Recent Progress in Two-way Shape Memory Crystalline Polymer and Its Composites

Miao-ming Huang; Xia Dong; Wei-li Liu; Xia Gao; Du-jin Wang

doi:10.11777/j.issn1000-3304.2017.16229

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Recent Progress in Two-way Shape Memory Crystalline Polymer and Its Composites

Reviews | 更新时间：2021-05-18

- Recent Progress in Two-way Shape Memory Crystalline Polymer and Its Composites
- Acta Polymerica Sinica Issue 4, Pages: 563-579(2017)
- 作者机构：
  
  1.北京市理化分析测试中心有机材料检测技术与质量评价北京市重点实验室北京 100089
  2.中国科学院化学研究所中国科学院工程塑料院重点实验室北京分子科学国家实验室北京 100190
- 作者简介：
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2017.16229
  CLC：
- Published：2017-6，
  
  Received：13 July 2016，
  
  Revised：15 August 2016，
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Miao-ming Huang, Xia Dong, Wei-li Liu, Xia Gao, Du-jin Wang. Recent Progress in Two-way Shape Memory Crystalline Polymer and Its Composites. [J]. Acta Polymerica Sinica (4):563-579(2017)
DOI：

Miao-ming Huang, Xia Dong, Wei-li Liu, Xia Gao, Du-jin Wang. Recent Progress in Two-way Shape Memory Crystalline Polymer and Its Composites. [J]. Acta Polymerica Sinica (4):563-579(2017) DOI： 10.11777/j.issn1000-3304.2017.16229.

摘要

形状记忆聚合物是一种典型的智能材料，具有质轻、形变量大、可对多种刺激进行响应等优点.根据形状记忆过程的可逆性进行分类，形状记忆效应可以分为2种：单向与双向形状记忆效应.与不可逆的单向形状记忆过程相比，双向形状记忆过程是可逆的，样品不需要使用者进行再次变形，就可以在原始形状与临时形状之间进行可逆转换，因此其具有极高的实用价值与广阔的应用前景，受到各国研究人员的广泛关注，成为当前的研究热点之一.本文总结了近年来所研究的双向形状记忆结晶聚合物及其复合材料，包括恒外力条件下（外力 ≠ 0）的准双向形状记忆结晶聚合物，无外力条件下的双向形状记忆结晶聚合物及其复合材料.具体来说，前者包括在恒外力作用下的化学或物理交联的结晶聚合物.后者包括双层或核-壳聚合物复合材料、由分步交联得到的双网络交联结晶聚合物、化学交联的双组分结晶聚合物、具有较宽熔融转变的化学交联结晶聚合物与物理交联的结晶聚合物.重点关注了这些材料的制备方法、影响因素及相应的双向形状记忆机理，并对其研究前景进行了展望.

Abstract

As a sort of intelligent material

shape memory polymer material is outstanding in various aspects

such as lower density

high recoverable strain

and in response to a vast array of external stimuli. According to whether the shape memory process is reversible or not

the shape memory effect could be classified into two categories: one-way shape memory effect and two-way shape memory effect. The one-way shape memory process is actually irreversible

in which the recovered permanent shape cannot revert back to the temporary shape by merely altering the external stimulus and a re-programming process is necessarily needed. On the contrary

the two-way one is fully reversible

meaning that the sample would be able to vary between distinguished shapes reversibly without external re-shaping process applied by user. As a consequence

two-way shape memory polymer materials have high practical values and broad application prospects

which have aroused wide attention and become one of the hot spots of current researches. This work presents a brief review of two-way shape memory crystalline polymer and its composites that have been investigated and developed in recent years

including quasi two-way shape memory crystalline polymer under constant external stress and two-way shape memory crystalline polymer plus its composites without external stress. More specifically

the former consists of chemically and physically cross-linked crystalline polymer with persistent external stress

while the latter is comprised of polymer laminates

polymer/elastomer core/shell composites

chemically cross-linked crystalline polymer possessing dual-cure network architectures

chemically cross-linked two-component crystalline polymer

chemically cross-linked crystalline polymer with a broad melting transition

and physically cross-linked crystalline polymer. More importantly

preparation methods

influencing factors and the corresponding two-way shape memory mechanism of the aforementioned materials are introduced and discussed in detail. In the end

the future developments and research directions of these polymer materials are proposed as well.

关键词

双向形状记忆结晶聚合物复合材料机理外力作用

Keywords

Two-way shape memory effectCrystalline polymerCompositesMechanismExternal stress

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