Helical Bulky Polystyrene DerivativesChiral Teleinduction and Self-assembly

Rong Wang; Jie Zhang; Xin-hua Wan

doi:10.11777/j.issn1000-3304.2016.16037

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Helical Bulky Polystyrene DerivativesChiral Teleinduction and Self-assembly

Feature Articles | 更新时间：2021-03-19

- Helical Bulky Polystyrene DerivativesChiral Teleinduction and Self-assembly
- Acta Polymerica Sinica Issue 4, Pages: 409-421(2016)
- 作者机构：
  
  北京分子科学国家实验室高分子化学与物理教育部重点实验室北京大学化学与分子工程学院高分子科学与工程系,北京,100871
- 作者简介：
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2016.16037
  CLC：
- Published：20 April 2016，
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Rong Wang, Jie Zhang, Xin-hua Wan. Helical Bulky Polystyrene DerivativesChiral Teleinduction and Self-assembly. [J]. Acta Polymerica Sinica (4):409-421(2016)
DOI：

Rong Wang, Jie Zhang, Xin-hua Wan. Helical Bulky Polystyrene DerivativesChiral Teleinduction and Self-assembly. [J]. Acta Polymerica Sinica (4):409-421(2016) DOI： 10.11777/j.issn1000-3304.2016.16037.

摘要

设计、合成新型光学活性螺旋链聚合物是当今高分子科学领域一个十分活跃的前沿研究课题.光学活性乙烯基三联苯螺旋链聚合物具有良好的物理和化学稳定性

在手性识别、不对称催化等领域具有重要的潜在应用价值.本文将系统介绍不同结构乙烯基三联苯类单体的螺旋选择性自由基聚合、共聚合过程中的手性长程传递规律以及相应两亲性刚柔嵌段共聚物在水气界面处和溶液中的自组装行为

归纳总结迄今已经取得的初步结果

并对今后的发展提出一点拙见.

Abstract

Design and synthesis of novel optically active helical polymers are active subjects and frontiers in the field of polymer science.Optically active helical vinylterphenyl polymers are physically and chemically stable and are of potential applications in chiral recognition and asymmetric catalysis.In this review

the helix-sense-selective radical polymerization of vinylterphenyl monomers

chiral teleinduction in radical copolymerization

and self-assembly of amphiphilic block copolymers consisting of helical chains as rigid segments in solution and at the air/water interface are comprehensively introduced.The results obtained up to now are summarized and a short outlook on the development of optically active vinylaromatic polymers is provided.

关键词

手性长程传递螺旋链光学活性螺旋选择性自由基聚合嵌段聚合物自组装

Keywords

Chiral teleinductionHelixOptical activityHelix-sense-selective radical polymerizationBlock copolymerSelf-assembly

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Related Institution

State Key Laboratory of Chemical Resource Engineering, Beijing Advanced Innovation Center for Soft Matter Science and Engineering, Beijing University of Chemical Technology

Department of Polymer Science and Engineering, University of Massachusetts, Amherst

Shanghai Key Laboratory of Advanced Polymeric Materials, School of Materials Science and Engineering, East China University of Science and Technology

College of Textile Science and Engineering, Jiangnan University

School of Materials Science and Engineering, East China University of Science and Technology

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