PEDOT-PSS/PVA Composite Conductive Textile with Electromagnetic Wave Absorption Properties Prepared by <italic style="font-style: italic">in situ</italic> Polymerization

Xin Li; Ying-tao Xu; Yi-ping Zheng; Yan Zhang; Cong-ju Li; Guang-ming Chen

doi:10.11777/j.issn1000-3304.2017.16158

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PEDOT-PSS/PVA Composite Conductive Textile with Electromagnetic Wave Absorption Properties Prepared by in situ Polymerization

Research Article | 更新时间：2021-05-18

- PEDOT-PSS/PVA Composite Conductive Textile with Electromagnetic Wave Absorption Properties Prepared by in situ Polymerization
- Acta Polymerica Sinica Issue 4, Pages: 661-668(2017)
- 作者机构：
  
  1.北京服装学院材料科学与工程学院服装材料研究开发与评价北京市重点实验室北京 100029
  2.北京分子科学国家实验室中国科学院化学研究所北京 100190
- 作者简介：
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2017.16158
  CLC：
- Published：20 April 2017，
  
  Received：3 June 2016，
  
  Revised：2 August 2016，
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Xin Li, Ying-tao Xu, Yi-ping Zheng, Yan Zhang, Cong-ju Li, Guang-ming Chen. PEDOT-PSS/PVA Composite Conductive Textile with Electromagnetic Wave Absorption Properties Prepared by in situ Polymerization. [J]. Acta Polymerica Sinica (4):661-668(2017)
DOI：

Xin Li, Ying-tao Xu, Yi-ping Zheng, Yan Zhang, Cong-ju Li, Guang-ming Chen. PEDOT-PSS/PVA Composite Conductive Textile with Electromagnetic Wave Absorption Properties Prepared by in situ Polymerization. [J]. Acta Polymerica Sinica (4):661-668(2017) DOI： 10.11777/j.issn1000-3304.2017.16158.

摘要

在自行织造的聚（3，4-乙烯二氧噻吩）-聚对苯乙烯磺酸钠/聚乙烯醇（PEDOT-PSS/PVA）导电织物表面，通过原位聚合法生成了致密的PEDOT-PSS导电聚合物覆盖层，所得织物称之为

in situ

PEDOT-PSS/PVA复合导电织物.研究发现，在优化的合成条件下，

in situ

PEDOT-PSS/PVA复合导电织物具有优异的导电性能，其表面电阻最低可达2 Ω/cm

.电磁屏蔽性能测试结果表明，单层

in situ

PEDOT-PSS/PVA导电复合织物的电磁屏蔽效能可达12 dB左右，屏蔽率约为75%；在4~18 GHz的范围内，其电磁波反射率大部分都在-5~-10 dB之间，可吸收75%~90%的电磁波，基本达到了军事吸波材料的要求.

Abstract

On the surface of self-made PEDOT-PSS/PVA conductive textiles

compact and uniform PEDOT-PSS conductive coating is formed by

in situ

polymerization

and the resulted composite conductive textile is called

in situ

PEDOT-PSS/PVA. The synthesis conditions of the

in situ

polymerization are optimized. The morphology

structure and properties of the

in situ

PEDOT-PSS/PVA are measured. It is shown that the optimum molar ration of the reactant is [PSS]:[FeCl

]:[EDOT]

= 2.1:1.4:1 with a reaction time of 10 h. The resulted

in situ

PEDOT-PSS/PVA has excellent conductive property with a low surface resistance of 2 Ω/□ and electron conductivity of 360 S/cm under the optimized synthesis condition

which may be resulted from the synergistic action between PEDOT-PSS inside the fiber and the surface coating

forming the connected and effective conductive path to facilitate the electron transport. FTIR analysis indicates that there exists strong bonding force between base textile and PEDOT-PSS coating. Besides

the

in situ

PEDOT-PSS/PVA has strong near infrared shielding capability. The XPS measurements show that the sulfur content of the

in situ

PEDOT-PSS/PVA is much higher than that of the PEDOT-PSS/PVA

implying a higher PEDOT-PSS conductive component

which is also responsible for its low surface resistance. Moreover

the electromagnetic shielding measurements demonstrate that the electromagnetic shielding effectiveness of the

in situ

PEDOT-PSS/PVA can reach to 12 dB with a shielding efficiency of 75% compared with the 0 dB of PEDOT-PSS/PVA. In the range of 4 ~ 18 GHz

the most reflectivity of electromagnetic wave is between-5 and-10 dB

which can absorb 75% ~ 90% electromagnetic wave. Furthermore

the

in situ

PEDOT-PSS/PVA composite conductive textile presents a higher stability

good fastness to washing and acid resistance. The results indicate that the

in situ

polymerization is an effective method to improve the conductive property of PEDOT-PSS/PVA conductive textile

and the resulted

in situ

PEDOT-PSS/PVA composite conductive textile has an important application prospect as a novel kind of military electromagnetic wave absorption material.

关键词

PEDOT-PSS复合导电织物原位聚合电磁波吸收功能

Keywords

PEDOT-PSSConductive textileIn situ polymerizationElectromagnetic wave absorption properties

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Jiangxi Provincial Key Laboratory of New Energy Chemistry/Institute of Polymers, Nanchang University

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⁰

PEDOT-PSS/PVA Composite Conductive Textile with Electromagnetic Wave Absorption Properties Prepared by in situ Polymerization

DOI：10.11777/j.issn1000-3304.2017.16158

摘要

Abstract

关键词

Keywords

references