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Progress in Stimuli-responsive Photonic Crystals with Biological Structures
- Acta Polymerica Sinica Issue 2, Pages: 229-244(2017)
- 作者机构：
上海交通大学 金属基复合材料国家重点实验室 上海 200240
- 作者简介：
- 基金信息：
DOI：10.11777/j.issn1000-3304.2017.16271
CLC：Published：20 February 2017，
Received：5 September 2016，
Revised：12 October 2016，
扫 描 看 全 文
Zhu Shen-min, Lu Tao, Zhang Di. Progress in Stimuli-responsive Photonic Crystals with Biological Structures. [J]. Acta Polymerica Sinica (2):229-244(2017)
Zhu Shen-min, Lu Tao, Zhang Di. Progress in Stimuli-responsive Photonic Crystals with Biological Structures. [J]. Acta Polymerica Sinica (2):229-244(2017) DOI： 10.11777/j.issn1000-3304.2017.16271.
摘要
自然物种演化形成了多种复杂而精细的光子结构，这类结构兼具功能的特点，将具有刺激响应特性的材料与天然生物光子结构相结合，能够制备得到响应性光子晶体材料，在生物医疗检测、传感器件、装饰和防伪等方面具有巨大的应用前景.本文在前期研究工作的基础上，综述了近年来，具有生物结构的响应性光子晶体的研究进展，总结了自然界的天然分级光子结构种类及显色机理，重点阐述了基于刺激响应聚合物的响应性光子晶体的构筑及应用、以及响应机理，最后对具有生物结构的响应性光子晶体材料的问题进行了总结，对未来的研究进行了展望.
Abstract
There are diverse photonic structures formed in nature
which can perfectly match the functional and survival demands of the plants or creatures. Inspired by these hierarchical structures
researches have been trying to biomimetic fabrication of responsive photonic crystals through the combination of responsive materials and natural structures for the potential applications in biomedical detections
sensors
decorations and anti-counterfeiting
etc
. In this review
progress in stimuli-responsive photonic crystals with biological structures is summarized based on the recent research works
especially those on the variety of the natural photonic crystals with hierarchical structures and the coloration mechanism. The concept of photonic structures in nature is first given and the types are clarified separately with a typical example presented. Generally
these photonic structures can be divided into three categories:1D
2D and 3D. Accordingly
the coloration mechanism of these structures is explained. With periodic structures arranged in different directions
some of the nature species obtained the magnificent structural colours
which are ultra-difficult for artificial manufacture. Based on these hierarchically photonic structures
functionalization is achieved by introduction of functional materials into the system
such as noble metal
Fe
3
O
4
carbon nanotubes
and organic materials. This review emphasizes on the fabrication
application and responsive mechanism of the responsive photonic crystals based on the responsive polymers. It is known that there are many kinds of stimuli-responsive polymers. By depositing different kinds of stimuli-responsive polymers onto the nature species
that is biotemplates
the stimuli-responsive photonic crystals can be synthesized. The properties of the deposited polymers can be tuned accurately
which could lead to the change of the parameters of the biotemplates including periodic lengths and refractive indexes upon the environmental stimuli signals. Correspondingly
the coloration of the obtained materials is changed. A summary of the existing problems of the photonic crystals with natural structures is also given
making an outlook for the future research work.
关键词
光子晶体刺激响应聚合物生物结构
Keywords
Photonic crystalsStimuli-responsive polymersBiological structures
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