Magnetic Responsive Oil-absorbing Polymeric Resins Based on 4-<italic style="font-style: italic">Tert</italic>-butyl-styrene and Methyl Methacrylate

Yuan-peng Wu; Hao Yang; Shang-guo Zhu; Yuan-hua Lin; Zhao-hui Zheng; Xiao-bin Ding

doi:10.11777/j.issn1000-3304.2016.16046

您当前的位置：

首页 >

文章列表页 >

Magnetic Responsive Oil-absorbing Polymeric Resins Based on 4-Tert-butyl-styrene and Methyl Methacrylate

Research Article | 更新时间：2021-03-19

- Magnetic Responsive Oil-absorbing Polymeric Resins Based on 4-Tert-butyl-styrene and Methyl Methacrylate
- Acta Polymerica Sinica Issue 11, Pages: 1599-1605(2016)
- 作者机构：
  
  1.西南石油大学材料科学与工程学院新能源材料及技术研究中心成都 610500
  2.中国科学院成都有机化学研究所成都 610041
- 作者简介：
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2016.16046
  CLC：
- Published：2016-11，
  
  Received：29 January 2016，
  
  Revised：31 March 2016，
扫描看全文
Yuan-peng Wu, Hao Yang, Shang-guo Zhu, Yuan-hua Lin, Zhao-hui Zheng, Xiao-bin Ding. Magnetic Responsive Oil-absorbing Polymeric Resins Based on 4-Tert-butyl-styrene and Methyl Methacrylate. [J]. Acta Polymerica Sinica (11):1599-1605(2016)
DOI：

Yuan-peng Wu, Hao Yang, Shang-guo Zhu, Yuan-hua Lin, Zhao-hui Zheng, Xiao-bin Ding. Magnetic Responsive Oil-absorbing Polymeric Resins Based on 4-Tert-butyl-styrene and Methyl Methacrylate. [J]. Acta Polymerica Sinica (11):1599-1605(2016) DOI： 10.11777/j.issn1000-3304.2016.16046.

摘要

以4-叔丁基苯乙烯(

BS)和甲基丙烯酸甲酯(MMA)为单体，二乙烯基苯(DVB)为交联剂，与双键修饰的Fe

纳米粒子共聚，制备了一系列基于

BS和MMA的磁性高分子吸油树脂.用红外光谱(FTIR)、X-射线衍射(XRD)、光学显微镜(OM)、扫描电子显微镜(SEM)、接触角(CA)和比表面积测试等技术对样品进行了表征.详细考察了两单体配比、交联剂用量对树脂的吸附容量、吸附速率的影响规律.实验发现，当两单体用量分别为2 mL，交联剂为0.5 mL时，磁性吸油树脂的吸油性能达到最好.

Abstract

Monolithic oil-absorbing polymers with magnetic responsiveness were prepared through solution radical polymerization combining with freeze-drying technology.A series of the polymer resins were first synthesized using different amount of 4-tert-butyl-styrene (

BS) and methyl methacrylate (MMA) in the presence of Fe

nanoparticles

which were modified by methacryloxy propyl trimethoxyl silane prior to the synthesis.Divinylbenzene (DVB) was used as cross linking agent and azodiisobutyronitrile as initiator in the polymerization carried out at 80℃ for 6 h.The obtained polymers were washed by ethanol/water several times and then freeze dried to obtain monolithic polymeric resins.The as-prepared monolithic polymers were characterized by Fourier transform infrared spectroscopy

X-ray diffraction

scanning electronic microscopy

optical microscope and contact angles of water droplet on the surface of polymers.Effects of molar ratio of MMA/

DVB amount on the oil absorption capacities and absorption rate were investigated in detail.Oil-absorbing polymeric resins with optimized property were prepared by selecting MMA as 2 mL

BS as 2 mL and DVB as 0.5 mL.The polymeric resins are hydrophobic and oleophilic.They can absorb more than 10 times of their own weight for different organic solvents and oils

such as dimethylbenzene

dichloroethane

ethyl acetate

-hexane

cyclohexane

trichloromethane

engineering and crude oil.And the oil-saturated absorption can be achieved within 20 min.The polymeric resins can also effectively absorb organic solvents from the oil/water mixture and the polymers still float on the surface of water.The oil-saturated polymer resins can be easily separated and collected from the surface of water by applying an external magnet.Furthermore

after the treatment of the absorbed oil

the polymer resins can be reused for oil absorption.The monolithic polymers can be recycled more than 10 times without obvious damaged.These magnetic oil-absorbing polymeric resins are potential candidates for dealing with oil spills.

关键词

4-叔丁基苯乙烯甲基丙烯酸甲酯Fe3O4纳米粒子吸油树脂

Keywords

4-Tert-butyl-styreneMethyl methacrylateFe3O4 nanoparticlesOil-absorption polymers

references

S G Xiong , H L Long , G P Tang , J Wan , H Y Li . Mar Pollut Bull , 2015 . 5 ( 27 ): 7 - 17.

V K Gupta , I Ali , T A Saleh , S Agarwal . RSC Adv , 2012 . 2 ( 16 ): 6380 - 6388 . DOI:10.1039/c2ra20340ehttp://doi.org/10.1039/c2ra20340e.

D Lan , B Liang , C Bao , Y Xu , C Yu . Mar Pollut Bull , 2015 . 96 ( 2 ): 220 - 225.

A L Rodd , M A Creighton , C A Vaslet , J B Rangel-Mendez , R H Hurt , A B Kane . Environ Sci Technol , 2014 . 48 ( 11 ): 6419 - 6427 . DOI:10.1021/es500892mhttp://doi.org/10.1021/es500892m.

X Y Zhou , Z Z Zhang , X H Xu , X H Men , X T Zhu . Ind Eng Chem Res , 2013 . 52 ( 27 ): 9411 - 9416 . DOI:10.1021/ie400942thttp://doi.org/10.1021/ie400942t.

X F Huang , T T Lim . Desalination , 2006 . 190 ( 1 ): 295 - 307.

D M Wei , H B Zheng , S S Zhang . Appl Mech Mater , 2014 . 535 666 - 670 . DOI:10.4028/www.scientific.net/AMM.535http://doi.org/10.4028/www.scientific.net/AMM.535.

Z Xue , Y Cao , N Liu , L Jiang . J Mater Chem A , 2014 . 2 ( 8 ): 2445 - 2460 . DOI:10.1039/C3TA13397Dhttp://doi.org/10.1039/C3TA13397D.

L Fan , H Chen , Z Hao , Z Tan . J Polym Sci,Part A:Polym Chem , 2013 . 51 ( 2 ): 457 - 462 . DOI:10.1002/pola.26404http://doi.org/10.1002/pola.26404.

J Wang , Y Zheng , Y Kang , A Wang . Chem Eng J , 2013 . 223 632 - 637 . DOI:10.1016/j.cej.2013.03.007http://doi.org/10.1016/j.cej.2013.03.007.

J Sun , Y Xu , H Chen , Z Tan , L Fan . Sep Sci Technol , 2014 . 49 ( 16 ): 2518 - 2524 . DOI:10.1080/01496395.2014.928322http://doi.org/10.1080/01496395.2014.928322.

X M Zhou , C Z Chuai . Polym Eng Sci , 2013 . 53 ( 3 ): 540 - 545 . DOI:10.1002/pen.v53.3http://doi.org/10.1002/pen.v53.3.

P Fang , P P Mao , J Chen , Y Du , X Hou . J Appl Polym Sci , 2014 . 131 ( 8 ): 40180 - 40189.

X Yuan , T C M Chung . Energy Fuels , 2012 . 26 ( 8 ): 4896 - 4902 . DOI:10.1021/ef300388hhttp://doi.org/10.1021/ef300388h.

Y P Wu , T Zhang , Z G Xu , Q P Guo . J Mater Chem A , 2015 . 3 ( 5 ): 1906 - 1909 . DOI:10.1039/C4TA05761Ahttp://doi.org/10.1039/C4TA05761A.

T Zhang , Y P Wu , Z G Xu , Q P Guo . Chem Commun , 2014 . 50 ( 89 ): 13821 - 13824 . DOI:10.1039/C4CC06674Jhttp://doi.org/10.1039/C4CC06674J.

J Zhou , L Wang , X Qiao , B P Binks , K Sun . J Colloid Interface Sci , 2012 . 367 ( 1 ): 213 - 224 . DOI:10.1016/j.jcis.2011.11.001http://doi.org/10.1016/j.jcis.2011.11.001.

L An , G Wang , X Shi , M Su , F Gao , Y Cheng . Russ J Phys Chem A , 2014 . 88 ( 13 ): 2419 - 2423 . DOI:10.1134/S0036024414130093http://doi.org/10.1134/S0036024414130093.

S Li , W Liang , F Zheng , H Zhou , X Lin , J Cai . Sens Actuators B Chem , 2016 . 224 48 - 54 . DOI:10.1016/j.snb.2015.10.016http://doi.org/10.1016/j.snb.2015.10.016.

T Ramani , P Umadevi , K L Prasanth , B Sreedhar . Europ J Org Chem , 2013 . 2013 ( 27 ): 6021 - 6026 . DOI:10.1002/ejoc.201300909http://doi.org/10.1002/ejoc.201300909.

Y Lin , G J Ehlert , C Bukowsky , H Sodano . ACS Appl Mater Interfaces , 2011 . 3 ( 7 ): 2200 - 2203 . DOI:10.1021/am200527jhttp://doi.org/10.1021/am200527j.

N Chen , Q Pan . ACS Nano , 2013 . 7 ( 8 ): 6875 - 6883 . DOI:10.1021/nn4020533http://doi.org/10.1021/nn4020533.

Yuanpeng Wu , Changliang Zhou , Lingjiang Guo , Hao Yang , Zhaohui Zheng , Xiaobin Ding . Acta Polymerica Sinica , 2016 . ( 4 ): 399 - 405 . http://www.gfzxb.org/CN/abstract/abstract14570.shtml.

武元鹏 , 周昌亮 , 郭凌江 , 杨浩 , 郑朝晖 , 丁小斌 . 高分子学报 , 2016 . ( 4 ): 399 - 405 . http://www.gfzxb.org/CN/abstract/abstract14570.shtml.

更多指标>

Views

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Reversible-deactivation Radical Polymerization of Methyl Methacrylate Mediated by Carbodiimide Catalysts

Kinetics of Methyl Methacrylate Polymerization Mediated by 4, 4'-Dimethoxydiphenyl Nitroxide

Effect of Graphene Modified by P[MMA-IL] on the Crystallization and Dielectric Behavior of PVDF Composite Film

Preparation and Characterization of Oil/Water Separation Membranes via Grafting Methyl Methacrylate onto Poly(vinylidene fluoride)

Transformation of the Counterion of Active Species and Anionic Block Copolymerization of PBMA-b-PMMA

Related Author

No data

Related Institution

State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology

State Key Laboratory of Chemical Engineering(Zhejiang University), College of Chemical Engineering and Biochemical Engineering, Zhejiang University

School of Chemistry and Chemical Engineering, Hefei University of Technology

Key Laboratory of Advanced Functional Materials and Devices

内蒙古科技大学化学与化工学院

Postal code：100190
Tel：010-62588927 Email：gfzxb@iccas.ac.cn
Technical support is provided by Beijing Founder electronics co., LTD 京ICP备05002797号-8 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰

Magnetic Responsive Oil-absorbing Polymeric Resins Based on 4-Tert-butyl-styrene and Methyl Methacrylate

DOI：10.11777/j.issn1000-3304.2016.16046

摘要

Abstract

关键词

Keywords

references