浏览全部资源
扫码关注微信
Mechanoluminescent Polymers
- Acta Polymerica Sinica Issue 11, Pages: 1495-1507(2016)
- 作者机构：
分子光电科学天津市重点实验室 天津大学 天津 300354
- 作者简介：
- 基金信息：
DOI：10.11777/j.issn1000-3304.2016.16223
CLC：Published：2016-11，
Received：6 July 2016，
Revised：22 July 2016，
扫 描 看 全 文
Wei Yuan, Yuan Yuan, Yu-lan Chen. Mechanoluminescent Polymers. [J]. Acta Polymerica Sinica (11):1495-1507(2016)
Wei Yuan, Yuan Yuan, Yu-lan Chen. Mechanoluminescent Polymers. [J]. Acta Polymerica Sinica (11):1495-1507(2016) DOI： 10.11777/j.issn1000-3304.2016.16223.
摘要
发展具有机械力诱导发光性质的高分子是目前高分子力化学领域的一个新兴前沿课题.这类响应性高分子材料由于能够将机械能转换成灵敏的光信号，是连接微观分子水平研究与宏观材料性能表征的桥梁，因而有望作为高灵敏（在空间和时间2个维度上）应力探针在高分子材料损伤探测与失效机理研究方面发挥重要作用.本文详细介绍了机械力诱导发光高分子的设计与合成策略，以及研究者对发光机理的探索、发光效率的优化、发光过程的应用，揭示这类高分子的发光特点及其作为应力探针的优势，归纳总结已取得的初步进展，并对这类新型响应性高分子材料的发展进行简单的评述和展望.
Abstract
The development of mechanoluminescent polymers is one of the emerging and frontier subjects in the field of polymer mechanochemistry.This important research effort has been driven by the need for advanced stress probes to report rare molecular scission events that precede failure in polymers.What is already known is that the stress-induced scission of chemical bonds often plays a critical role in failure initiation state
thus
precise location and timing of chain-scission events during fracture are although difficult in practice
yet key to understanding failure mechanisms.If these rare failure initiation events could be well characterized and cast in the language of organic and physical organic chemistry
opportunities for preventing and ameliorating early failure events will be obtained
and rational molecular strategies for advanced polymeric materials will result.Stimuli-responsive polymers
that can convert mechanical force into sensitive light signal
represent a unique platform that opens the way to the detailed study of the specific molecular failure events and the macroscopic properties of polymers
and therefore
are considered as a versatile spectroscopic probe capable of sensing and mapping deformations
stresses and damage in different polymer architectures with high spatial and temporal resolutions.In this review
the strategies for the design and synthesis of mechanoluminescent polymers
and the great efforts towards the understanding of the mechanisms of such mechanically induced light from polymers
the approaches to fine-tune the optophysical properties of the light (including light intensity
colour of light emission
and the force thresholds of light)
as well as the applications of mechanoluminescence to probe the failure of different polymers are comprehensively introduced.The unique features of mechanoluminescence from polymers and the advantages of these polymers as sensitive stress probes over other responsive polymers with measureable output are revealed.The progress achieved up to now is summarized
and a short outlook concerning the development of mechanoluminescent polymers is provided.
关键词
刺激响应高分子高分子力化学机械力诱导发光12-二氧环丁烷应力探针
Keywords
Stimuli-responsive polymerPolymer mechanochemistryMechanoluminescence12-DioxetaneStress probe
references
S N Zhurkov . Int J Fract , 1984 . 26 295 - 307 . DOI:10.1007/BF00962961http://doi.org/10.1007/BF00962961.
A Plumtree , G Cheng . Plast Rubber Compos , 1998 . 27 349 - 355.
K Liu , M R Piggott . Polym Eng Sci , 1998 . 38 60 - 68 . DOI:10.1002/(ISSN)1548-2634http://doi.org/10.1002/(ISSN)1548-2634.
T Li , M Zhang , H Zeng . J Mater Sci Lett , 2000 . 19 837 - 839 . DOI:10.1023/A:1006768927475http://doi.org/10.1023/A:1006768927475.
M R Wisnom . Compos Part A:Appl Sci Manufac , 2010 . 41 795 - 805 . DOI:10.1016/j.compositesa.2010.02.011http://doi.org/10.1016/j.compositesa.2010.02.011.
M Rheinfurth , P Fey , S Allinger , G Busse . Int J Fract , 2013 . 48 80 - 89.
N Zafeiropoulos , R J Davies , S V Roth , M Burghammer , K Schneider , C Riekel , M Stamm . Macromol Rapid Commun , 2005 . 26 1547 - 1551 . DOI:10.1002/(ISSN)1521-3927http://doi.org/10.1002/(ISSN)1521-3927.
M K Beyer , H Clausen-Schaumann . Chem Rev , 2005 . 105 2921 - 2948 . DOI:10.1021/cr030697hhttp://doi.org/10.1021/cr030697h.
M M Caruso , D A Davis , Q Shen , S A Odom , N R Sottos , S White . R,Moore J S.Chem Rev , 2009 . 109 5755 - 5798.
K M Wiggins , J N Brantley , C W Bielawski . Chem Soc Rev , 2013 . 42 7130 - 7147 . DOI:10.1039/c3cs35493hhttp://doi.org/10.1039/c3cs35493h.
R Groote , R T M Jakobs , R P Sijbesma . Polym Chem , 2013 . 4 4846 - 4859 . DOI:10.1039/c3py00071khttp://doi.org/10.1039/c3py00071k.
A L Black , J M Lenhardt , S L Craig . J Mater Chem , 2011 . 21 1655 - 1663 . DOI:10.1039/C0JM02636Khttp://doi.org/10.1039/C0JM02636K.
Y Chen , A J H Spiering , S Karthikeyan , G W M Peters , E W Meijer , R P Sijbesma . Nat Chem , 2012 . 4 559 - 562 . DOI:10.1038/nchem.1358http://doi.org/10.1038/nchem.1358.
H Staudinger , W Heuer . Ber Deutsch Chem Ges , 1934 . 67 1159 - 1164 . DOI:10.1002/cber.v67:7http://doi.org/10.1002/cber.v67:7.
W Kauzmann , H Eyring . J Am Chem Soc , 1940 . 62 3113 - 3125 . DOI:10.1021/ja01868a059http://doi.org/10.1021/ja01868a059.
J A Odell , A J Keller . Polym Sci,Part B:Polym Phys , 1986 . 24 1889 - 1916 . DOI:10.1002/polb.1986.090240901http://doi.org/10.1002/polb.1986.090240901.
Qi Wang , Canhui Lu , Hesheng Xia . Chin Polym Bull , 2013 . ( 9 ): 35 - 49.
王 琪 , 卢 灿辉 , 夏 和生 . 高分子通报 , 2013 . ( 9 ): 35 - 49.
Zhe Chen , Qi Wang , Xi Xu . Acta Polymerica Sinica , 2001 . ( 1 ): 13 - 16 . http://www.gfzxb.org/CN/abstract/abstract11045.shtml.
陈 哲 , 王 琪 , 徐 僖 . 高分子学报 , 2001 . ( 1 ): 13 - 16 . http://www.gfzxb.org/CN/abstract/abstract11045.shtml.
Changsheng Liu , Qi Wang . Acta Polymerica Sinica , 2000 . ( 2 ): 219 - 223 . http://www.gfzxb.org/CN/abstract/abstract10902.shtml.
刘 长生 , 王 琪 . 高分子学报 , 2000 . ( 2 ): 219 - 223 . http://www.gfzxb.org/CN/abstract/abstract10902.shtml.
Xiao Meng , Qi Chen , Zhangyuan Wang , Shu Xu , Yuguo Ma . Chin Polym Bull , 2014 . ( 8 ): 23 - 33.
孟 晓 , 陈 起 , 王 章远 , 徐 澎 , 马 玉国 . 高分子通报 , 2014 . ( 8 ): 23 - 33.
M B Larsen , Andrew J Boydston . J Am Chem Soc , 2013 . 135 8189 - 8192 . DOI:10.1021/ja403757phttp://doi.org/10.1021/ja403757p.
J M Clough , A Balan , R P Sijbesma . Top Curr Chem , 2015 . 369 209 - 238 . DOI:10.1007/978-3-319-22825-9http://doi.org/10.1007/978-3-319-22825-9.
A P Haehnel , Y Sagara , Y C Simon , C Weder . Top Curr Chem , 2015 . 369 345 - 375 . DOI:10.1007/978-3-319-22825-9http://doi.org/10.1007/978-3-319-22825-9.
D A Davis , A Hamilton , J L Yang , L D Cremar , D Van Gough , S L Potisek , M T Ong , P V Braun , T J Martinez , S R White , J S Moore , N R Sottos . Nature , 2009 . 459 68 - 72 . DOI:10.1038/nature07970http://doi.org/10.1038/nature07970.
C K Lee , D A Davis , S R White , J S Moore , N R Sottos , P V Braun . J Am Chem Soc , 2010 . 132 16107 - 16111 . DOI:10.1021/ja106332ghttp://doi.org/10.1021/ja106332g.
P A May , N F Munaretto , M B Hamoy , M J Robb , J S Moore . ACS Macro Lett , 2016 . 5 177 - 180 . DOI:10.1021/acsmacrolett.5b00855http://doi.org/10.1021/acsmacrolett.5b00855.
H Zhang , Y Chen , Y Lin , X Fang , Y Xu , Y Ruan , W G Weng . Macromolecules , 2014 . 47 6783 - 6790 . DOI:10.1021/ma500760phttp://doi.org/10.1021/ma500760p.
L Wang , X Zhou , X H Zhang , B Y Du . Macromolecules , 2016 . 49 98 - 104 . DOI:10.1021/acs.macromol.5b02383http://doi.org/10.1021/acs.macromol.5b02383.
G I Peterson , M B Larsen , M A Ganter . ACS Appl Mater Inter , 2015 . 7 577 - 583 . DOI:10.1021/am506745mhttp://doi.org/10.1021/am506745m.
G R Gossweiler , C L Brown , G B Hewage . ACS Appl Mater Inter , 2015 . 7 22431 - 2435 . DOI:10.1021/acsami.5b06440http://doi.org/10.1021/acsami.5b06440.
R Göstl , R P Sijbesma . Chem Sci , 2016 . 7 370 - 375 . DOI:10.1039/C5SC03297Khttp://doi.org/10.1039/C5SC03297K.
M.J Matsumoto . Photochem Photobiol C , 2005 . 5 27 - 53.
H Burrows , R Weir , J Stohner . Pure App Chem , 1987 . 59 639 - 650.
Y Chen , R P Sijbesma . Macromolecules , 2014 . 47 3797 - 3805 . DOI:10.1021/ma500598thttp://doi.org/10.1021/ma500598t.
J M Clough , R P Sijbesma . Chem Phys Chem , 2014 . 15 3565 - 3571.
J M Clough , A Balan , T J van Daal , R P Sijbesma . Angew Chem Int Ed , 2016 . 55 1445 - 1449 . DOI:10.1002/anie.201508840http://doi.org/10.1002/anie.201508840.
E Ducrot , Y Chen , M Bulters , R P Sijbesma , C Creton . Science , 2014 . 344 186 - 189 . DOI:10.1126/science.1248494http://doi.org/10.1126/science.1248494.
Z S Kean , J L Hawk , S T Lin , X Zhao , R P Sijbesma , S L Craig . Adv Mater , 2014 . 26 6013 -6018 . DOI:10.1002/adma.201401570http://doi.org/10.1002/adma.201401570.
T M Swager , J B Ravnsbæk . Synfacts , 2012 . 8 1084 DOI:10.1055/s-00000131http://doi.org/10.1055/s-00000131.
J P Gong . Science , 2014 . 344 161 - 162 . DOI:10.1126/science.1252389http://doi.org/10.1126/science.1252389.
0
Views
25
下载量
1
CSCD
- L-PDFDownload
- BibTeXDownload
- EndnoteDownload
- RefMan Download
- NoteExpressDownload
- NoteFirstDownload
Publicity Resources
Related Articles
Related Author
Related Institution
- Postal code：100190
- Tel：010-62588927 Email：gfzxb@iccas.ac.cn
- Technical support is provided by Beijing Founder electronics co., LTD 京ICP备05002797号-8
京公网安备11010802024621 - It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
- Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.