Research Progress on Phase Transformation Behavior of <italic style="font-style: italic">β</italic> to <italic style="font-style: italic">α</italic>-Form Isotactic Polypropylene

Wei-wei Zhen; Hui-hui Li; Shou-ke Yan

doi:10.11777/j.issn1000-3304.2017.16240

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Research Progress on Phase Transformation Behavior of β to α-Form Isotactic Polypropylene

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- Research Progress on Phase Transformation Behavior of β to α-Form Isotactic Polypropylene
- Acta Polymerica Sinica Issue 4, Pages: 580-586(2017)
- 作者机构：
  
  北京化工大学化工资源有效利用国家重点实验室北京 100029
- 作者简介：
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2017.16240
  CLC：
- Published：2017-4，
  
  Received：31 July 2016，
  
  Revised：29 August 2016，
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Wei-wei Zhen, Hui-hui Li, Shou-ke Yan. Research Progress on Phase Transformation Behavior of β to α-Form Isotactic Polypropylene. [J]. Acta Polymerica Sinica (4):580-586(2017)
DOI：

Wei-wei Zhen, Hui-hui Li, Shou-ke Yan. Research Progress on Phase Transformation Behavior of β to α-Form Isotactic Polypropylene. [J]. Acta Polymerica Sinica (4):580-586(2017) DOI： 10.11777/j.issn1000-3304.2017.16240.

摘要

等规聚丙烯（iPP）是典型的多晶型半结晶性聚合物，其常见晶型有单斜（

），三方（

），三斜（

）以及四方或双四方（

），其中稳定性最好的

晶型和处于亚稳态的

晶型工业和经济价值较大，因此二者之间的相转变行为得到了人们的广泛关注.本文综述了近年来

→

-iPP生长相转变的研究进展.在高临界温度（141℃）和低临界温度（100 ℃）区间内，

-iPP生长速率高于

-iPP，而温度高于141 ℃，或低于100 ℃，由于

-iPP在动力学上占优势，

-iPP会发生向

-iPP的生长转变.但由于

-iPP是热力学上最稳定的晶型，

-iPP熔融重结晶过程也会发生

→

-iPP相转变.此外，拉伸形变过程中也会发生

→

-iPP相转变，广泛用于制备聚丙烯气体交换膜、过滤膜或锂电池隔膜等.目前对变形过程中的

→

-iPP相转变机理还存在争议，本文也对2种主要的机理进行了介绍，并对聚丙烯晶型转变行为的研究方向进行了展望.

Abstract

Isotactic polypropylene (iPP) is a semi-crystalline polymer which exhibits polymorphisms

designated respectively as monoclinic

trigonal

orthorhombic

-and tetragonal

-form. Due to the industrial and economic value

-and

-iPP have been widely studied

and the transformation behavior between these two phases has been extensively investigated. Therefore

studies in recent years with the focus on such topic are generally reviewed in this article. Originally

the growth rate of

-iPP is over that of

-iPP between high critical temperature (141 ℃) and low critical temperature (100-105 ℃). But when the temperature is higher than 141 ℃ or lower than 100 ℃

→

-iPP phase transformation could occur

for

-iPP is kinetically favorable. This growth transformation can be realized by two-step crystallization of iPP. Besides

such phase transformation would take place during melting and recrystallization because

-iPP crystals are thermodynamically more stable. Moreover

the

→

-iPP phase transformation can also be observed during deformation at room temperature or high temperature

and microporous membranes can be prepared

via

this process due to the higher density of

-iPP. Such products could be used as gas exchange membrane

filter membrane or separator of lithium-ion batteries. Since the transformation mechanism during deformation is still controversial

the article also reviews two proposed ideas about it. One is that the transformation during stretching should experience partial melting and recrystallization

and the other is just a solid-solid phase transformation. In addition

there are problems remaining that should be further explored about the

→

-iPP phase transformation. For example

it is still unknown whether there is crystallographic relationship between new formed

-iPP and original

-iPP during two-step crystallization

or it is just realized by a nucleation process. So

this will be an appealing direction for researchers in the field of polymer physics.

关键词

等规聚丙烯α相等规聚丙烯β相等规聚丙烯相转变

Keywords

Isotactic polypropyleneα-Form isotactic polypropyleneβ-Form isotactic polypropylenePhase transformation

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School of Polymer Science and Engineering, Shandong Provincial Key Laboratory of Olefin Catalysis and Polymerization, Key Laboratory of Rubber-plastics of Ministry of Education, Qingdao University of Science and Technology

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College of Material and Metallurgy, Guizhou University

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⁰

Research Progress on Phase Transformation Behavior of β to α-Form Isotactic Polypropylene

DOI：10.11777/j.issn1000-3304.2017.16240

摘要

Abstract

关键词

Keywords

references