Preparation and Characterization of POSS-based Seven-arm Star-shaped Polymers <italic style="font-style: italic">via</italic> Living Anionic Polymerization

Yan Xue-sheng; Xu Jun; He Jin-lin; Zhang Ming-zu; Dai Li-xing; Ni Pei-hong

doi:10.11777/j.issn1000-3304.2017.16128

您当前的位置：

首页 >

文章列表页 >

Preparation and Characterization of POSS-based Seven-arm Star-shaped Polymers via Living Anionic Polymerization

Research Article | 更新时间：2021-03-19

- Preparation and Characterization of POSS-based Seven-arm Star-shaped Polymers via Living Anionic Polymerization
- Acta Polymerica Sinica Issue 3, Pages: 454-463(2017)
- 作者机构：
  
  苏州大学材料与化学化工学部新型功能高分子材料国家地方联合工程实验室苏州市大分子设计与精密合成重点实验室江苏省先进功能高分子材料设计及应用重点实验室苏州 215123
- 作者简介：
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2017.16128
  CLC：
- Published：2017-3，
  
  Received：12 April 2016，
  
  Revised：5 May 2016，
扫描看全文
Yan Xue-sheng, Xu Jun, He Jin-lin, Zhang Ming-zu, Dai Li-xing, Ni Pei-hong. Preparation and Characterization of POSS-based Seven-arm Star-shaped Polymers via Living Anionic Polymerization. [J]. Acta Polymerica Sinica (3):454-463(2017)
DOI：

Yan Xue-sheng, Xu Jun, He Jin-lin, Zhang Ming-zu, Dai Li-xing, Ni Pei-hong. Preparation and Characterization of POSS-based Seven-arm Star-shaped Polymers via Living Anionic Polymerization. [J]. Acta Polymerica Sinica (3):454-463(2017) DOI： 10.11777/j.issn1000-3304.2017.16128.

摘要

首先利用高真空活性负离子聚合方法制备聚异戊二烯锂（PI-Li）和（聚苯乙烯-

-聚异戊二烯）锂（PS-PI-Li）活性链，再与单羟基七乙烯基多面体齐聚倍半硅氧烷（VPOSS-OH）发生加成反应，一步法制备2种含羟基的七臂星形聚合物.用分级沉淀法去除低加成产物，即可得到纯的七臂星形聚合物7PI-POSS-OH和7（PS-PI）-POSS-OH，利用凝胶渗透色谱（GPC）、核磁共振波谱（

H-，

C-NMR）、红外光谱（FTIR）和基质辅助激光解吸电离飞行时间质谱（MALDI-TOF MS）表征了聚合物的化学结构、分子量及分子量分布，并通过热失重分析（TGA）测试了聚合物的热分解温度.

Abstract

The preparation of star-shaped polymers using incorporation of living anionic polymerization with polyhedral oligomeric silsesquioxane (POSS) is rarely reported. In this study

two types of POSS-cored star-shaped polymers were obtained by one-step addition reaction. Firstly

the living (polyisopryl)lithium (PI-Li) and living polystyrene-block-polyisoprene block copolymer chain (PS-PI-Li) were synthesized by high-vacuum living anionic polymerization. Meanwhile

a POSS derivative with one hydroxyl and seven vinyl groups (VPOSS-OH) was prepared by the addition of triflic acid to commercial octavinyl POSS with eight vinyl groups (V

). Subsequently

the mono-hydroxyl functionalized seven-arm star polymers were prepared by directly adding living PI-Li or PS-PI-Li to VPOSS-OH in benzene. The purified star-shaped polyisoprene 7PI-POSS-OH and star-block copolymer 7(PS-PI)-POSS-OH were obtained after fractionation precipitation

and then characterized by nuclear magnetic resonance (

H- and

C-NMR)

gel permeation chromatography (GPC)

Fourier transform infrared spectroscopy (FTIR) and matrix-assisted laser desorption/ionization time-of-flight (MALDI-TOF) mass spectroscopy

respectively. By changing the feed ratio of the monomer to initiator

the polymers with different degree of polymerizations were synthesized. The compositions of the polymers were calculated by comparison of the integrals of the characteristic signals from

H-NMR spectra. GPC analysis indicated that the trace of the crude products showed an apparent shift to smaller retention time compared with that of the base PI or PS-PI. The fractionated samples had symmetric peaks and relatively narrow polydispersity. MALDI-TOF MS tests demonstrated that the base PS gave a single molecular weight distribution

and the observed molecular weight was in good agreement with the calculated value. The similar result was also found for the base PS-PI. However

the MALDI-TOF MS spectra were not obtained for the fractionated star-shaped polymers

possibly because of their high molecular weights. TGA analysis showed that the thermal decomposition temperature of 7PI-POSS-OH and 7(PS-PI)-POSS-OH was higher than the base PI and the block copolymer PS-PI. In addition

it was also found that about 6% of residue left at 600℃

which may be due to the incorporation of POSS segment. The process reported here may serve as an alternative approach to produce functional star-shaped polymers by changing the structure of the initiators and the monomers.

关键词

高真空活性负离子聚合多面体齐聚倍半硅氧烷POSS星形聚合物

Keywords

Living anionic polymerizationPolyhedral oligomeric silsesquioxanePOSSStar-shaped polymer

references

Y Abe , T Gunji . . Prog Polym Sci , 2004 . 29 ( 3 ): 149 - 182 . DOI:10.1016/j.progpolymsci.2003.08.003http://doi.org/10.1016/j.progpolymsci.2003.08.003.

K Tanaka , Y Chujo . . J Mater Chem , 2012 . 22 ( 5 ): 1733 - 1746 . DOI:10.1039/C1JM14231Chttp://doi.org/10.1039/C1JM14231C.

F K Wang , X H Lu , C B He . . J Mater Chem , 2011 . 21 ( 9 ): 2775 - 2782 . DOI:10.1039/C0JM02785Ehttp://doi.org/10.1039/C0JM02785E.

Yonggang Hou , Qiuyu Zhang , Hepeng Zhang , Aijie Ma , Jiuli Sun . . Chemistry Online , 2010 . 73 ( 3 ): 227 - 234.

侯永刚 , 张秋禹 , 张和鹏 , 马爱洁 , 孙九立 . . 化学通报 , 2010 . 73 ( 3 ): 227 - 234.

D B Cordes , P D Lickiss , F Rataboul . . Chem Rev , 2010 . 110 ( 4 ): 2081 - 2173 . DOI:10.1021/cr900201rhttp://doi.org/10.1021/cr900201r.

S W Kuo , F C Chang . . Prog Polym Sci , 2011 . 36 ( 12 ): 1649 - 1696 . DOI:10.1016/j.progpolymsci.2011.05.002http://doi.org/10.1016/j.progpolymsci.2011.05.002.

G Z Li , L C Wang , H L Ni , Jr C U Pittman . . J Inorg Organomet Polym , 2001 . 11 ( 3 ): 123 - 154 . DOI:10.1023/A:1015287910502http://doi.org/10.1023/A:1015287910502.

W A Zhang , A H E Müller . . Prog Polym Sci , 2013 . 38 ( 8 ): 1121 - 1162 . DOI:10.1016/j.progpolymsci.2013.03.002http://doi.org/10.1016/j.progpolymsci.2013.03.002.

Kaiqiang Zhang , Bo Li , Yunhui Zhao , Hui Li , Xiaoyan Yuan . . Progress in Chemistry , 2014 . 26 ( 2/3 ): 394 - 402.

张凯强 , 李博 , 赵蕴慧 , 李辉 , 袁晓燕 . . 化学进展 , 2014 . 26 ( 2/3 ): 394 - 402.

H Q Guo , M A B Meador , L McCorkle , D J Quade , J Guo , B Hamilton , M Cakmak , G Sprowl . . ACS Appl Mater Interfaces , 2011 . 3 ( 2 ): 546 - 552 . DOI:10.1021/am101123hhttp://doi.org/10.1021/am101123h.

W B Zhang , X F Yu , C L Wang , H J Sun , I F Hsieh , Y W Li , X H Dong , K Yue , Horn R van , S Z D Cheng . . Macromolecules , 2014 . 47 ( 4 ): 1221 - 1239 . DOI:10.1021/ma401724phttp://doi.org/10.1021/ma401724p.

W B Zhang , S Z D Cheng . . Chinese J Polym Sci , 2015 . 33 ( 6 ): 797 - 814 . DOI:10.1007/s10118-015-1653-8http://doi.org/10.1007/s10118-015-1653-8.

Wenbin Zhang , Xiaoman Wang , Xiaowei Wang , Dong Liu , Shuaiyuan Han , Stephen Z D Cheng . . Progress in Chemistry , 2015 . 27 ( 10 ): 1333 - 1342.

张文彬 , 王晓曼 , 王晓威 , 刘栋 , 韩帅元 , 程正迪 . . 化学进展 , 2015 . 27 ( 10 ): 1333 - 1342.

Y W Li , W B Zhang , I F Hsieh , G L Zhang , Y Cao , X P Li , C Wesdemiotis , B Lotz , H M Xiong , S Z D Cheng . . J Am Chem Soc , 2011 . 133 ( 28 ): 10712 - 10715 . DOI:10.1021/ja202906mhttp://doi.org/10.1021/ja202906m.

X F Yu , K Yue , I F Hsieh , Y W Li , X H Dong , C Liu , Y Xin , H F Wang , A C Shi , G R Newkome , R M Ho , E Q Chen , W B Zhang , S Z D Cheng . . Proc Natl Acad Sci USA , 2013 . 110 ( 25 ): 10078 - 10083 . DOI:10.1073/pnas.1302606110http://doi.org/10.1073/pnas.1302606110.

M J Huang , C H Hsu , J Wang , S Mei , X H Dong , Y W Li , M X Li , H Liu , W Zhang , T Aida , W B Zhang , K Yue , S Z D Cheng . . Science , 2015 . 348 ( 6233 ): 424 - 428 . DOI:10.1126/science.aaa2421http://doi.org/10.1126/science.aaa2421.

C H Hsu , X H Dong , Z W Lin , B Ni , P T Lu , Z Jiang , D Tian , A C Shi , E L Thomas , S Z D Cheng . . ACS Nano , 2016 . 10 ( 1 ): 919 - 929 . DOI:10.1021/acsnano.5b06038http://doi.org/10.1021/acsnano.5b06038.

X H Dong , B Ni , M J Huang , C H Hsu , R B Bai , W B Zhang , A C Shi , S Z D Cheng . . Angew Chem Int Ed , 2016 . 55 ( 7 ): 2459 - 2463 . DOI:10.1002/anie.201510524http://doi.org/10.1002/anie.201510524.

G S Grest , L J Fetters , J S Huang , D Richter . . Adv Chem Phys , 1996 . 94 67 - 163.

K Inoue . . Prog Polym Sci , 2000 . 25 ( 4 ): 453 - 571 . DOI:10.1016/S0079-6700(00)00011-3http://doi.org/10.1016/S0079-6700(00)00011-3.

N Hadjichristidis , H Iatrou , M Pitsikalis , J Mays . . Prog Polym Sci , 2006 . 31 ( 12 ): 1068 - 1132 . DOI:10.1016/j.progpolymsci.2006.07.002http://doi.org/10.1016/j.progpolymsci.2006.07.002.

H F Gao , K Matyjaszewski . . Prog Polym Sci , 2009 . 34 ( 4 ): 317 - 350 . DOI:10.1016/j.progpolymsci.2009.01.001http://doi.org/10.1016/j.progpolymsci.2009.01.001.

O Altintas , A P Vogt , C Barner-Kowollik , U Tunca . . Polym Chem , 2012 . 3 ( 1 ): 34 - 45 . DOI:10.1039/C1PY00249Jhttp://doi.org/10.1039/C1PY00249J.

Y Sun , C B He . . Macromolecules , 2013 . 46 ( 24 ): 9625 - 9633 . DOI:10.1021/ma4020615http://doi.org/10.1021/ma4020615.

Y Y Yang , X Wang , Y Hu , H Hu , D C Wu , F J Xu . . ACS Appl Mater Interfaces , 2014 . 6 ( 2 ): 1044 - 1052 . DOI:10.1021/am404585dhttp://doi.org/10.1021/am404585d.

Y M Li , B Xu , T Bai , W G Liu . . Biomaterials , 2015 . 55 12 - 23 . DOI:10.1016/j.biomaterials.2015.03.034http://doi.org/10.1016/j.biomaterials.2015.03.034.

M Szwarc . . Nature , 1956 . 178 1168 - 1169 . DOI:10.1038/1781168a0http://doi.org/10.1038/1781168a0.

N Hadjichristidis , H Iatrou , S Pispas , M Pitsikalis . . J Polym Sci, Part A:Polym Chem , 2000 . 38 ( 18 ): 3211 - 3234 . DOI:10.1002/(ISSN)1099-0518http://doi.org/10.1002/(ISSN)1099-0518.

D Uhrig , J W Mays . . J Polym Sci, Part A:Polym Chem , 2005 . 43 ( 24 ): 6179 - 6222 . DOI:10.1002/(ISSN)1099-0518http://doi.org/10.1002/(ISSN)1099-0518.

Hongwei Ma , Yang Li , Chunqing Zhang , Yurong Wang . . Polymer Bulletin , 2011 . ( 9 ): 35 - 51.

马红卫 , 李杨 , 张春庆 , 王玉荣 . . 高分子通报 , 2011 . ( 9 ): 35 - 51.

Hongwei Ma , Chunqing Zhang , Yang Li , Yurong Wang , Yanming Hu , Zhansheng Li , Zhongfu Zhao , Kaihua Shen . . Acta Polymerica Sinica , 2011 . ( 12 ): 1390 - 1394 . http://www.gfzxb.org/CN/abstract/abstract13343.shtml.

马红卫 , 张春庆 , 李杨 , 王玉荣 , 胡雁鸣 , 李战胜 , 赵忠夫 , 申凯华 . . 高分子学报 , 2011 . ( 12 ): 1390 - 1394 . http://www.gfzxb.org/CN/abstract/abstract13343.shtml.

H L Hsieh , R P Quirk . Anionic Polymerization:Principles and Practical Applications , : New York Marcel Dekker , 1996 .

N Hadjichristidis , M Pitsikalis , S Pispas , H Iatrou . . Chem Rev , 2001 . 101 ( 12 ): 3747 - 3792 . DOI:10.1021/cr9901337http://doi.org/10.1021/cr9901337.

A Hirao , M Hayashi , S Loykulnant , K Sugiyama , S W Ryu , N Haraguchi , A Matsuo , T Higashihara . . Prog Polym Sci , 2005 . 30 ( 2 ): 111 - 182 . DOI:10.1016/j.progpolymsci.2004.12.002http://doi.org/10.1016/j.progpolymsci.2004.12.002.

D Uhrig , R Schlegel , R Weidisch , J Mays . . Eur Polym J , 2011 . 47 ( 4 ): 560 - 568 . DOI:10.1016/j.eurpolymj.2010.10.030http://doi.org/10.1016/j.eurpolymj.2010.10.030.

A Hirao , R Goseki , T Ishizone . . Macromolecules , 2014 . 47 ( 6 ): 1883 - 1905 . DOI:10.1021/ma401175mhttp://doi.org/10.1021/ma401175m.

L X Hong , S H Yang , J P He . . Eur Polym J , 2015 . 65 171 - 190 . DOI:10.1016/j.eurpolymj.2015.02.019http://doi.org/10.1016/j.eurpolymj.2015.02.019.

G C Zhang , J Zheng , F Liu , Z J Zhang , L Ma , T Tang . . Chinese J Polym Sci , 2014 . 32 ( 6 ): 731 - 742 . DOI:10.1007/s10118-014-1448-3http://doi.org/10.1007/s10118-014-1448-3.

R Goseki , A Hirao , M Kakimoto , T Hayakawa . . ACS Macro Lett , 2013 . 2 ( 7 ): 625 - 629 . DOI:10.1021/mz400125thttp://doi.org/10.1021/mz400125t.

W B Zhang , J L He , K Yue , C Liu , P H Ni , R P Quirk , S Z D Cheng . . Macromolecules , 2012 . 45 ( 21 ): 8571 - 8579 . DOI:10.1021/ma301597fhttp://doi.org/10.1021/ma301597f.

F J Feher , K D Wyndham , R K Baldwin , D Soulivong , J D Lichtenhan , J W Ziller . . Chem Commun , 1999 . 14 1289 - 1290.

Lifeng Chen , Junpo He . . Acta Polymerica Sinica , 2015 . ( 8 ): 973 - 981 . http://www.gfzxb.org/CN/abstract/abstract14356.shtml.

陈李峰 , 何军坡 . . 高分子学报 , 2015 . ( 8 ): 973 - 981 . http://www.gfzxb.org/CN/abstract/abstract14356.shtml.

更多指标>

Views

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Living Anionic Synthesis of Eight-arm Star-shaped Block Copolymer and Study on Its Hydrogenation

Preparation and Characterization of Functionalized POSS Derivatives and Multi-arm Star-shaped Polyesters

Anionic Synthesis and Characterization of Epoxidized Eight-arm Star-shaped Polyisoprene

Anionic Synthesis of Heptaisobutyl Polyhedral Oligomeric Silsesquioxane Functionalized Polystyrene

Preparation of Porous Films with Tadpole-shaped POSS-Poly(fluorinated acrylate)s

Related Author

No data

Related Institution

College of Chemistry, Chemical Engineering and Materials Science, State and Local Joint Engineering Laboratory for Novel Functional Polymeric Materials, Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, Suzhou Key Laboratory of Macromolecular Design and Precision Synthesis, Soochow University

College of Transportation Equipments and Ocean Engineering, Dalian Maritime University

Key Laboratory of Space Applied Physics and Chemistry, Ministry of Education, Key Laboratory of Polymer Science and Technology, Shaanxi Province, Northwestern Polytechnical University

桂林理工大学广西矿冶与环境科学实验中心有色金属及材料加工新技术教育部重点实验室材料科学与工程学院

Postal code：100190
Tel：010-62588927 Email：gfzxb@iccas.ac.cn
Technical support is provided by Beijing Founder electronics co., LTD 京ICP备05002797号-8 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰

Preparation and Characterization of POSS-based Seven-arm Star-shaped Polymers via Living Anionic Polymerization

DOI：10.11777/j.issn1000-3304.2017.16128

摘要

Abstract

关键词

Keywords

references