen Cheng , Linsheng Li , Mingtao Li , Yunxia Jin . Acta Polymerica Sinica , 2007 . ( 6 ): 524 - 530.

安秋凤 , 程广文 , 李临生 , 李明涛 , 金云霞 . 高分子学报 , 2007 . ( 6 ): 524 - 530.

Qiufeng An , Kefeng Wang , Qianjin Wang , Liangxian Huang , Xianqi Li . Acta Polymerica Sinica , 2010 . ( 10 ): 1225 - 1230.

安秋凤 , 王科峰 , 王前进 , 黄良仙 , 李献起 . 高分子学报 , 2010 . ( 10 ): 1225 - 1230.

M M Joyner . Text Chem Color , 1986 . 18 ( 3 ): 34 - 37.

Y Chen , M Q Niu , S Yuan . Appl Surf Sci , 2013 . 264 ( 1 ): 171 - 175.

Q F An , K F Wang , Y Jia . Appl Surf Sci , 2011 . 257 4569 - 4574.

Q F An , G W Cheng , L S Li . J Appl Polym Sci , 2006 . 101 4480 - 4486.

L F Hao , Q F An , W Xu . Fiber Polym , 2012 . 13 ( 9 ): 1145 - 1153.

Q F An , Q J Wang , L S Li . AATCC Review , 2010 . 10 ( 2 ): 45 - 50.

Liangxian Huang , Qiufeng An , Kefeng Wang . Polymer Materials Science and Engineering , 2011 . 27 ( 12 ): 48 - 51.

黄良仙 , 安秋凤 , 王科峰 . 高分子材料科学与工程 , 2011 . 27 ( 12 ): 48 - 51.

S Gunnars , L Wagberg , M A C Stuart . Cellulose , 2002 . 9 239 - 249.

C B Michael , D B Matthew , D Daniel . Appl Surf Sci , 2004 . 227 1 - 6.

X Y Song , J Zhai , Y L Wang . J Phys Chem , 2005 . 109 ( 9 ): 4048 - 4052.

R Helmy , A Y Fadeev . Langmuir , 2002 . 18 ( 23 ): 8924 - 8928.

L Fras , L S Johansson , P Stenius . Colloid Surface A , 2005 . 260 ( 1-3 ): 101 - 108.

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