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Study on Supramolecular Polymers in China: An Overview and Outlook
- Acta Polymerica Sinica Issue 1, Pages: 37-49(2017)
- 作者机构：
清华大学化学系 北京 100084
- 作者简介：
- 基金信息：
DOI：10.11777/j.issn1000-3304.2017.16262
CLC：Published：2017-1，
Received：29 August 2016，
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Xu Jiang-fei, Zhang Xi. Study on Supramolecular Polymers in China: An Overview and Outlook. [J]. Acta Polymerica Sinica (1):37-49(2017)
Xu Jiang-fei, Zhang Xi. Study on Supramolecular Polymers in China: An Overview and Outlook. [J]. Acta Polymerica Sinica (1):37-49(2017) DOI： 10.11777/j.issn1000-3304.2017.16262.
摘要
超分子聚合物是高分子科学与超分子科学交叉的研究方向.超分子聚合物的研究在中国引起了学术界的广泛兴趣，中国的学者们对推动此研究领域的发展做出了贡献，并在新的超分子聚合方法、可控超分子聚合以及功能超分子聚合物等方面取得了一系列重要的创新成果.本文总结和评述了中国超分子聚合物的研究与动态，并展望了超分子聚合物化学、超分子聚合物物理、超分子聚合物表征及功能超分子聚合物的未来发展.
Abstract
Supramolecular polymers are polymeric arrays of monomeric units that are held together by highly directional and reversible noncovalent interactions
resulting in polymeric properties in solution and bulk. It is an interdisciplinary direction of polymer science and supramolecular science. In contrast with conventional polymers on the basis of covalent bond
supramolecular polymers have drawn increasing attention because of many fascinating properties such as reversibility
adaptiveness
self-healing
and stimuli-responsiveness owing to the dynamic nature of noncovalent interactions. These attributes have endowed supramolecular polymers with great potential applications in the field of functional materials
and also have motivated chemists to construct a variety of supramolecular polymers and supramolecular polymeric materials. The fabrication of supramolecular polymers and the investigation of functional supramolecular polymers have been a topic of great interest for the scientific communities in China in recent years. This review article is aimed to summarize some research progresses on supramolecular polymers in China
including the design of building blocks and driving forces for the fabrication of supramolecular polymers with high molecular weight
construction of supramolecular polymers with various topologies
new methods for controllable supramolecular polymerization
and functional supramolecular polymers. The characteristics
advantages
and potential applications of supramolecular polymers
as well as the comparisons of the structure and properties between the covalent polymers and the supramolecular polymers are also discussed. Although polymer science on the basis of covalent bond has been and will still be the core science in the polymer community
supramolecular polymers based on noncovalent interactions are complementary to traditional polymer science and represent new growth point by marrying supramolecular science with polymer science. Last but not least
with the aim to push forward the studies on supramolecular polymers
more attention should be paid to developing and enriching supramolecular polymer chemistry and physics
the methods for their characterization and special supramolecular polymers with tailor-made molecular architectures and functions.
关键词
超分子聚合物非共价键作用超分子化学分子自组装
Keywords
Supramolecular polymerNoncovalent interactionSupramolecular chemistryMolecular self-assembly
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