Photo-responsive Supramolecular Polymers

Ma Xiang; Tian He

doi:10.11777/j.issn1000-3304.2017.16253

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Photo-responsive Supramolecular Polymers

Feature Articles | 更新时间：2021-03-12

- Photo-responsive Supramolecular Polymers
- Acta Polymerica Sinica Issue 1, Pages: 27-36(2017)
- 作者机构：
  
  华东理工大学化学与分子工程学院精细化工研究所结构可控先进功能材料及其制备教育部重点实验室上海 200237
- 作者简介：
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2017.16253
  CLC：
- Published：2017-1，
  
  Received：26 July 2016，
  
  Revised：12 August 2016，
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Ma Xiang, Tian He. Photo-responsive Supramolecular Polymers. [J]. Acta Polymerica Sinica (1):27-36(2017)
DOI：

Ma Xiang, Tian He. Photo-responsive Supramolecular Polymers. [J]. Acta Polymerica Sinica (1):27-36(2017) DOI： 10.11777/j.issn1000-3304.2017.16253.

摘要

超分子聚合物是超分子化学、高分子化学和材料化学领域的研究热点.将光响应的功能基团以非共价作用构筑到超分子聚合物体系中，得到光响应型超分子聚合物，从而能够将超分子聚合物的独特性质与光化学反应的优势有效地结合起来，从而构筑新型的光功能材料.本文总结了近年来本课题组有关光响应超分子聚合物方面的研究工作：介绍了主链型的光响应超分子聚合物的光调控组装和解离，超分子聚合物和共价聚合物的光控可逆切换和光调控组装形貌；另外还举例介绍了具有自修复和室温磷光发射等功能的侧链型光响应超分子聚合物，并对刺激-响应的超分子聚合物领域的发展做了展望.

Abstract

Supramolecular polymer has been the hotspot in the field of supramolecular chemistry

polymer chemistry and material chemistry which has received unprecedented support from a growing number of scientific researchers. Supramolecular polymers are defined as highly directional and ordered polymeric arrays of monomeric units which are brought together by reversible noncovalent interactions including hydrogen bonding

host-guest recognition

donor-acceptor interaction

metal-ligand coordination

and

stacking. Photo-responsive functional groups are incorporated into supramolecular polymer systems to obtain photo-responsive supramolecular polymers

which could efficiently combine the unique characteristics of supramolecular polymer and the advantages of photochemical reactions in order to construct novel photochromic materials. Supramolecular polymer chemistry now comprises broad researching areas including main-chain supramolecular polymers and side-chain supramolecular polymers

as well as hierarchical structures. This monograph reviews the recent progress on photo-responsive supramolecular polymers in our group. Specifically

photo-switching between monomer/oligomer and supramolecular polymers constructed

via

cyclodextrin

cucurbituril and bis-p-sulfonatocalix

[

]

arene host recognition were illustrated respectively

together with such various functions as photochromism

aggregation-induced emission

gelation

and so forth. Covalent/noncovalent bond transitions in linear and netlike supramolecular polymers were introduced in details

typically

via

the photo-induced reversible dimerization reaction of such photo-active groups as coumarin

anthracene

stilbene

etc

. Photo-responsive reversible morphology transitions of supramolecular polymers realized

via

photo-responsive reversible chiral morphology transition

via

cyclodextrin including azobenzene group and those containing chiral binaphthol group in the system

photochrosim and isomerization of the groups in the system. Other functional supramolecular polymers based on the supramolecular interactions in the side chains

like self-healing property realized by the host-guest interaction between the cyclodextrin and bromonaphthalene moieties on their side chains

and cyclodextrin host and hydrogen bonding induced room temperature phosphorescence emission

were also well introduced. Finally

comments and some prospects were given on the future research of the supramolecular polymers as well.

关键词

超分子聚合物光响应荧光室温磷光

Keywords

Supramolecular polymerPhoto-responsiveFluorescenceRoom-temperature phosphorescence

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